Room temperature synthesis of β-ketonitriles catalyzed by metal–organic framework supported Pd nanoparticles
Journal of Catalysis,
Год журнала:
2024,
Номер
430, С. 115308 - 115308
Опубликована: Янв. 21, 2024
Язык: Английский
Green and scalable synthesis of a dual-ligand Zn-MOF with unprecedented space–time yield in aqueous media and efficient CH4/N2 separation
Zhang-Ye Han,
Xuefeng Bai,
Yan‐Long Zhao
и другие.
Green Chemistry,
Год журнала:
2024,
Номер
26(21), С. 10867 - 10875
Опубликована: Янв. 1, 2024
A
pioneering
green
and
scalable
modulator/base
co-regulation
strategy
was
developed,
enabling
the
kg-scale
synthesis
of
a
dual-ligand
Zn-MOF
in
water
with
superior
space–time
yield,
offering
promising
material
for
industrial
CH
4
/N
2
separation.
Язык: Английский
Natural product synthesis by a nanoporous In-MOF Catalyst: Crystallographic insight by incorporating substrate inside its nanopores
Journal of Catalysis,
Год журнала:
2024,
Номер
437, С. 115641 - 115641
Опубликована: Июль 14, 2024
Язык: Английский
Highly Efficient Photocatalytic Divergent Decarbonylative Silylation with Cinnamaldehyde via a [Ru(dcbpy)(bpy)2]2+-Incorporated UiO-67 Framework
Huahui Wang,
Bing-Bing Qin,
Jiali Cai
и другие.
ACS Catalysis,
Год журнала:
2024,
Номер
unknown, С. 18542 - 18549
Опубликована: Дек. 5, 2024
We
herein
develop
an
innovative
approach
for
the
decarbonylative
silylation
using
a
molecular
[Ru(dcbpy)(bpy)2]2+
(dcbpy
=
2,2′-bipyridyl-5,5′-dicarboxylic
acid;
bpy
2,2′-bipyridine)
incorporated
UiO-67
metal–organic
framework
(MOFs)
(denoted
as
UiO-67-Ru)
powerful
heterogeneous
catalyst,
which
is
then
applied
in
reaction
of
abundantly
available
cinnamaldehydes
with
silanes
under
photothermal
condition.
Mechanistic
studies
reveal
that
silane
can
be
absorbed
and
activated
within
cavities
framework,
leading
to
generation
silyl
radical.
The
radical
plays
key
role
process
further
goes
through
oxidative
generate
corresponding
alkenyl
silanes.
This
work
not
only
develops
strategy
preparation
from
highly
abundant
cinnamaldehyde
but
also
affords
useful
inspiration
on
rational
design
MOFs
materials
silylation.
Язык: Английский
Potassium xanthate-promoted reductive sulfuration reaction: from aldehydes to thiol, disulfide, and thioester derivatives
Yingqi Feng,
Jinli Nie,
Sijie Xie
и другие.
Chemical Communications,
Год журнала:
2023,
Номер
60(9), С. 1140 - 1143
Опубликована: Дек. 26, 2023
Herein,
we
developed
a
synthetic
strategy
for
the
direct
construction
of
C-S
bonds
to
obtain
biologically
active
sulfur-containing
compounds
and
methodology
involving
reductive
sulfuration
aldehydes
or
ketones
diverse
substituted
thiol,
disulfide,
thioester
derivatives.
EtOCS
Язык: Английский