Microchimica Acta, Год журнала: 2024, Номер 191(11)
Опубликована: Окт. 28, 2024
Язык: Английский
Microchimica Acta, Год журнала: 2024, Номер 191(11)
Опубликована: Окт. 28, 2024
Язык: Английский
Nature Communications, Год журнала: 2025, Номер 16(1)
Опубликована: Фев. 25, 2025
Cryptochiral compounds are indispensable in biology systems and medical applications, yet the development of high-performance detection method remains challenging. Here, we report a hinge-like dinuclear Pt(II) complex as stereodynamic probe for cryptochirality sensing. This features constrained, closed conformation achieved through synergistic intramolecular π − stacking metal-metal interactions between cyclometalated wings. The shows robust chiroptical response to center-to-axial chiral induction during rapid condensation with cryptochiral that adopts more energetically favorable conformation. resulting intense Cotton effects at long wavelengths enable in-situ circular dichroism analysis determinate absolute configuration enantiometric composition molecules. Furthermore, near-infrared phosphorescence characteristics hinge have been explored develop it an optical sensor accurate quantification With its dual CD capabilities, this great potential high-throughput screening analysis. authors complexes probes
Язык: Английский
Процитировано
1Sensors and Actuators B Chemical, Год журнала: 2024, Номер 423, С. 136753 - 136753
Опубликована: Окт. 13, 2024
Язык: Английский
Процитировано
8Talanta, Год журнала: 2024, Номер 282, С. 126972 - 126972
Опубликована: Сен. 28, 2024
Язык: Английский
Процитировано
4Analytical Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Янв. 15, 2025
Arginine (Arg) is involved in tissue metabolism and regulates the immune function; thereby, achieving detection of Arg crucial for early diagnosis treatment diseases. Herein, dual ratiometric fluorescence sensors were prepared with blue emission levorotatory/dextrorotatory carbon dots (CDs) red porphyrin (L/D-CDs-PP) sensitive portable Arg. Interestingly, L-CDs-PP D-CDs-PP displayed not only peaks at 493 650 nm but also different response modes to Arg; thus, they could serve as achieve accurate reliable Arg, limit 23.87 μM 2.39 D-CDs-PP. Importantly, solid-state successfully achieved dual-mode visual support a smartphone platform. In addition, exhibited excellent biocompatibility cell imaging capabilities, cells biological samples urine rat plasma. Therefore, broad application prospects fields analytical sensing, imaging, medical diagnosis.
Язык: Английский
Процитировано
0Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162592 - 162592
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2025, Номер unknown, С. 136969 - 136969
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0Separation and Purification Technology, Год журнала: 2024, Номер unknown, С. 129852 - 129852
Опубликована: Сен. 1, 2024
Язык: Английский
Процитировано
1Sensors and Actuators B Chemical, Год журнала: 2024, Номер 423, С. 136765 - 136765
Опубликована: Окт. 11, 2024
Язык: Английский
Процитировано
1Scientia Sinica Chimica, Год журнала: 2024, Номер 54(8), С. 1289 - 1307
Опубликована: Май 28, 2024
圆偏振发光(CPL)材料凭借其独特的光物理特性, 在3D显示、防伪、生物成像、不对称催化等领域展现出巨大的应用潜力. 通常, 手性和发光组分的同时存在是实现CPL的必要条件. 螺旋取代聚炔的手性放大效应赋予其强烈的光学活性, 且主链的动态螺旋结构使其具有刺激响应性, 因而在构筑 CPL材料方面具有显著的优势. 本文依据手性和发光组分之间相互作用方式的不同, 系统地综述了螺旋取代聚炔CPL材料的构筑方法和手性光学性能, 并介绍了其在手性传感、防伪和光电器件方面的应用. 最后, 探讨了该领域当前的挑战和未来的发展前景.
Процитировано
0