Construction of three-dimensional porous organic polymers with enhanced CO2 uptake performance via solid-state thermal conversion from tetrahedral benzoxazine-linked precursor

European Polymer Journal, Год журнала: 2023, Номер 200, С. 112551 - 112551

Опубликована: Окт. 30, 2023

Язык: Английский

---

Bifunctional imidazolium linked tetraphenylethene based conjugated microporous polymers for dynamic antibacterial properties and supercapacitor electrodes

Polymer Chemistry, Год журнала: 2023, Номер 15(5), С. 397 - 411

Опубликована: Дек. 27, 2023

Using Sonogashira coupling reactions and a postmodification approach, we successfully synthesized TPET-Im CMP incorporating an imidazolium unit to enhance antibacterial properties optimize its performance as supercapacitor electrode.

Язык: Английский

---

Molecular level design of conjugated polymers based on a synergistic adsorption-photocatalytic strategy for efficient uranium capture

Chemical Engineering Journal, Год журнала: 2024, Номер 496, С. 153493 - 153493

Опубликована: Июнь 27, 2024

Язык: Английский

---

Novel advancements in synthesis, modulation, and potential applications of conjugated microporous polymer-based materials

Nano Materials Science, Год журнала: 2025, Номер unknown

Опубликована: Март 1, 2025

Язык: Английский

---

Systematic Design and Synthesis of Conjugated Microporous Polymers Containing Pyrene and Azobenzene Building Materials for High-Performance Energy Storage

ACS Applied Energy Materials, Год журнала: 2023, Номер 6(21), С. 11342 - 11351

Опубликована: Ноя. 1, 2023

Conjugated microporous polymers (CMPs), known for their high specific capacities, exceptional cycling stability, and outstanding rate performance, are being actively studied as advanced electrode materials energy storage applications. The utilization of redox-active units in CMP exhibits substantial promise. Nevertheless, the influence positioning region on electrochemical behavior battery performance remains a topic uncertainty. Herein, we successfully created two CMPs using Sonogashira–Hagihara coupling method, specifically by including azobenzene (Azo) moieties meta (m) para (p) locations. These named Py-mAzo-CMP Py-pAzo-CMP. To produce them, used precursor compounds (E)-1,2-bis(3-bromophenyl)diazene (mAzo-Br2) (E)-1,2-bis(4-bromophenyl)diazene (pAzo-Br2), combined with tetraethynylpyrene (Py-T). Our primary focus was to investigate impact substituting Azo unit at different positions. assess orientation molecules pores these Py-Azo-CMPs, conducted thorough analysis, BET isotherm measurements various spectroscopic microscopic techniques. findings from TGA analysis indicated that Py-Azo-CMPs exhibit moderate thermal stability. One remarkable discovery excellent Py-pAzo-CMP, which displayed capacitance 142 F g–1 (determined 1 A g–1), showcasing its capacitive properties. Despite operating current density 10 g–1, both Py-mAzo Py-pAzo-CMPs exhibited long-term retaining over 92% capacity even after 5000 cycles. results underscore potential Py-pAzo-CMP dependable enduring choice highlight significant promise Py-Azo-CMP suitability useful applications, electrical (EES).

Язык: Английский

---

Selective Capturing of the CO2 Emissions Utilizing Ecological (3-Mercaptopropyl)trimethoxysilane-Coated Porous Organic Polymers in Composite Materials

Polymers, Год журнала: 2024, Номер 16(13), С. 1759 - 1759

Опубликована: Июнь 21, 2024

Capturing carbon dioxide (CO2) is still a major obstacle in the fight against climate change and reduction of greenhouse gas emissions. To address this problem, we employed simple Friedel–Crafts alkylation to investigate effectiveness porous organic polymers (POPs) based on triphenylamine (TPA) trihydroxy aryl terms derived from chloranil (CH), designated as TPA-CH POP. We then treated POP with (3-mercaptopropyl)trimethoxysilane (3-MPTS), forming POP-SH nanocomposite enhance CO2 capture. Utilizing FTIR, solid-state NMR, SEM, TEM, along XPS techniques, molecular makeup, morphological characteristics, well physical features were thoroughly explored. Upon scorching 800 °C, demonstrated more thermal durability over POP, achieving char yield up 71.5 wt.%. The displayed 2.5-times better capture, comparable adsorption capacity 48.07 cm3 g−1 at 273 K. Additionally, found that exhibited an improved CO2/nitrogen (N2) selectivity versus original Typical enthalpy changes for capture somewhat increased by 3-MPTS coating, indicating greater binding energies between molecules adsorbent surface. Our outcomes demonstrate composite coated MPTS viable candidate effective uses. findings encourage investigation different functional groups optimization strategies.

Язык: Английский

---

Review: Development and application of porous materials to antibiotic drug adsorption and removal

Journal of Water Process Engineering, Год журнала: 2024, Номер 69, С. 106583 - 106583

Опубликована: Ноя. 22, 2024

Язык: Английский

---

Luminescent hollow spherical nanoparticles with enhanced imaging contrast through hydrogen bonding connected micelles

European Polymer Journal, Год журнала: 2024, Номер 210, С. 112954 - 112954

Опубликована: Март 26, 2024

Язык: Английский

---

Preparation and Properties of Polyaniline Self-Healing Conductive Materials Based on Hydrogen Bonding and Electrostatic Interaction Forces

ACS Applied Polymer Materials, Год журнала: 2023, Номер 5(11), С. 9585 - 9593

Опубликована: Окт. 26, 2023

Self-healing conductivity of materials is a very attractive property, but preparing simple green conductive material still challenge. In this article, self-healing was prepared by using polyaniline as substance with oxidized nanocellulose and polyacrylamide. When the are 1:1, fracture stress can reach 1.62 MPa (≈400%). Meanwhile, has certain effect due to presence hydrogen bonding electrostatic interaction forces. After 48 h at room temperature, maximum reached 0.83 MPa. The electrical 47.22 μS/cm, efficiency >90% after 1 temperature. This solution casting process, which allows be in large areas.

Язык: Английский

---

Visible-light-induced photocatalytic degradation of organic contaminants by Silver(I)-loaded N-rich porous organic polymers

Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(2), С. 112394 - 112394

Опубликована: Март 4, 2024

Язык: Английский

---