eScience,
Год журнала:
2022,
Номер
2(6), С. 591 - 605
Опубликована: Ноя. 1, 2022
Electrochemiluminescence
(ECL)
has
been
widely
applied
in
imaging
owing
to
features
that
distinguish
it
from
other
microscopic
techniques
and
electrochemical
methods,
including
its
high
signal-to-noise
ratio,
remarkable
sensitivity,
wide
linear
range,
spatiotemporal
resolution,
near-zero
background
light.
Imaging
technology
based
on
ECL
used
the
fields
of
immunosensing,
pathological
cell
detection,
drug
analysis.
Additionally,
simple
operation
ability
detect
dynamic
processes
catalytic
sites
strengthen
potential
for
research
material
surfaces
interfaces,
vivo
biological
analysis,
visualization.
At
same
time,
emergence
a
variety
nanomaterials
new
analysis
equipment
further
promoted
development
high-resolution
technology.
This
paper
introduces
mechanisms
main
systems.
It
then
describes
various
forms
reviews
progress
single-particle
imaging,
fingerprint
structure
single-cell
imaging.
Finally,
authors
offer
their
views
about
prospects
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 5, 2025
Abstract
Electrocatalytic
NO
3
−
reduction
to
NH
is
a
promising
technique
for
both
ammonia
synthesis
and
nitrate
wastewater
treatment.
However,
this
conversion
involves
tandem
processes
of
H
2
O
dissociation
hydrogenation,
leading
inferior
Faraday
efficiency
(FE)
yield
rate.
Herein,
catalyst
by
anchoring
atomically
dispersed
Cu
species
on
Mo‐doped
WO
(Cu
5
/Mo
0.6
‐WO
)
the
RR
constructed,
which
achieves
superior
FE
N
98.6%
rate
26.25
mg
h
−1
cat
at
−0.7
V
(vs
RHE)
in
alkaline
media,
greatly
exceeding
performance
Mo
/WO
counterparts.
Systematic
electrochemical
measurement
results
reveal
that
promoted
activation
sites,
accompanying
accelerated
water
producing
active
hydrogens
are
responsible
performance.
In
situ
infrared
spectroscopy
theoretical
calculation
further
demonstrate
sites
accelerate
,
dopant
activates
adjacent
resulting
decreased
energy
barrier
*
stepwise
hydrogenation
processes,
making
thermodynamically
favorable.
This
work
demonstrates
critical
role
atomic
level
enhancing
electrocatalytic
paving
feasible
avenue
developing
high‐performance
electrocatalysts.
eScience,
Год журнала:
2022,
Номер
3(1), С. 100086 - 100086
Опубликована: Ноя. 23, 2022
Electrochemical
C–N
coupling
has
generated
intense
research
interest
as
a
promising
approach
to
reduce
carbon
and
nitrogen
emissions
store
excess
renewable
electricity
in
valuable
chemicals
(e.g.,
urea,
amides,
amines).
In
this
review,
we
discuss
the
emerging
trends
electrocatalytic
reactions
using
CO2
inorganic
nitrogenous
species
(i.e.,
dinitrogen
(N2),
nitrate
(NO2−),
nitrite
(NO3−),
ammonia
(NH3))
raw
materials.
The
related
reaction
mechanisms
potential
design
principles
for
advanced
electrocatalysts
are
outlined.
addition,
effects
of
different
reactors,
including
H-cells,
membrane-based
flow
membrane
electrode
assembly
electrolyzers,
on
emphasized.
Finally,
current
challenges
future
opportunities
field
described.
We
aim
provide
an
up-to-date
overview
electrochemical
system
advance
progress
toward
its
practical
application.
eScience,
Год журнала:
2022,
Номер
2(6), С. 591 - 605
Опубликована: Ноя. 1, 2022
Electrochemiluminescence
(ECL)
has
been
widely
applied
in
imaging
owing
to
features
that
distinguish
it
from
other
microscopic
techniques
and
electrochemical
methods,
including
its
high
signal-to-noise
ratio,
remarkable
sensitivity,
wide
linear
range,
spatiotemporal
resolution,
near-zero
background
light.
Imaging
technology
based
on
ECL
used
the
fields
of
immunosensing,
pathological
cell
detection,
drug
analysis.
Additionally,
simple
operation
ability
detect
dynamic
processes
catalytic
sites
strengthen
potential
for
research
material
surfaces
interfaces,
vivo
biological
analysis,
visualization.
At
same
time,
emergence
a
variety
nanomaterials
new
analysis
equipment
further
promoted
development
high-resolution
technology.
This
paper
introduces
mechanisms
main
systems.
It
then
describes
various
forms
reviews
progress
single-particle
imaging,
fingerprint
structure
single-cell
imaging.
Finally,
authors
offer
their
views
about
prospects
