Occurrence of bisphenol A analogues in the aquatic environment and their behaviors and toxicity effects in plants

Environment International, Год журнала: 2024, Номер 193, С. 109105 - 109105

Опубликована: Окт. 30, 2024

Язык: Английский

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The difference of organophosphate esters (OPEs) uptake, translocation and accumulation mechanism between four varieties in Poaceae

Journal of Plant Physiology, Год журнала: 2025, Номер 305, С. 154418 - 154418

Опубликована: Янв. 1, 2025

Язык: Английский

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Occurrence and bioaccumulation of organophosphate flame retardants in high-altitude regions: A comprehensive field survey in Qinghai Province, China

Ecotoxicology and Environmental Safety, Год журнала: 2025, Номер 289, С. 117715 - 117715

Опубликована: Янв. 1, 2025

Organophosphate flame retardants (OPFRs) are a class of substances that pose potential risks to human health and ecosystems due their large-scale production, wide range applications, ubiquitous presence in the environment. With for long-range atmospheric transport (LRAT), OPFR pollution high-altitude areas has become an increasing concern. Herein, general pretreatment method OPFRs across various sample matrices was established combined with gas chromatography-mass spectrometry (GC-MS), utilizing programmed temperature ramp vaporization chamber enable high-throughput detection environmental matrices. were quantified soil, grass, tree bark, wild rat liver samples collected from Qinghai, China (elevation: 2657-4635 m), occurrence bioaccumulation behaviors systematically investigated. All contaminated OPFRs, ∑OPFR concentrations showing trend (mean: 439 ng/g, median: 420 ng/g) > grass 338 273 soil 190 162 bark 125 116 ng/g). Paired Spearman correlation analysis showed ∑OPFRs significantly positively correlated (P = 0.0023), indicating is main source grass. Among samples, tris(2-chloroisopropyl) phosphate (TCIPP) tris(2-chloroethyl) (TCEP) had highest contribution rates ∑OPFRs, cumulative contributions 60.9 %, 48.6 76.5 71.1 respectively, proportion industrial sources reaching this area through LRAT relatively high. Biomagnification factor (BMF) revealed exhibited significant biomagnification effects within soil-grass-rat terrestrial food chain. The ecological risk assessment results indicated study high risk, aryl-OPFRs posing greatest risk. Our findings provide crucial foundation further investigation into contamination characteristics regions.

Язык: Английский

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Analysis of potential human accumulation differences and mechanisms of environmental new flame retardants: Based on in vitro experiments and theoretical calculations

The Science of The Total Environment, Год журнала: 2025, Номер 963, С. 178542 - 178542

Опубликована: Янв. 17, 2025

Язык: Английский

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Uptake, translocation, and biotransformation of phthalate acid esters in crop plants: A comprehensive review

Journal of Hazardous Materials, Год журнала: 2025, Номер 489, С. 137580 - 137580

Опубликована: Фев. 11, 2025

Язык: Английский

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Understanding phytotoxicity of fosthiazate on crop seedlings through uptake kinetics, ROS burst and chloroplast metabolism

Journal of Hazardous Materials, Год журнала: 2025, Номер unknown, С. 138010 - 138010

Опубликована: Март 1, 2025

Язык: Английский

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Percutaneous penetration of typical Organophosphate esters under catalysis by Carboxylesterase: Characteristics, mechanism and prediction model

Environment International, Год журнала: 2025, Номер unknown, С. 109419 - 109419

Опубликована: Март 1, 2025

Язык: Английский

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Nationwide investigation on organophosphate esters and di-esters in raw grains from China: Distribution, sources, and implications for risk assessment

Environment International, Год журнала: 2025, Номер unknown, С. 109437 - 109437

Опубликована: Апрель 1, 2025

Studies on dietary exposure to organophosphate esters (OPEs) and diesters (di-OPEs) are limited, especially regarding di-OPEs their presence in raw grains, which fundamental staples of the human diet. In this study, 18 OPEs 8 were measured 289 grain samples from 13 major grain-producing regions China belonging four types: wheat, rice, maize, soybean. Tris(2-chloroisopropyl) phosphate (TCIPP) tris(2-ethylhexyl) (TEHP) dominant OPEs, while bis(2-ethylhexyl) (BEHP) was main di-OPE. The highest concentrations both ∑OPEs ∑di-OPEs observed soybean (median: 14.9 1.87 ng/g, respectively), followed by wheat (4.79 1.69 ng/g), maize (2.63 1.10 rice (2.37 0.726 ng/g). regional distribution relatively homogeneous. significantly higher Sichuan Shandong provinces, whereas spatial patterns differed, suggesting separate sources for di-OPEs. Soil type, straw turnover, pesticide use could affect TEHP, tri(2-chloroethyl) (TCEP), triethyl (TEP) respectively. Except TEHP tris(1,3-dichloro-2-propyl) (TDCPP), whose similar polished other accounted only 1.9-36 % those reported previously, indicating industrial processing as source these marketed grains. estimated daily intake through consumption 25.0-40.4 ng/kg bw/d 7.55-11.7 bw/d, respectively, primarily contributed than dust ingestion drinking water, that is exposure. Di-OPEs directly ingested grains derived metabolism parent implying estimating OPE based internal di-OPE levels inaccurate warrants further research.

Язык: Английский

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Analysis of Organic Contaminants and In Vitro Cytotoxicity to Test the Suitability of External Organic Matter Processing

ACS Environmental Au, Год журнала: 2025, Номер unknown

Опубликована: Апрель 10, 2025

Язык: Английский

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Field study on the uptake pathways and their contributions to the accumulation of organophosphate esters, phthalates, and polycyclic aromatic hydrocarbons in upland rice

The Science of The Total Environment, Год журнала: 2024, Номер 946, С. 174205 - 174205

Опубликована: Июнь 22, 2024

Язык: Английский

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