Recent advances and practical challenges of high-energy-density flexible lithium-ion batteries DOI
Guangxiang Zhang, Xin Chen, Yulin Ma

и другие.

Frontiers of Chemical Science and Engineering, Год журнала: 2024, Номер 18(8)

Опубликована: Июнь 11, 2024

Язык: Английский

Gel polymer electrolytes for rechargeable batteries toward wide-temperature applications DOI Creative Commons
Xiaoyan Zhou,

Yifang Zhou,

Le Yu

и другие.

Chemical Society Reviews, Год журнала: 2024, Номер 53(10), С. 5291 - 5337

Опубликована: Янв. 1, 2024

Design principles, engineering strategies, challenges, and opportunities of gel polymer electrolytes for rechargeable batteries toward wide-temperature applications are thoroughly reviewed.

Язык: Английский

Процитировано

61

Three-Dimensional Metal–Organic Framework@Cellulose Skeleton-Reinforced Composite Polymer Electrolyte for All-Solid-State Lithium Metal Battery DOI
Xin Song, Kang Ma,

Jian Wang

и другие.

ACS Nano, Год журнала: 2024, Номер 18(19), С. 12311 - 12324

Опубликована: Май 1, 2024

High-safety and high-energy-density solid-state lithium metal batteries (SSLMBs) attract tremendous interest in both academia industry. Especially, composite polymer electrolytes (CPEs) can overcome the limitations of single-component electrolytes. In this work, a strategy combining rigid functional skeleton with soft electrolyte to prepare reinforced CPEs was adopted. The situ grown zeolitic imidazolate frameworks (ZIFs) three-dimensional cellulose fiber (ZIF-67@CF) succinonitrile (SN) plasticizer into poly(ethylene oxide) (PEO) together form ZIF-67@CF/PEO-SN CPEs. addition ZIF-67@CF SN PEO synergistically enhanced physical electrochemical properties Furthermore, conduction mechanism lithium-ion (Li+) studied using density theory. It is impressive that at 30 °C exhibit high ionic conductivity 1.17 × 10–4 S cm–1, competitive Li+ transference number 0.40, wide window 5.0 V, notable tensile strength 18.7 MPa, superior plating/stripping stability (>550 h 0.1 mA cm2). Such favorable features endowed LiFePO4/(ZIF-67@CF/PEO-SN)/Li cell discharging capacity (152.5 g–1 0.2 C), long cycling lifespan (>150 cycles 99% retention), operating safety. This work provides insights promotes application functionalized for SSLMBs.

Язык: Английский

Процитировано

39

Challenges and Solutions of Solid‐State Electrolyte Film for Large‐Scale Applications DOI
Xiaozhong Huang, Tao Li,

Weiwei Fan

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер 14(11)

Опубликована: Янв. 26, 2024

Abstract Solid‐state lithium‐ion batteries are widely accepted as the promising next‐generation energy storage technology due to higher density and improved safety compared conventional with liquid electrolytes. Large‐area solid‐state electrolyte (SSE) films adequate thickness control, ionic conductivity, good interfacial contact can reduce internal resistance, increase real of batteries, manufacturing costs. Optimization SSE properties at particle scale large‐scale preparation key development high‐performance their industrialization. Therefore, this paper provides a comprehensive review SSE, covering both particle‐level features like effects size, density, air stability on electrochemical performance, well four major routes for relevant strategies structural optimization films. In addition, large‐area performance applications in pouch battery systems discussed detail. Finally, design principles particles summarized direction thin SSEs is envisaged.

Язык: Английский

Процитировано

20

Ultra-homogeneous dense Ag nano layer enables long lifespan solid-state lithium metal batteries DOI

Yaning Liu,

Tianqi Yang, Ruyi Fang

и другие.

Journal of Energy Chemistry, Год журнала: 2024, Номер 96, С. 110 - 119

Опубликована: Апрель 24, 2024

Язык: Английский

Процитировано

20

Progress in the application of polymer fibers in solid electrolytes for lithium metal batteries DOI

Junbao Kang,

Nanping Deng, Bowen Cheng

и другие.

Journal of Energy Chemistry, Год журнала: 2024, Номер 92, С. 26 - 42

Опубликована: Янв. 11, 2024

Язык: Английский

Процитировано

19

Boosting the Ionic Conductivity of Pyrrolidinium-Based Ionic Plastic Crystals by LLZO Fillers DOI Creative Commons
Kotoko Ariga,

Shuho Akakabe,

Ryotaro Sekiguchi

и другие.

ACS Omega, Год журнала: 2024, Номер 9(20), С. 22203 - 22212

Опубликована: Май 9, 2024

Organic ionic plastic crystals (OIPCs) have attracted attention as novel organic solid electrolyte materials, but their insufficient mechanical strength and conductivity prevented application. In this study, a lithium salt, bis(fluorosulfonyl)amide (LiFSA), an inorganic electrolyte, Li7La3Zr2O12 (LLZO), were added to OIPC, N,N-diethylpyrrolidinium ([C2epyr][FSA]). The fabricated organic–inorganic hybrid electrolytes evaluated thermally, mechanically, electrochemically reveal which factors affect the properties of electrolytes. All samples showed excellent thermal stability regardless LiFSA or LLZO concentration, they found be highly ion-conductive solids at wide range temperatures. It was also revealed that addition raised nanoindentation stiffness (HIT) [C2epyr][FSA]/LiFSA composites. higher than pristine reaching value 2.1 × 10–4 S cm–1 25 °C upon appropriate amounts LLZO. Overall, with concentration moderate exhibited conductivity. Cyclic voltammetry results [C2epyr][FSA]/LiFSA/LLZO composites lithium-ion conductors. These findings indicate by optimizing concentrations salt LLZO, it would possible realize applications

Язык: Английский

Процитировано

14

Polymer solid electrolytes with ultra-stable cycles and high-capacity retention for all-solid-state Li-metal battery DOI
Jingshun Wang, Yongquan Zhang,

Zengxu Chen

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 492, С. 152222 - 152222

Опубликована: Май 13, 2024

Язык: Английский

Процитировано

14

Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries DOI Open Access
M. Zampieri,

Guillermina Tommasone,

Luciana Morel

и другие.

Polymers, Год журнала: 2025, Номер 17(2), С. 164 - 164

Опубликована: Янв. 10, 2025

Lithium-sulfur (Li-S) batteries are promising candidates for next-generation energy storage due to their high density, cost-effectiveness, and environmental friendliness. However, commercialization is hindered by challenges, such as the polysulfide shuttle effect, lithium dendrite growth, low electrical conductivity of sulfur cathodes. Cellulose, a natural, renewable, versatile biopolymer, has emerged multifunctional material address these issues. In anode protection, cellulose-based composites coatings mitigate formation improve lithium-ion diffusion, extending cycle life enhancing safety. As separators, cellulose materials exhibit ionic conductivity, thermal stability, excellent wettability, effectively suppressing effect maintaining electrolyte stability. For cathode, cellulose-derived carbon frameworks binders loading, active retention, resulting in higher density cycling This review highlights diverse roles Li-S batteries, emphasizing its potential enable sustainable high-performance storage. The integration into systems not only enhances electrochemical performance but also aligns with goals green technologies. Further advancements processing functionalization could pave way broader application battery systems.

Язык: Английский

Процитировано

2

Sandwich-like polyimide nanofiber membrane of PEO-based solid-state electrolytes to promote mechanical properties and security for lithium metal batteries DOI
Yan He, Jinpeng Guo, Chuang Bi

и другие.

International Journal of Hydrogen Energy, Год журнала: 2025, Номер 109, С. 1266 - 1273

Опубликована: Фев. 17, 2025

Язык: Английский

Процитировано

2

Oxygen-rich vacancies amorphous metal-organic frameworks composited with PEO solid electrolyte for lithium metal batteries DOI

Huiyao Li,

Wenhao Tang, Youlan Zou

и другие.

Journal of Power Sources, Год журнала: 2025, Номер 631, С. 236249 - 236249

Опубликована: Янв. 22, 2025

Язык: Английский

Процитировано

1