Construction of S-Scheme 2D/2D Crystalline Carbon Nitride/BiOIO3 van der Waals Heterojunction for Boosted Photocatalytic Degradation of Antibiotics

Molecules, Год журнала: 2023, Номер 28(13), С. 5098 - 5098

Опубликована: Июнь 29, 2023

Utilization of semiconductor photocatalyst materials to degrade pollutants for addressing environmental pollution problems has become a research focus in recent years. In this work, 2D/2D S-scheme crystalline carbon nitride (CCN)/BiOIO3 (BOI) van der Waals heterojunction was successfully constructed effectively enhancing the degradation efficiency antibiotic contaminant. The as-synthesized optimal CCN/BOI-3 sample exhibited highest 80% photo-degradation tetracycline (TC, 20 mg/L) after 120 min visible light irradiation, which significantly higher than that pure CCN and BOI. significant improvement photocatalytic performance is mainly attributed two aspects: (i) can accelerate interface carriers' separation transfer afford sufficient active sites; (ii) elevated redox capacity CCN/BOI, thus providing driving force reaction. pathways TC CCN/BOI composite were investigated detail by liquid chromatography-mass spectrometry (LC-MS) analysis. This work provides design idea development efficient photocatalysts based on heterojunctions.

Язык: Английский

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Construction of an S-scheme Ce/Ti-MOFs heterojunction with abundant Oxygen vacancies (Ovs) for efficient charges separation: Performance and mechanism insight

Journal of Water Process Engineering, Год журнала: 2023, Номер 56, С. 104585 - 104585

Опубликована: Ноя. 21, 2023

Язык: Английский

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Carbonate radicals mediated catalytic degradation of antibiotics over earth-abundant BaCO3-based system: Performance, mechanism and calculation

Journal of Alloys and Compounds, Год журнала: 2024, Номер 1004, С. 175687 - 175687

Опубликована: Июль 23, 2024

Язык: Английский

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Enhancing catalytic ozonation activity of aluminum oxide via fluorine-doping engineering for water purification

Separation and Purification Technology, Год журнала: 2023, Номер 330, С. 125383 - 125383

Опубликована: Окт. 28, 2023

Язык: Английский

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Construction of Z-scheme Fe3O4/BiOBr/BiOI heterojunction with magnetically recyclable for enhanced photocatalytic reaction activity

Process Safety and Environmental Protection, Год журнала: 2024, Номер 210, С. 382 - 392

Опубликована: Сен. 3, 2024

Язык: Английский

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Constructing novel inorganic-organic α-Fe2O3/SNW-1 Z-scheme heterojunction for Methylene Blue photodegradation

Journal of Solid State Chemistry, Год журнала: 2023, Номер 327, С. 124242 - 124242

Опубликована: Авг. 2, 2023

Язык: Английский

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Polyaniline-derived nitrogen-doped carbon/MoS2 nanocomposites as cathode for efficient hybrid capacitive deionization

Environmental Engineering Research, Год журнала: 2023, Номер 29(2), С. 230204 - 0

Опубликована: Июль 10, 2023

Molybdenum disulfide (MoS2) has become an attractive faradic material for capacitive deionization (CDI) process, but it still suffers from several drawbacks, such as low electrical conductivity, inferior hydrophilicity and easy restacking. Hence, we integrated MoS2 with high nitrogen content carbonized polyaniline (MoS2/CP) intercalation cathode CDI. The disordered entanglement between CP nanosheets enlarged interlayer spacing, improved pore structure surface area which can provide multiple charge transfer routes endow more embedding sites to storage Na+. Mo-N-C bonds improve the conductivity wettability facilitate ions diffusion process well ensure cyclic stability of composites electrode. Moreover, Na+ N-containing functional groups is beneficial forming pseudo-capacitance. Accordingly, MoS2/CP electrode possess a large specific capacitance 99.1 F g-1 at 5 mV s-1, 36% higher than MoS2. hybrid cell AC//MC-2 delivers remarkable desalination capacity (29.14 mg g-1), rapid rate (2.9 min-1) favorable durability 1.2 V in 500 L-1 NaCl solution. superior performance was evaluated based on capacitance-controlled contribution 85.8% diffusion-controlled 14.2%.

Язык: Английский

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Multi-functional energy conversion by strongly coupled Ag3PO4/ZIF-67 heterostructures

Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(2), С. 112283 - 112283

Опубликована: Март 1, 2024

Язык: Английский

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Construction of N-doped 2D TiO2/MoS2 S-scheme heterojunction for enhanced photodegradation activity by rhodamine B

Reaction Kinetics Mechanisms and Catalysis, Год журнала: 2024, Номер unknown

Опубликована: Авг. 10, 2024

Язык: Английский

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Promoting •OH-dominant Fenton-like process over peracetic acid activation by ultrafine FeOx nanoclusters anchored carbonaceous nanosheets

Fundamental Research, Год журнала: 2023, Номер unknown

Опубликована: Май 1, 2023

Peracetic acid (PAA) has recently been considered a promising oxidant candidate for heterogeneous Fenton-like reactions; however, the main generation and contribution of organic radicals (R-O•) with unsatisfactory oxidation potential compromises wastewater decontamination efficiency. In this study, we demonstrate rational design synthesis ultrafine FeOx nanocluster-anchored carbonaceous nanosheets (UFe-CN) altering PAA activation pathway from R-O• to •OH dominant process via in situ framework collapse carbonization MIL-53(Fe). The constructed UFe-CN/PAA system effectively accelerated refractory micropollutant (e.g., p-nitrophenol (4-NP)) decomposition by enhanced formation (up 65.24 μmol L− 1) under wide pH range (3.0–9.0), outperforming benchmark iron-based catalyst counterparts 4.2–10.8 times. This outstanding catalytic activity UFe-CN is primarily attributed significant improvement electron mitigation, ca. 49 times higher than that its MIL-53(Fe) counterpart, interface catalysis reactions triggered iron species cycling. Furthermore, facilitate adaptive engineering, pollutant removal efficiency could be easily tuned varying several key treatment factors, including initial pH, concentration, dosage. More importantly, excellent practicality was demonstrated systematically evaluating impact water matrix, regeneration capability, Overall, study provides understanding •OH-dominated an effective development paradigm practical application PAA-based oxidation.

Язык: Английский

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