Applied Organometallic Chemistry,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 2, 2024
ABSTRACT
Amid
growing
environmental
concerns
and
the
need
for
a
sustainable
future,
green
synthetic
methodologies
are
gaining
popularity
their
simplicity
nontoxicity.
In
pursuit
of
eco‐friendly
synthesis
nanomaterials,
study
reports
an
innovative
Ag‐CuO
nanocomposites
via
coprecipitation
method
utilizing
Citrus
limetta
fruit
juice
extract
as
bioreductant
stabilizing
agent.
The
morphological
structural
characteristics
fabricated
were
evaluated
by
ultraviolet–visible
diffuse
reflectance
spectroscopy
(UV–vis
DRS),
Fourier
transform
infrared
(FTIR),
scanning
electron
microscopy
(SEM),
energy‐dispersive
X‐ray
(EDX),
transmission
(TEM),
diffraction
(XRD),
Raman
Brunauer–Emmett–Teller
(BET)
analyses.
crystalline
with
particle
sizes
ranging
from
15
to
24
nm
exhibited
spherical
rod‐like
shapes.
band
gap
value
specific
surface
area
found
be
1.5
eV
25.50
m
2
/g,
respectively.
photoluminescence
(PL)
analysis
electrochemical
studies
revealed
significant
charge
separation
effective
migration
behaviour
nanocomposites,
effectively
catalysed
Schiff
bases
aryl
aldehydes
aromatic
amines
at
room
temperature
without
solvents.
reactions
proceeded
in
brief
time
excellent
product
yields,
nanocatalyst
retained
its
activity
five
consecutive
cycles.
also
efficiently
photodegradation
Congo
red
dye
under
visible
light.
A
degradation
94.33%
was
attained
55
min,
maintained
efficacy
over
four
reaction
Moreover,
notable
anticancer
properties
against
MCF‐7
(human
breast)
cell
line,
demonstrating
remarkable
cytotoxicity
rate
87.79%.
findings
highlight
biosynthesized
catalysis,
remediation
biological
applications.
Abstract
This
study
introduces
a
novel
microwave‐assisted
combustion
method
for
synthesizing
AlFeO
3
perovskite,
promising
catalyst
environmental
remediation.
The
synthesized
perovskite
was
characterized
using
various
techniques:
FT‐IR,
XRD,
XRF,
BET,
VSM,
EDAX,
DRS,
Raman,
and
FE‐SEM.
optimal
operating
conditions
Rhodamine
B(RhB),
Remazol
Golden
Yellow
RNL
(RGY),
α‐lipoic
acid
(ALA)
ultrasonic
degradation
processes
were
established
(30,
15,
20
mg/L),
(5,
5,
9),
(1.00,
1.75,
1.50
g/L),
respectively.
addition
of
oxidants
like
H
2
O
K
S
8
significantly
enhanced
the
efficiency.
Furthermore,
antibacterial
properties
assessed.
Computational
simulations
Monte
Carlo
adsorption
locator
conducted
to
investigate
pollutant
molecules
adsorption,
orientation,
interaction
energy
on
surface,
revealing
spontaneous
with
negative
binding
energies.
provides
valuable
insights
into
potential
application
as
an
effective
Heliyon,
Год журнала:
2024,
Номер
10(16), С. e36189 - e36189
Опубликована: Авг. 1, 2024
This
review
underscores
the
fundamentals
of
MIP-CMs
and
systematically
summarizes
their
synthetic
strategies
applications,
potential
developments.
are
widely
acclaimed
for
versatility,
finding
applications
in
separation,
filtration,
detection,
trace
analysis,
as
well
serving
scaffolds
a
range
analytical,
biomedical
industrial
contexts.
Also
characterized
by
extraordinary
selectivity,
remarkable
sensitivity,
outstanding
capability
to
bind
molecules,
those
membranes
also
cost-effective,
highly
stable,
configurable
terms
recognition
and,
therefore,
inalienable
various
application
fields.
Issues
relating
future
paper
discussed
last
section
with
focus
on
improvement
resource
practical
across
different
areas.
Hence,
this
can
be
seen
kind
cookbook
design
fabrication
an
intention
expand
scope
application.
PLoS ONE,
Год журнала:
2024,
Номер
19(8), С. e0309388 - e0309388
Опубликована: Авг. 30, 2024
Investigating
novel
compounds
has
become
necessary
due
to
the
need
for
sophisticated
materials
in
optoelectronic
devices
and
spintronics.
Because
of
their
unique
properties,
magnesium-based
spinels
MgSm2X4
(X
=
S
Se)
are
very
promising
these
applications.
We
used
spin-polarized
PBEsol
structural
properties
functional
mechanical
behavior,
both
using
WIEN2k
code.
Both
compounds'
stability
magnetic
non-magnetic
phases
was
validated
by
Birch-Murnaghan
equation
state,
cubic
phase
verified
Born
criterion.
Their
ductile
character
shown
computation
Pugh's
ratio
Poisson
ratio.
MgSm2S4
MgSm2Se4
display
metallic
behavior
spin-up
channel
semiconducting
spin-down
channel,
indicating
a
half-metallic
nature,
according
TB-mBJ
potential
calculations.
With
total
moments
20
μB,
showed
ferromagnetic
properties.
Samarium
ions
contributed
5.27
μB
5.34
MgSm2Se4.
Furthermore,
we
computed
optical
parameters
energy
range
0
15
eV,
such
as
absorption,
extinction
coefficient,
reflectivity,
dielectric
function,
refractive
index.
Our
results
demonstrate
future
technological
developments
revealing
prospective
spintronic
