Metal–Organic Frameworks as Photocatalysts for Solar-Driven Overall Water Splitting

Chemical Reviews, Год журнала: 2022, Номер 123(1), С. 445 - 490

Опубликована: Дек. 12, 2022

Metal–organic frameworks (MOFs) have been frequently used as photocatalysts for the hydrogen evolution reaction (HER) using sacrificial agents with UV–vis or visible light irradiation. The aim of present review is to summarize use MOFs solar-driven targeting overcome current efficiency limitations in overall water splitting (OWS). Initially, fundamentals photocatalytic OWS under solar irradiation are presented. Then, different strategies that can be implemented on adapt them photocatalysis discussed detail. Later, most active reported until now HER and/or oxygen (OER) critically commented. These studies taken precedents discussion existing sunlight requirements met at large scale also discussed. last section this provides a summary state field and comments future prospects could bring closer commercial application.

Язык: Английский

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Current trends on In2O3 based heterojunction photocatalytic systems in photocatalytic application

Chemical Engineering Journal, Год журнала: 2022, Номер 450, С. 137804 - 137804

Опубликована: Июнь 28, 2022

Язык: Английский

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Recent developments in photocatalysis of industrial effluents ։ A review and example of phenolic compounds degradation

Chemosphere, Год журнала: 2022, Номер 296, С. 133688 - 133688

Опубликована: Янв. 21, 2022

Язык: Английский

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Metal–Organic Framework‐Based Photocatalysis for Solar Fuel Production

Small Methods, Год журнала: 2022, Номер 7(1)

Опубликована: Дек. 1, 2022

Abstract Metal–organic frameworks (MOFs) represent a novel class of crystalline inorganic–organic hybrid materials with tunable semiconducting behavior. MOFs have potential for application in photocatalysis to produce sustainable solar fuels, owing their unique structural advantages (such as clarity and modifiability) that can facilitate deeper understanding the structure–activity relationship photocatalysis. This review takes photocatalytic active sites particular perspective, summarizing progress MOF‐based fuel production; mainly including three categories solar‐chemical conversions, water splitting hydrogen fuel, carbon dioxide reduction hydrocarbon nitrogen fixation high‐energy carriers such ammonia. focuses on types photocatalysts discusses enhanced activity based well‐defined structure MOFs, offering deep insights into

Язык: Английский

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A review of metal–organic framework (MOF) materials as an effective photocatalyst for degradation of organic pollutants

Nanoscale Advances, Год журнала: 2023, Номер 5(23), С. 6318 - 6348

Опубликована: Янв. 1, 2023

An overview of MOFs and their composite materials for better photocatalytic performance towards organic pollutants.

Язык: Английский

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A review on Z/S – scheme heterojunction for photocatalytic applications based on metal halide perovskite materials

Applied Surface Science Advances, Год журнала: 2022, Номер 9, С. 100241 - 100241

Опубликована: Апрель 1, 2022

As an emerging class of semiconductors, Metal Halide Perovskites (MHPs) form a major paradigm photocatalysts for its truly unique and superior optoelectronic properties over the traditional photocatalysts. Based on similar phenomenon plant's chlorophyll, use solar radiation to split water into oxygen hydrogen. MHPs, therefore significantly contribute family as novel rapidly expanding technological advancement. Whereas Z-scheme heterojunction is charge transfer mechanism that promotes diversified photocatalytic operations by utilizing ability sunlight, correctly synthesized semiconductor are potential substances addressing today's energy environmental concerns. Expanding number active reductive oxidative sites possessing high redox capacity just handful advantages recently designed which closely mimic actual photosynthesis mechanism. An efficient direct Z scheme heterojunction, system combined with enables us create higher efficiency activity. By combining second constituent appropriate band arrangement offsets, can be created, enabling innate competencies perovskites fully utilized. However, low inspires towards more step-scheme (S-scheme) photocatalysts, alternatively dwell developing heterojunctions incorporating multitude essential properties. This review paper focuses basic understanding different classes studied in academic world, would rather important define why MHP may successful endeavor being applications like CO2 reduction H2 evolution. given MHPs still infancy considered commercially, it underline present readiness level this technology drawbacks if any therefore, imperative lay down future roadmap development these

Язык: Английский

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Metal-organic frameworks (MOFs)-derived Co3O4@N-doped carbon as an electrode materials for supercapacitor

Journal of Energy Storage, Год журнала: 2022, Номер 55, С. 105449 - 105449

Опубликована: Авг. 16, 2022

Язык: Английский

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Photocatalytic active metal–organic framework and its derivatives for solar-driven environmental remediation and renewable energy

Coordination Chemistry Reviews, Год журнала: 2022, Номер 468, С. 214639 - 214639

Опубликована: Июнь 6, 2022

Язык: Английский

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A novel (Ti/Ce)UiO-X MOFs@TiO2 heterojunction for enhanced photocatalytic performance: Boosting via Ce4+/Ce3+ and Ti4+/Ti3+ redox mediators

Applied Catalysis B Environment and Energy, Год журнала: 2022, Номер 310, С. 121349 - 121349

Опубликована: Март 26, 2022

Язык: Английский

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MOF based composites with engineering aspects and morphological developments for photocatalytic CO2 reduction and hydrogen production: A comprehensive review

Journal of environmental chemical engineering, Год журнала: 2023, Номер 11(2), С. 109408 - 109408

Опубликована: Фев. 1, 2023

Язык: Английский

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