Insight into the effect of support properties on DBD plasma-catalytic NH3 synthesis over Ru-Co bimetallic catalysts
Fuel,
Год журнала:
2024,
Номер
382, С. 133802 - 133802
Опубликована: Ноя. 21, 2024
Язык: Английский
Ammonia Can Be Currently Considered One of the Best Green Energy Allies
Sustainable Chemistry,
Год журнала:
2024,
Номер
5(2), С. 163 - 195
Опубликована: Июнь 19, 2024
Ammonia
can
be
considered
a
relevant
compound
in
the
future
energy
sector,
playing
significant
role
as
an
carrier,
storage,
or
carbon-free
fuel.
However,
production
of
this
molecule
has
high
demand,
and
use
natural
gas,
which
is
not
free
controversy
due
to
accidental
leakage
into
atmosphere
produced
during
extraction
fact
that
it
nonrenewable
source,
contributes
increasing
greenhouse
gas
emissions.
Reducing
process’s
demand
carbon
footprint
will
essential
making
ammonia
clear
alternative
for
economy.
Given
vast
research
handling,
seems
logical
step
forward
evolution
sector.
current
uncertainty
global
market
requires
cautiousness
decision
making.
Several
factors
may
impact
economic
growth
human
welfare,
thus
needing
careful
assessment
before
any
transcendental
decisions
could
affect
worldwide
prices
raw
material
availability.
Язык: Английский
Construction of a Novel Hydrogen-Bond-Assisted Bisulfide Nonmetallic Active Center for Solar Ammonia Fertilizer Production
ACS Sustainable Chemistry & Engineering,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 4, 2024
Solar-driven
photocatalytic
nitrogen
reduction
is
a
promising
and
effective
way
to
produce
NH3
in
sustainable
manner.
The
reaction
product,
ammonium-based
nitrogen,
can
mimic
biological
fixation
for
plant
growth
replace
the
use
of
exogenous
fertilizers.
To
address
bottleneck
N2
activation
during
reduction,
catalyst
dithiosalicylic
acid
(DTSA)
with
hydrogen-bond-assisted
S–S
nonmetallic
active
center
was
constructed
by
thiosalicylic
this
study,
which
achieved
an
ammonia
yield
278.9
μmol/h/gcat..The
innovative
application
catalytic
product
as
replacement
fertilizer
Chlorella
resulted
significant
increase
concentration
without
yellowing
algal
filaments
compared
blank
control
group,
indicating
adequate
supply
functioning
Further
mechanistic
studies
reveal
alternating
pathway
at
center.
energy
barrier
rate-determining
step
(RDS)
effectively
reduced
from
2.79
2.11
eV
aid
intermolecular
hydrogen
bonding
DTSA.
controllable
mass
production
simple
synthesis,
used
cultivation
opportunity
development
NRR
catalysts
solar
Furthermore,
proposed
novel
provides
new
idea
direction
future
catalysts.
Язык: Английский