Sol-Gel Heterogeneization of an Ir(III) Complex for Sustainable Visible-Light Redox Photocatalysis DOI Creative Commons

Janira Herce,

Mónica Martínez-Aguirre,

Javier Gómez-Benito

и другие.

Molecules, Год журнала: 2025, Номер 30(8), С. 1680 - 1680

Опубликована: Апрель 9, 2025

Photocatalysis is a key strategy for the development of sustainable solar-driven chemical processes. In this work, we report synthesis and characterization novel organometallo–ionosilica material derived from self-condensation an alcoxysilane functionalized Ir(III) complex. acetonitrile suspension, retains photophysical properties its precursor in solution same solvent, together with significant absorption visible between 400 500 nm. As heterogeneous photocatalyst, showed high efficiency reductive dehalogenation 2-bromoacetophenone under blue light irradiation, achieving yields conversion about 90%, excellent recyclability seven catalytic cycles, retaining more than 70% efficiency. All these self-condensed highlight potential as efficient photocatalyst applications organic redox

Язык: Английский

Sol-Gel Heterogeneization of an Ir(III) Complex for Sustainable Visible-Light Redox Photocatalysis DOI Creative Commons

Janira Herce,

Mónica Martínez-Aguirre,

Javier Gómez-Benito

и другие.

Molecules, Год журнала: 2025, Номер 30(8), С. 1680 - 1680

Опубликована: Апрель 9, 2025

Photocatalysis is a key strategy for the development of sustainable solar-driven chemical processes. In this work, we report synthesis and characterization novel organometallo–ionosilica material derived from self-condensation an alcoxysilane functionalized Ir(III) complex. acetonitrile suspension, retains photophysical properties its precursor in solution same solvent, together with significant absorption visible between 400 500 nm. As heterogeneous photocatalyst, showed high efficiency reductive dehalogenation 2-bromoacetophenone under blue light irradiation, achieving yields conversion about 90%, excellent recyclability seven catalytic cycles, retaining more than 70% efficiency. All these self-condensed highlight potential as efficient photocatalyst applications organic redox

Язык: Английский

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