In Situ Monitoring of Mechanofluorescence in Polymeric Nanofibers DOI Creative Commons

Valentina Antonia Dini,

Derek J. Kiebala, Damiano Genovese

и другие.

Macromolecular Rapid Communications, Год журнала: 2024, Номер unknown

Опубликована: Дек. 23, 2024

Mechanofluorescent polymers represent a promising class of materials exhibiting fluorescence changes in response to mechanical stimuli. One approach fabricating these involves incorporating aggregachromic dyes, whose emission properties are governed by the intermolecular distance, which can, turn, be readily altered microstructural surrounding polymer matrix during deformation. In this study, mechanofluorescent additive featuring excimer-forming oligo(p-phenylene vinylene) dyes (tOPV) is incorporated into electrospun polyurethane fibers, producing mats fibers with diameters ranging from 300 700 nm. The influence concentration and fiber orientation on under tensile deformation investigated. situ spectroscopy microscopy imaging reveal strain-dependent change color orange yellow or green, more pronounced prealigned fibers. Stresses experienced nanofibers elongation mapped real-time. data that forces initially concentrate aligned parallel applied strain, only later redistribute as other once they also align. These findings advance understanding force transfer within fibrous expected facilitate development self-reporting for applications load-bearing devices, wearable technologies, mechanochromic textiles.

Язык: Английский

Designing High-performance Fruit Packaging: Gelatin Films Enriched with Marine Seaweed Polysaccharides and Carbon Dots DOI

Cuirong Luan,

Zhiyu Li,

Jianan Lin

и другие.

Food Hydrocolloids, Год журнала: 2025, Номер 163, С. 111056 - 111056

Опубликована: Янв. 8, 2025

Язык: Английский

Процитировано

4

Development and characterization of polylactic acid/starch biocomposites – From melt blending to preliminary life cycle assessment DOI Creative Commons
Hossein Baniasadi,

Laura Äkräs,

Zahra Madani

и другие.

International Journal of Biological Macromolecules, Год журнала: 2024, Номер 279, С. 135173 - 135173

Опубликована: Авг. 28, 2024

This study presents a comprehensive analysis encompassing melt blending, characterization, life cycle assessment (LCA), and 3D printing of range polylactic acid (PLA)/starch biocomposites, with starch content varying from 0 to 50 wt%. To enhance compatibility between the particles PLA matrix, we utilized solvent-free method graft N-octadecyl isocyanate (ODI) molecules onto surface particles, resulting in ODI-g-starch, which yielded several improved properties. Notably, toughness elongation at break by approximately 170 % 300 %, respectively. Moreover, crystallinity increased 11.6 plain 30.1 suggesting that uniform dispersion ODI-g-starch acted as nucleating sites for crystallization chains. Additionally, viscosity decreased significantly introduction indicating their plasticizing effect, thereby enhancing processability ease fabrication biocomposite. Crucially, our LCA revealed significant reduction carbon footprint these up 18 63 compared selected fossil-based plastics, respectively, upon incorporation ODI-g-starch. In summary, research introduces newly developed PLA/starch biocomposites sustainable eco-friendly alternative commercially available specific plastics.

Язык: Английский

Процитировано

10

Strong, tough, and UV-resistant polylactic acid composites by incorporating doped carbon dots DOI

Ling Sun,

Song Liu,

WU Guo-qi

и другие.

International Journal of Biological Macromolecules, Год журнала: 2025, Номер unknown, С. 142416 - 142416

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

1

Physical and Mechanical Properties of Fused Deposition Modelling PLA/Carbon Dot Nanocomposites DOI
Alberto Jorge Baeza Campuzano,

Rafael Barbosa Rezende,

N. Cifuentes

и другие.

Materials Today Communications, Год журнала: 2024, Номер 40, С. 110025 - 110025

Опубликована: Авг. 1, 2024

Язык: Английский

Процитировано

1

Thermal conversion of Achillea maritima biomass into dual-functional carbon quantum dots for antioxidant activity and methylene blue removal DOI
Erdi Can Aytar, Alper Durmaz, İbrahim Mizan Kahyaoğlu

и другие.

Biomass Conversion and Biorefinery, Год журнала: 2024, Номер unknown

Опубликована: Окт. 28, 2024

Язык: Английский

Процитировано

1

In Situ Monitoring of Mechanofluorescence in Polymeric Nanofibers DOI Creative Commons

Valentina Antonia Dini,

Derek J. Kiebala, Damiano Genovese

и другие.

Macromolecular Rapid Communications, Год журнала: 2024, Номер unknown

Опубликована: Дек. 23, 2024

Mechanofluorescent polymers represent a promising class of materials exhibiting fluorescence changes in response to mechanical stimuli. One approach fabricating these involves incorporating aggregachromic dyes, whose emission properties are governed by the intermolecular distance, which can, turn, be readily altered microstructural surrounding polymer matrix during deformation. In this study, mechanofluorescent additive featuring excimer-forming oligo(p-phenylene vinylene) dyes (tOPV) is incorporated into electrospun polyurethane fibers, producing mats fibers with diameters ranging from 300 700 nm. The influence concentration and fiber orientation on under tensile deformation investigated. situ spectroscopy microscopy imaging reveal strain-dependent change color orange yellow or green, more pronounced prealigned fibers. Stresses experienced nanofibers elongation mapped real-time. data that forces initially concentrate aligned parallel applied strain, only later redistribute as other once they also align. These findings advance understanding force transfer within fibrous expected facilitate development self-reporting for applications load-bearing devices, wearable technologies, mechanochromic textiles.

Язык: Английский

Процитировано

0