Materials Today,
Год журнала:
2023,
Номер
73, С. 105 - 129
Опубликована: Июнь 10, 2023
Interconnected
porous
materials
have
recently
emerged
as
hybrid
materials,
comprising
(meso/micro)pores
with
interconnected
(micro/meso)porous
walls.
Benefiting
from
structural,
morphological,
and
geometrical
properties,
are
endowed
high
porosity,
specific
surface
area,
mass
transfer
capacity,
tailored
pore
sizes,
volume
shape
compatibility.
These
can
be
synthesized
further
functionalized
into
a
wide
range
of
nanomaterials
by
either
modifying
conventional
strategies
or
involving
novel
such
pillared-layer
assembly,
defect-formation
and/or
the
use
structure-directing
agents.
Owing
to
their
exceptional
already
exhibited
remarkable
potential
in
various
practical
applications
including
reduction,
sensing,
purification,
detection
gases,
harvesting,
conversion,
storage
energy,
photocatalysis,
electrocatalysis,
chemical
synthesis,
well
non-automotive
applications.
A
brief
description
recent
advancements
catalysis
energy
conversion/storage
prospects
is
provided
this
contribution.
Advanced Materials,
Год журнала:
2022,
Номер
35(8)
Опубликована: Дек. 8, 2022
Due
to
the
unique
electronic
structure
of
aluminum
ions
(Al3+
)
with
strong
Coulombic
interaction
and
complex
bonding
situation
(simultaneously
covalent/ionic
bonds),
traditional
electrodes,
mismatching
orbital
Al3+
,
usually
exhibit
slow
kinetic
process
inferior
rechargeable
batteries
(RABs)
performance.
Herein,
break
confinement
mismatch
between
electrode,
a
previously
unexplored
Se2.9
S5.1
-based
cathode
sufficient
valence
energy
overlap
easily
accessible
is
potentially
developed.
Through
this
new
strategy,
encapsulated
in
multichannel
carbon
nanofibers
free-standing
exhibits
high
capacity
606
mAh
g-1
at
50
mA
rate-capacity
(211
2.0
A
),
robust
stability
(187
0.5
after
3,000
cycles),
enhanced
flexibility.
Simultaneously,
in/ex-situ
characterizations
also
reveal
mechanism
Sex
Sy
RABs.
Advanced Functional Materials,
Год журнала:
2023,
Номер
33(26)
Опубликована: Март 31, 2023
Abstract
Introducing
sodium
as
anode
to
develop
metal
batteries
(SMBs)
is
a
promising
approach
for
improving
the
energy
density
of
sodium‐ion
batteries.
However,
fatal
problems,
such
uncontrollable
dendrite
growth,
unstable
solid
electrolyte
interphase
(SEI)
in
low‐cost
carbonate‐based
electrolytes,
and
serious
safety
issues,
greatly
impede
practical
applications.
Here,
multifunctionalized
separator
rationally
designed,
by
coating
PP
(<25
µm)
with
solid‐state
NASICON‐type
fast
ionic
conductor
layer
(NZSP@PP)
replace
widely
used
thick
glass
fiber
(>200
successfully
solves
all
above
first
time
creats
high
performance
SMBs
using
Na
3
V
2
(PO
4
)
(NVP)
cathodes
pouch
cell.
The
Na||NVP
full
cells
can
stably
cycle
over
1200
times
capacity
retention
80%
at
rate
10
C
deliver
specific
80
mAh
g
−1
even
30
C,
indicating
extraordinary
fast‐charging
characters.
also
200
96.4%
under
NVP
loading
10.7
mg
cm
−2
.
Most
importantly,
SMB
cell
long‐life
cycles
well
high‐temperature
battery
performance,
which
guarantees
application.
Materials Today,
Год журнала:
2023,
Номер
73, С. 105 - 129
Опубликована: Июнь 10, 2023
Interconnected
porous
materials
have
recently
emerged
as
hybrid
materials,
comprising
(meso/micro)pores
with
interconnected
(micro/meso)porous
walls.
Benefiting
from
structural,
morphological,
and
geometrical
properties,
are
endowed
high
porosity,
specific
surface
area,
mass
transfer
capacity,
tailored
pore
sizes,
volume
shape
compatibility.
These
can
be
synthesized
further
functionalized
into
a
wide
range
of
nanomaterials
by
either
modifying
conventional
strategies
or
involving
novel
such
pillared-layer
assembly,
defect-formation
and/or
the
use
structure-directing
agents.
Owing
to
their
exceptional
already
exhibited
remarkable
potential
in
various
practical
applications
including
reduction,
sensing,
purification,
detection
gases,
harvesting,
conversion,
storage
energy,
photocatalysis,
electrocatalysis,
chemical
synthesis,
well
non-automotive
applications.
A
brief
description
recent
advancements
catalysis
energy
conversion/storage
prospects
is
provided
this
contribution.
