Efficient adsorption removal of anionic dyes by waste PET-derived MIL-101(Cr)

Separation and Purification Technology, Год журнала: 2024, Номер 354, С. 128985 - 128985

Опубликована: Июль 26, 2024

Язык: Английский

---

A 3D rigid Mn-MOF heterogeneous catalyst for thioether oxidation, cyanosilylation and Knoevenagel condensation

CrystEngComm, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A robust Mn( ii ) MOF with high thermal stability and chemical was prepared as an effective catalyst for thioether oxidation, cyanosilylation Knoevenagel condensation recycling runs.

Язык: Английский

---

Upcycling of Organic and Inorganic Waste into MIL-88B(Fe) at Room Temperature for Tetracycline Degradation

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 23, 2025

Upcycling organic and inorganic waste into value-added metal–organic frameworks (MOFs) presents a sustainable strategy for mitigating pollution promoting economic viability. However, rapid synthesis of MOF materials derived from actual industrial under mild conditions remains challenging. Herein, Fe-MOF MIL-88B(Fe) was successfully fabricated within 1 h at room temperature using galvanizing pickling liquid terephthalic acid poly(ethylene terephthalate). The resulting (s-MIL-88B(Fe)) employed to activate peroxymonosulfate (PMS) UV light irradiation, achieving over 87% degradation tetracycline hydrochloride (TCH) 15 min. effects the reaction parameters on TCH were thoroughly investigated. s-MIL-88B(Fe) demonstrated good stability reusability, maintaining 96% initial activity after five cycles. system also adaptability various pollutants water matrices. Radicals (SO4–•) nonradicals (1O2, h+) identified as key reactive species promoted degradation. formation mechanism pathway are proposed. Toxicity evaluation verified reduced toxicity This work provides approach upcycling MOF-based efficient environmental remediation conditions.

Язык: Английский

---

Conversion of Polyethylene Terephthalate Plastic into Metal-Organic Framework Materials for the Adsorption of Organic Dyes

Environmental Engineering Science, Год журнала: 2025, Номер 42(3), С. 126 - 136

Опубликована: Фев. 3, 2025

Язык: Английский

---

Naphthalenediimide crystalline metal -organic framework materials based on phenyl dicarboxylic acid ligands as a versatile platform for fluorescence sensing and reversible photochromism

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141699 - 141699

Опубликована: Фев. 1, 2025

Язык: Английский

---

A sustainable framework for advancing circular practices for polyethylene terephthalate textiles: optimized recycling of depolymerization byproducts and LCA validation

RSC Advances, Год журнала: 2025, Номер 15(10), С. 7354 - 7364

Опубликована: Янв. 1, 2025

This study demonstrates a novel circular approach for discarded polyethylene terephthalate (PET) textiles with life cycle assessment (LCA) validation, proposing an optimized recycling method PET depolymerization byproducts. The experimental emphasizes sourcing the metal-organic framework ingredients including metal and linker components from single reaction. For depolymerization, salt-based deep eutectic solvent (DES) composed of p-toluene sulfonic acid iron(iii) chloride hexahydrate was employed acting as both catalyst. Sequential recovery processes multiple products were established, their recyclability demonstrated. LCA performed on varied scenarios developed process, results provided solid grounds to conclude that suggested process produces relatively less burden environment, attributed effective catalytic action DES maximized use byproducts generated reactions. work pioneers comprehensive integrating methods establishing robust proof-of-concept maximizing potential products.

Язык: Английский

---

Engineered nanoporous HPM@NH2−MIL-101(Fe) catalyst for efficient oxidative desulfurization: Anchoring, electron channel, and valence state

Molecular Catalysis, Год журнала: 2025, Номер 579, С. 115046 - 115046

Опубликована: Март 21, 2025

Язык: Английский

---

Fabrication of BSA-protected AgNPs modified MIL-53(Al) as SERS substrate for trace determination of diquat and dipterex

Talanta, Год журнала: 2025, Номер unknown, С. 128002 - 128002

Опубликована: Март 1, 2025

Язык: Английский

---

Efficient and Selective Catalytic Oxidation of Ethylbenzene over Co-MOF Synthesized from Waste PET

Industrial & Engineering Chemistry Research, Год журнала: 2025, Номер unknown

Опубликована: Март 24, 2025

Язык: Английский

---

Eco-Frameworks for a Cleaner Planet: Harnessing Next-Gen MOFs for Pollution and Plastic Waste Remediation

Polymer Degradation and Stability, Год журнала: 2025, Номер unknown, С. 111349 - 111349

Опубликована: Март 1, 2025

Язык: Английский

---