Review on strategies for improving the added value and expanding the scope of CO₂ electroreduction products

Chemical Society Reviews, Год журнала: 2024, Номер 53(10), С. 5149 - 5189

Опубликована: Янв. 1, 2024

This review summarizes promising strategies including the design of catalysts and construction coupled electrocatalytic reaction systems, aimed at achieving selective production various products from CO 2 electroreduction.

Язык: Английский

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Urea Electrosynthesis Accelerated by Theoretical Simulations

Advanced Functional Materials, Год журнала: 2023, Номер 34(14)

Опубликована: Дек. 27, 2023

Abstract Urea is not only a primary fertilizer in modern agriculture but also crucial raw material for the chemical industry. In past hundred years, prevailing industrial synthesis of urea heavily relies on Bosch–Meiser process to couple NH 3 and CO 2 under harsh conditions, resulting high carbon emissions energy consumption. The conversion carbon‐ nitrogen‐containing species into through electrochemical reactions ambient conditions represents sustainable strategy. Despite increasing reports electrosynthesis, comprehensive review that delves profound, atomic‐level comprehension fundamental reaction mechanisms currently absent. this Perspective, recent advancements from /CO various nitrogenous (i.e., N , NO x − NO) are presented, with special emphasis theoretical understanding C─N coupling mechanisms. Several key strategies facilitate then pinpointed, which enhance their applicability practical experiments highlight significant progress achieved field. At end, major obstacles potential opportunities advancing electrosynthesis accelerated by simulations situ techniques discussed. This hoped act as roadmap ignite fresh insights inspiration development electrocatalytic synthesis.

Язык: Английский

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Defect and interface engineering for promoting electrocatalytic N-integrated CO2 co-reduction

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Год журнала: 2024, Номер 57, С. 1 - 17

Опубликована: Фев. 1, 2024

Язык: Английский

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Single and double transition metal atoms doped graphdiyne for highly efficient electrocatalytic reduction of nitric oxide to ammonia

Journal of Colloid and Interface Science, Год журнала: 2023, Номер 656, С. 155 - 167

Опубликована: Ноя. 10, 2023

Язык: Английский

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Highly efficient and selective electrosynthesis of urea via co-reduction of carbon dioxide and nitrate over the TiN catalyst

Chemical Engineering Journal, Год журнала: 2024, Номер 486, С. 150178 - 150178

Опубликована: Март 5, 2024

Язык: Английский

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Electrocatalytic Synthesis of Urea: An In‐depth Investigation from Material Modification to Mechanism Analysis

Small, Год журнала: 2024, Номер 20(43)

Опубликована: Июнь 27, 2024

Abstract Industrial urea synthesis production uses NH 3 from the Haber‐Bosch method, followed by reaction of with CO 2 , which is an energy‐consuming technique. More thorough evaluations electrocatalytic C−N coupling are needed for development process, catalyst design, and underlying mechanisms. However, challenges adsorption activation reactant suppression side reactions still hinder its development, making systematic review necessary. This meticulously outlines progress in electrochemical utilizing different nitrogen (NO − N NO O) carbon (CO CO) sources. Additionally, it delves into advanced methods materials such as doping, facet engineering, alloying, vacancy introduction. Furthermore, existing classes catalysts clearly defined, include 2D nanomaterials, Mott–Schottky structure, artificially frustrated Lewis pairs, single−atom (SACs), heteronuclear dual−atom (HDACs). A comprehensive analysis benefits, drawbacks, latest developments modern detection techniques discussed. It aspired that this will serve a valuable reference subsequent designs highly efficient electrocatalysts strategies to enhance performance synthesis.

Язык: Английский

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N2 reduction to NH3 on surfaces of Co-Al18P18, Ni-Al21N21, Fe-B24N24, Mn-B27P27, Ti-C60 and Cu-Si72 catalysts

Journal of Molecular Modeling, Год журнала: 2024, Номер 30(3)

Опубликована: Фев. 7, 2024

Язык: Английский

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Benzohydroxamic acid adsorption on the surface of scheelite: New insights from experiments and AIMD simulations

Applied Surface Science, Год журнала: 2024, Номер 663, С. 160180 - 160180

Опубликована: Апрель 27, 2024

Язык: Английский

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Screening of transition metal and boron atoms co-doped graphdiyne catalysts for electrocatalytic urea synthesis

Journal of Colloid and Interface Science, Год журнала: 2023, Номер 655, С. 80 - 89

Опубликована: Ноя. 2, 2023

Язык: Английский

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Advances in Electrocatalytic Urea Synthesis: From Fundamentals to Applications

Advanced Powder Materials, Год журнала: 2024, Номер unknown, С. 100245 - 100245

Опубликована: Окт. 1, 2024

Язык: Английский

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