Polymers,
Год журнала:
2023,
Номер
15(19), С. 3879 - 3879
Опубликована: Сен. 25, 2023
This
paper
proposes
a
different
strategy
for
deriving
carbon
materials
from
biomass,
abandoning
traditional
strong
corrosive
activators
and
using
top−down
approach
with
mild
green
enzyme
targeted
to
degrade
the
pectin
matrix
in
inner
layer
of
pomelo
peel
cotton
wool,
inducing
large
number
nanopores
on
its
surface.
Meanwhile,
additional
hydrophilic
groups
produced
via
an
enzymatic
treatment
can
be
used
effectively
anchor
metallic
iron
atoms
prepare
porous
uniformly
dispersed
Fe−Nx
structures,
this
case
optimizing
sample
PPE−FeNPC−900’s
specific
surface
area
by
up
1435
m2
g−1.
PPE−FeNPC−900
is
as
electrode
material
6
M
KOH
electrolyte;
it
manifests
decent
capacitance
400
F
The
assembled
symmetrical
supercapacitor
exhibits
high
energy
density
12.8
Wh
kg−1
at
300
W
power
excellent
cycle
stability.
As
catalyst,
also
half−wave
potential
0.850
V
(vs.
RHE)
diffusion-limited
current
5.79
mA
cm−2
0.3
RHE).
It
has
higher
electron
transfer
lower
hydrogen
peroxide
yield
compared
commercial
Pt/C
catalysts.
green,
simple,
efficient
designed
study
converts
abundant,
low−cost
waste
biomass
into
high-value
multifunctional
materials,
which
are
critical
achieving
applications.
Energy & Fuels,
Год журнала:
2023,
Номер
37(15), С. 11432 - 11444
Опубликована: Июль 20, 2023
In
this
work,
the
preparation
of
porous
carbon
obtained
from
teak
(Tectona
grandis)
leaves
is
reported
and
used
for
supercapacitors
(SCs).
The
leaf
(TLC)
was
prepared
using
biowaste
as
source
precursors
by
NaOH
activation
pyrolysis
at
700–1000
°C
under
a
nitrogen
atmosphere.
crystallinity,
structural
features,
textural
properties,
thermal
stability
TLCs
were
characterized
variety
state-of-the-art
techniques.
Further
electrochemical
(EC)
measurements,
such
cyclic
voltammetry,
impedance
spectroscopy,
galvanostatic
charge–discharge
three-electrode
setup,
done.
TLC-900
has
micro-
mesoporous
materials
with
large
surface
areas
pore
volumes
high
1692.6
m2
g–1
0.86
cm3
g–1,
respectively.
Also,
they
exhibit
remarkable
EC
capacitive
achieving
maximum
specific
capacitance
(Csp)
310
F
current
density
1.0
A
in
3.0
M
KOH
solution.
Notably,
attained
stability,
123%
retention
same
electrolyte
after
10,000
cycles
g–1.
As
result,
fabricated
device
displayed
energy
24
W
h
kg–1
power
1818
10
These
outstanding
behaviors,
oxygen-containing
functional
groups,
characteristics
material
indicate
that
are
attractive
fabrication
future
large-scale
industrial
SCs.
Polymers,
Год журнала:
2023,
Номер
15(19), С. 3879 - 3879
Опубликована: Сен. 25, 2023
This
paper
proposes
a
different
strategy
for
deriving
carbon
materials
from
biomass,
abandoning
traditional
strong
corrosive
activators
and
using
top−down
approach
with
mild
green
enzyme
targeted
to
degrade
the
pectin
matrix
in
inner
layer
of
pomelo
peel
cotton
wool,
inducing
large
number
nanopores
on
its
surface.
Meanwhile,
additional
hydrophilic
groups
produced
via
an
enzymatic
treatment
can
be
used
effectively
anchor
metallic
iron
atoms
prepare
porous
uniformly
dispersed
Fe−Nx
structures,
this
case
optimizing
sample
PPE−FeNPC−900’s
specific
surface
area
by
up
1435
m2
g−1.
PPE−FeNPC−900
is
as
electrode
material
6
M
KOH
electrolyte;
it
manifests
decent
capacitance
400
F
The
assembled
symmetrical
supercapacitor
exhibits
high
energy
density
12.8
Wh
kg−1
at
300
W
power
excellent
cycle
stability.
As
catalyst,
also
half−wave
potential
0.850
V
(vs.
RHE)
diffusion-limited
current
5.79
mA
cm−2
0.3
RHE).
It
has
higher
electron
transfer
lower
hydrogen
peroxide
yield
compared
commercial
Pt/C
catalysts.
green,
simple,
efficient
designed
study
converts
abundant,
low−cost
waste
biomass
into
high-value
multifunctional
materials,
which
are
critical
achieving
applications.