Chemical Papers, Год журнала: 2024, Номер 78(9), С. 5393 - 5405
Опубликована: Май 4, 2024
Язык: Английский
Chemical Papers, Год журнала: 2024, Номер 78(9), С. 5393 - 5405
Опубликована: Май 4, 2024
Язык: Английский
Nature Communications, Год журнала: 2025, Номер 16(1)
Опубликована: Фев. 19, 2025
Abstract Acidic electrochemical CO 2 conversion is a promising alternative to overcome the low utilization. However, over-reliance on highly concentrated K + inhibit hydrogen evolution reaction also causes (bi)carbonate precipitation interfere with catalytic performance. In this work, under screening and guidance of computational simulations, we present carbon coated tip-like O 3 electrocatalyst for stable efficient acidic synthesize formic acid (HCOOH) concentration. The layer protects oxidized species higher intrinsic activity from reductive corrosion, peripherally formulates tip-induced electric field regulate adverse H attraction desirable enrichment. an electrolyte at pH 0.94, only 0.1 M required achieve Faradaic efficiency (FE) 98.9% 300 mA cm −2 HCOOH long-time stability over100 h. By up-scaling electrode into 25 electrolyzer setup, total current 7 A recorded sustain durable production 291.6 mmol L −1 h .
Язык: Английский
Процитировано
3Journal of the American Chemical Society, Год журнала: 2024, Номер 146(33), С. 23625 - 23632
Опубликована: Авг. 9, 2024
The interfacial species-built local environments on Cu surfaces impact the CO
Язык: Английский
Процитировано
9eScience, Год журнала: 2024, Номер unknown, С. 100306 - 100306
Опубликована: Авг. 1, 2024
Язык: Английский
Процитировано
8Small, Год журнала: 2024, Номер 20(49)
Опубликована: Сен. 29, 2024
Copper sulfides (Cu
Язык: Английский
Процитировано
8Materials Today Sustainability, Год журнала: 2024, Номер 25, С. 100686 - 100686
Опубликована: Янв. 24, 2024
Язык: Английский
Процитировано
7eScience, Год журнала: 2024, Номер unknown, С. 100333 - 100333
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
7Processes, Год журнала: 2024, Номер 12(2), С. 303 - 303
Опубликована: Янв. 31, 2024
Given the environmental problems caused by burning fossil fuels, it is believed that converting carbon dioxide (CO2) into chemical inputs a great ally to generating clean energy. In this way, investigative studies related electrochemical CO2 reduction (CO2RE) concerning behavior of metal catalysts have received attention about processes involved. CO2RE can be an important tool mitigate presence gas in Earth’s atmosphere. these considerations, review, we report main used act as CO2RE. Among them, emphasize based on Ni, Zn, and Cu, which encompass properties conversion CO2. Regarding Cu-based catalyst, presents high efficiency but low selectivity. Furthermore, also describe mechanisms
Язык: Английский
Процитировано
6eScience, Год журнала: 2024, Номер unknown, С. 100352 - 100352
Опубликована: Дек. 1, 2024
Язык: Английский
Процитировано
6ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown
Опубликована: Март 29, 2024
The conversion of CO2 into value-added chemicals and fuels using stable, cost-effective, eco-friendly metal-free catalysts is a promising technology to mitigate the global environmental crisis. In Calvin cycle natural photosynthesis, reduction (CO2R) achieved cofactor NADPH as reducing agent through 2e–/1H+ or H– transfer. Consequently, inspired by NAD(P)H, series organohydrides with adjustable reducibility show remarkable potential for efficient CO2R. this review, we first summarize photosensitizers NAD(P)H regeneration list representative photoenzyme CO2R system. Then, introduce NAD(P)H-inspired their applications in redox reactions. Furthermore, discuss recent progress breakthroughs utilizing catalysts. Moreover, delve reaction mechanisms these organohydrides, shedding light on sustainable alternatives metal-based Finally, offer insights prospects directions advancing intriguing avenue organohydride-based
Язык: Английский
Процитировано
5Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(36)
Опубликована: Июнь 19, 2024
Electrocatalytic conversion of CO
Язык: Английский
Процитировано
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