In Situ Growth of ZnAl‐LDH on Biomass Carbon for Highly Efficient Photodegradation of Malachite Green (MG) From Water DOI Open Access
Di Su, Wen Xu,

Dongbin Yang

и другие.

Applied Organometallic Chemistry, Год журнала: 2024, Номер 39(1)

Опубликована: Дек. 18, 2024

ABSTRACT As a renewable new material with high void ratio, large adsorption surface area, and rate, biomass carbon (BC) is promising adsorbent, which has received wide attention for the degradation of dyes. However, physical cannot completely remove dyes, there also risk secondary pollution. ZnAl‐layered double hydroxide (ZnAl‐LDH) semiconductor photocatalyst abundant active sites excellent efficiency. In this paper, we have designed oxide@biomass (ZnAl‐LDO@BC) formed by in situ grown LDH on waste poplar wood as synergistic photocatalytic system. BC support could enhance dispersity layered oxide (LDO), whereas LDO provide photodegradation function to BC. Our studies indicate that prepared ZnAl‐LDO@BC presents lower bandgap energy, higher complexation efficiency holes electrons than delignified (DB). result, increased removal rate malachite green (MG) 85.8%, 3.5 times DB. The maximum was close 98%, capacity 1954 mg g −1 under an initial concentration 200 L MG dye, possible mechanism investigated. study, conversion agroforestry wastes into high‐value materials applied dye provides pathway production stable, sustainable, superior material.

Язык: Английский

Tuned porous MOFs & COFs for arsenic removal- advanced water remediation approach DOI
Brij Mohan

Desalination, Год журнала: 2024, Номер 592, С. 118075 - 118075

Опубликована: Сен. 6, 2024

Язык: Английский

Процитировано

20
A series of MgAl layer double hydroxide-based materials intercalated with Clitoria ternatea flower extract as photocatalysts in the ciprofloxacin degradation DOI Creative Commons

Rohmatullaili,

Nur Ahmad,

Dila Savira

и другие.

Chemical Physics Impact, Год журнала: 2024, Номер 8, С. 100587 - 100587

Опубликована: Март 27, 2024

The preparation of MgAl Layer Double Hydroxide (LDH) was performed using the coprecipitation method. Pristine LDH calcined at 500°C to produce Oxide (LDO). two materials were modified via restacking-delaminating bioactive compounds from flower extract Clitoria ternatea (CT) LDH-CT and LDO-CT. Modifications are enhance stability catalyst structure, allowing its higher photocatalytic activities regeneration use. prepared catalysts characterized XRD, FT-IR, UV-DRS, BET, SEM-EDX. XRD diffraction pattern showed that three have typical patterns commonly observed in LDH-based materials. FT-IR spectra confirmed LDO-CT combined precursor has lowest bandgap energy with highest degradation kinetics. BET SEM-EDX characterization shows uniform surface pore size on used ciprofloxacin photodegradation under UV light. optimal dose 5 mg, while pH 5. LDO-CT, LDH-CT, capacity up 73.300%, 65.739%, 71.320%, respectively, within 120 minutes. Repeated use third cycle resulted %R reaching 80.871%, 74.003%, 52.025%, by LDH. Compared pristine LDH, CT intercalated exhibited more excellent stability.

Язык: Английский

Процитировано

6
ZnAl LDH-based Derivative Materials as Photocatalysts: Synthesis, Characterization, and Catalytic Performance in Tetracycline Degradation DOI Open Access

Rohmatullaili Rohmatullaili,

Nur Ahmad,

Desti Erviana

и другие.

Science & Technology Indonesia, Год журнала: 2024, Номер 9(2), С. 457 - 469

Опубликована: Апрель 2, 2024

Layered Double Hydroxide (LDH)-derived materials exhibited different characteristics from LDH precursors. The conversion of ZnAl into its derivative material has been carried out to find the best catalyst for TC degradation. (LDH)-based catalysts in this study have effectively synthesized using coprecipitation, calcination, and restacking procedures. Oxide (LDO) is derived calcination at 500°C. was also modified by adding Garcinia mangostana pericarp extract (GME). XRD, FT-IR, UV-DRS, SEM-EDX were used investigate catalyst. typical FT-IR spectra, whereas LDO showed metal oxide-like ZnAl-GME composite displayed combination spectra precursor material. XRD diffraction pattern attributes a layered material, other three did not. Calcination destroyed structure LDH, addition GME generated single-layered composite. decrease both particle size bandgap energy. At an ideal pH 5, batch system photodegradation 5 mg/L Tetracycline (TC), employing solar light irradiation. holds most significant catalytic activity structural stability through fifth regeneration cycle, degraded up 100% 90 minutes.

Язык: Английский

Процитировано

3
Zn-Al layered double hydroxide / polyurethane as a novel nanocomposite for cefixime antibiotic adsorption DOI Creative Commons

Hatem Kh. Mohamed,

Amna A. Kotp,

Asmaa Salah

и другие.

CHINESE JOURNAL OF ANALYTICAL CHEMISTRY (CHINESE VERSION), Год журнала: 2024, Номер 52(4), С. 100385 - 100385

Опубликована: Апрель 1, 2024

Wastewater contaminated with antibiotics requires innovative solutions to remove such pollutants efficiently. In this work, Zn-Al layered double hydroxide (LDH) adsorbent supported on polyurethane (PU) (Zn-Al LDH/PU) was synthesized using a simple co-precipitation method. The material characterized XRD, FTIR, SEM, TEM, TGA, zeta potential, and hydrodynamic size. This investigated for the removal of cefixime (CFX), which is model third-generation cephalosporin antibiotic. LDH phase showed typical hexagonal morphology layer sizes larger than 200 nm in diameter. CFX adsorption PU, LDH/PU maximum capacity 94.43, 57.17 mg/g 115.69 mg/g, respectively. Redlich-Peterson Baudu isotherm models were found be best fit Zn-Al/PU, equilibrium time 175 min 250 kinetics fitted pseudo-second order indicating chemisorption diffusion limited process. Numerous types bonding between functional groups both PU could explain mechanism. selectivity study Sulfamethoxazole Ciprofloxacin different concentrations discussed. . recyclability also studied. Also, effect temperature at (23, 35, 45, 55°C) thermodynamic parameters (∆H°, ∆S° ∆G°) calculated showing exothermic spontaneous process.The MTT assay indicated that biocompatibility nanostructures enhanced following modification demonstrating regulated minimal cytotoxic effects towards normal liver cell line (WRL-68).The can considered as promising low-cost antibiotic from wastewater streams.

Язык: Английский

Процитировано

3
High stability and selectivity of butterfly pea flower extract-NiAl LDH-based catalysts in the tetracycline degradation DOI

Rohmatullaili Rohmatullaili,

Nur Ahmad,

Zultriana Zultriana

и другие.

Environmental Science and Pollution Research, Год журнала: 2024, Номер 31(22), С. 33107 - 33119

Опубликована: Апрель 27, 2024

Язык: Английский

Процитировано

3
Progress on layered double hydroxides as green materials in sustainable agricultural production DOI
Tongtong Zhang, Zhenghong Xu,

Zhihua Xu

и другие.

Environmental Research, Год журнала: 2025, Номер unknown, С. 121031 - 121031

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
Boosting photocatalytic efficiency: LDH modified with gambier leaf extract for tetracycline degradation DOI Creative Commons

Jefri Jefri,

Najma Annuria Fithri, Fitri Suryani Arsyad

и другие.

Next Materials, Год журнала: 2025, Номер 7, С. 100633 - 100633

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
In-situ growth of polydopamine on the surface of heat-treated MgAl layered double hydroxide for capturing volatile iodine DOI
Yong Zhang, Kan Jiang, Jiaqi Feng

и другие.

Surfaces and Interfaces, Год журнала: 2025, Номер unknown, С. 106687 - 106687

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0
Study on the adsorption mechanism of heavy metal ions by Thiosulfate-Intercalated ZnAl-LDH DOI
Jinhui Li,

Yuming Wei,

Laixi Zou

и другие.

Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 114771 - 114771

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0
Insight of Anionic Dyes Adsorption from Their Aqueous Solutions onto MgAl LDH/Lignin: Characterization and Isotherm Studies DOI Creative Commons
Nur Ahmad,

Abd Rahman Marlan,

Satria Putra Jaya Negara

и другие.

Indonesian Journal of Material Research, Год журнала: 2024, Номер 2(2), С. 40 - 46

Опубликована: Июль 26, 2024

The removal of hazardous anionic dyes from wastewater is a critical environmental challenge due to their toxic effects and persistence in aquatic systems. This study investigates the adsorption performance new composite material, consisting MgAl layered double hydroxide (LDH) Lignin (MgAl LDH/Lignin), remove three different dyes: congo red, direct yellow, procion red. material was synthesized thoroughly examined using various techniques, including X-ray diffraction, Fourier transform infrared spectroscopy, Brunauer-Emmett-Teller, Barrett-Joyner-Halenda. isotherm studies indicate that red onto LDH/Lignin follows Langmuir model, suggesting monolayer on uniform surface. On other hand, yellow conforms Freundlich indicating possibility multiple layers being adsorbed surface with varying properties. maximum capacities for were found be 75.76 mg/g, 51.55 74.63 respectively. results this demonstrate promising capabilities composites as highly efficient adsorbents treatment contaminated dyes. research provides valuable insights into potential these address pressing issue water pollution sustainable manner.

Язык: Английский

Процитировано

2