Molecules, Год журнала: 2024, Номер 29(24), С. 6063 - 6063

Опубликована: Дек. 23, 2024

As a key means to solve energy and environmental problems, photocatalytic technology has made remarkable progress in recent years. Organic semiconductor materials offer structural diversity tunable levels thus attracted great attention. Among them, porphyrin its derivatives show potential reactions light therapy due their unique large-π conjugation structure, high apparent quantum efficiency, tailorable functionality, excellent biocompatibility. Compared unassembled molecules, supramolecular assemblies facilitate the solar absorption improve charge transfer exhibit enhanced performance. Herein, research of porphyrin-based assemblies, including construction, regulation separation transfer, stability, application photocatalysis, was systematically reviewed. The construction strategy supramolecules, mechanism separation, intrinsic relationship assembling structure-charge transfer-photocatalytic performance received special Surfactants, peptide polymers, metal ions were introduced stability assemblies. Donor-acceptor structure co-catalysts incorporated inhibit recombination photoinduced charges. These increase understanding supramolecules provide ideas for design high-performance photocatalysts.

Язык: Английский