Room temperature synthesis of β-ketonitriles catalyzed by metal–organic framework supported Pd nanoparticles

Journal of Catalysis, Год журнала: 2024, Номер 430, С. 115308 - 115308

Опубликована: Янв. 21, 2024

Язык: Английский

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Green and scalable synthesis of a dual-ligand Zn-MOF with unprecedented space–time yield in aqueous media and efficient CH₄/N₂ separation

Green Chemistry, Год журнала: 2024, Номер 26(21), С. 10867 - 10875

Опубликована: Янв. 1, 2024

A pioneering green and scalable modulator/base co-regulation strategy was developed, enabling the kg-scale synthesis of a dual-ligand Zn-MOF in water with superior space–time yield, offering promising material for industrial CH 4 /N 2 separation.

Язык: Английский

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Natural product synthesis by a nanoporous In-MOF Catalyst: Crystallographic insight by incorporating substrate inside its nanopores

Journal of Catalysis, Год журнала: 2024, Номер 437, С. 115641 - 115641

Опубликована: Июль 14, 2024

Язык: Английский

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Highly Efficient Photocatalytic Divergent Decarbonylative Silylation with Cinnamaldehyde via a [Ru(dcbpy)(bpy)₂]²⁺-Incorporated UiO-67 Framework

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 18542 - 18549

Опубликована: Дек. 5, 2024

We herein develop an innovative approach for the decarbonylative silylation using a molecular [Ru(dcbpy)(bpy)2]2+ (dcbpy = 2,2′-bipyridyl-5,5′-dicarboxylic acid; bpy 2,2′-bipyridine) incorporated UiO-67 metal–organic framework (MOFs) (denoted as UiO-67-Ru) powerful heterogeneous catalyst, which is then applied in reaction of abundantly available cinnamaldehydes with silanes under photothermal condition. Mechanistic studies reveal that silane can be absorbed and activated within cavities framework, leading to generation silyl radical. The radical plays key role process further goes through oxidative generate corresponding alkenyl silanes. This work not only develops strategy preparation from highly abundant cinnamaldehyde but also affords useful inspiration on rational design MOFs materials silylation.

Язык: Английский

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Potassium xanthate-promoted reductive sulfuration reaction: from aldehydes to thiol, disulfide, and thioester derivatives

Chemical Communications, Год журнала: 2023, Номер 60(9), С. 1140 - 1143

Опубликована: Дек. 26, 2023

Herein, we developed a synthetic strategy for the direct construction of C-S bonds to obtain biologically active sulfur-containing compounds and methodology involving reductive sulfuration aldehydes or ketones diverse substituted thiol, disulfide, thioester derivatives. EtOCS

Язык: Английский

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