C‐Bound or O‐Bound Surface: Which One Boosts Electrocatalytic Urea Synthesis?

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(19)

Опубликована: Март 9, 2023

Abstract The electrocatalytic C−N coupling from carbon dioxide and nitrate under ambient conditions is kind of sustainable promising alternative method for urea synthesis. To date, the influence catalyst surface properties on molecular adsorption configuration synthesis activity unclear. In this work, we proposed that closely linked with localized charge bimetallic electrocatalysts, it found a negatively charged induces C‐bound path boosts yield rate can reach 13.1 mmol g −1 h Cu 97 3 ‐C, which about 13 times positively 30 70 ‐C counterpart O‐bound surface. This conclusion also applies to Cu−Bi Cu−Sn systems. modification shifts state, leads sharp decline in performance. We demonstrated more favorable than one boost

Язык: Английский

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Biobased: Biostimulants and biogenic nanoparticles enter the scene

The Science of The Total Environment, Год журнала: 2023, Номер 885, С. 163912 - 163912

Опубликована: Май 5, 2023

Anthropogenic activities generally consume non-renewable resources and release polluting substances into the environment. Concerning agriculture, cropping systems are almost based on exploiting resources. In recent years, increasing interest has been devoted to reusing agricultural, food other biomass wastes, considered relevant as they can be seen rich in compounds that find numerous applications. Biomass biorefining successfully applied opened up sustainable alternatives disposal of agroindustrial wastes. this area, an emerging, smart environmentally friendly way reduce impact waste environment is obtain innovative materials for agriculture. Therefore, part biobased strategies, use biostimulants biogenic nanoparticles crops recently proposed. Some research shown appropriate nanomaterials have potential counteract some problems plague The above improve crop performance, enhance tolerance biotic abiotic stresses, plant nutrition. light above, review aspires, first part, provide overview ideas central points characterize concept bioeconomy circular economy. second hand, most studies related valorization various types wastes leading their application agriculture presented. particular, obtained through synthesis using residues considered. conclusion, reported show biomasses represents a management valorization, enabling

Язык: Английский

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A methodological framework for assessing sea level rise impacts on nitrate loading in coastal agricultural watersheds using SWAT+: A case study of the Tar-Pamlico River basin, North Carolina, USA

The Science of The Total Environment, Год журнала: 2024, Номер 951, С. 175523 - 175523

Опубликована: Авг. 13, 2024

Язык: Английский

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Non-CO2 Greenhouse Gases

Elsevier eBooks, Год журнала: 2024, Номер unknown, С. 493 - 500

Опубликована: Янв. 1, 2024

Язык: Английский

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Enigmatic evolution of microbial nitrogen fixation: insights from Earth’s past

Trends in Microbiology, Год журнала: 2023, Номер 32(6), С. 554 - 564

Опубликована: Апрель 13, 2023

The evolution of nitrogen fixation undoubtedly altered nearly all corners the biosphere, given essential role in synthesis biomass. To date, there is no unified view on what planetary conditions gave rise to or how these have sustained it evolutionarily. Intriguingly, concentrations metals that nitrogenases require function changed throughout Earth's history. In this review, we describe interconnection metal and cycles with nitrogenase importance ancient ecology formation modern cycle. We argue exploration cycle's deep past will provide insights into humanity's immediate environmental challenges centered availability.

Язык: Английский

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Conversion of steppe to cropland increases spatial heterogeneity of soil functional genes

The ISME Journal, Год журнала: 2023, Номер 17(11), С. 1872 - 1883

Опубликована: Авг. 22, 2023

Язык: Английский

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Unveiling the impacts of microplastic pollution on soil health: A comprehensive review

The Science of The Total Environment, Год журнала: 2024, Номер 951, С. 175643 - 175643

Опубликована: Авг. 22, 2024

Язык: Английский

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Effects of antibiotics on microbial nitrogen cycling and N2O emissions: A review

Chemosphere, Год журнала: 2024, Номер 357, С. 142034 - 142034

Опубликована: Апрель 12, 2024

Язык: Английский

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Reviewing the role of bioenergy with carbon capture and storage (BECCS) in climate mitigation

Engineering Science & Technology Journal, Год журнала: 2024, Номер 5(7), С. 2323 - 2333

Опубликована: Июль 24, 2024

Climate change poses an imminent threat, necessitating innovative and sustainable strategies for mitigation. This paper explores the potential of Bioenergy with Carbon Capture Storage (BECCS) as a promising approach. The introductory section sets stage by elucidating urgency climate action. background surveys existing mitigation strategies, introducing bioenergy carbon capture technologies. delves into distinctive contributions to emission reduction assesses viability various sources. Simultaneously, discussion on (CCS) provides insight technological aspects capture. An integral focus is integration technologies in BECCS, exploring synergies that enhance their combined efficacy. Real-world examples case studies illustrate successful BECCS projects. Environmental social impacts are critically examined, considering sustainability ethical dimensions. Challenges criticisms associated discussed comprehensively, addressing concerns proposing solutions. concludes outlining future prospects offering recommendations policymakers stakeholders. It also suggests avenues further research development this evolving field. Keywords: Bioenergy, (BECCS), Mitigation.

Язык: Английский

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Reactive nitrogen emissions from cropland and their dominant driving factors in China

The Science of The Total Environment, Год журнала: 2025, Номер 968, С. 178919 - 178919

Опубликована: Фев. 22, 2025

Язык: Английский

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