Ru single atom modified DUT-67(Zr) with unsaturated Zr for high-efficiency photocatalytic nitrogen reduction

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125034 - 125034

Опубликована: Янв. 1, 2025

Язык: Английский

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Mixed-valence metal–organic frameworks: concepts, opportunities, and prospects

Chemical Society Reviews, Год журнала: 2024, Номер unknown

Опубликована: Дек. 20, 2024

Mixed-valence MOFs have exhibited unique features in different practical fields, resulting from long-range charge delocalization and a tunable band gap within the framework.

Язык: Английский

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Ti3+-mediated MIL-125(Ti) by metal substitution for boosting photocatalytic N2 fixation

Journal of Colloid and Interface Science, Год журнала: 2024, Номер 678, С. 616 - 626

Опубликована: Авг. 30, 2024

Язык: Английский

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Review on photocatalytic nitrogen fixation by local surface plasmon

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 87, С. 686 - 698

Опубликована: Сен. 10, 2024

Язык: Английский

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Regulating the Electronic Structure of Biobr by Cu-Doping to Promote Efficient Photocatalytic Nitrogen Fixation Reaction

Опубликована: Янв. 1, 2025

Abstract: Element doping is critical in regulating the electronic structure to enhance N2 adsorption, opening up new possibilities for achieving highly efficient photocatalytic nitrogen reduction reactions (pNRR). In this study, we successfully prepared Cu-doped BiOBr (Cu-BiOBr) operating a simple solvothermal method. Density Functional Theory (DFT) calculations and experimental investigations were employed explore how Cu influences performance of pNRR over BiOBr. The DFT analysis indicates that alters structure, lowers energy barrier reaction, narrows bandgap. This adjustment leads remarkable NH3 production rate 466.3 μmol⋅gcat−1⋅h−1 without need sacrificial agents 2% Cu-BiOBr sample. addition, based on findings in-situ FTIR, detailed mechanism adsorption/activation hydrogenation reaction N ≡ bonds was proposed. research introduces prospective way designing transition metal-doped catalysts with regulated structures pNNR, which has significant implications advancing other material systems.

Язык: Английский

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Environmentally friendly synthesis of quasi-MIL-100(Fe) with modulation defects for efficient Fenton-photo degradation of ciprofloxacin

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 131990 - 131990

Опубликована: Фев. 1, 2025

Язык: Английский

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Plasmon assisted generation of solvated electrons from low work function scandium oxide and their utilization for enhanced nitrogen reduction

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125148 - 125148

Опубликована: Фев. 1, 2025

Язык: Английский

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Regulating the Unsaturated Co Sites on MOF-74(Co) for Enhancing Photocatalytic N₂ to NH₃ Conversion

ACS Sustainable Chemistry & Engineering, Год журнала: 2025, Номер unknown

Опубликована: Фев. 27, 2025

Язык: Английский

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Emerging metal−organic framework-based materials for photocatalytic and electrocatalytic NH3 synthesis: Design principles, structure-activity correlation, and mechanistic insights

Coordination Chemistry Reviews, Год журнала: 2025, Номер 534, С. 216543 - 216543

Опубликована: Март 4, 2025

Язык: Английский

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Regulating the electronic structure of BiOBr by Cu-doping to promote efficient photocatalytic nitrogen fixation reaction

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132501 - 132501

Опубликована: Март 1, 2025

Язык: Английский

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