Solid State Sciences, Год журнала: 2025, Номер unknown, С. 107993 - 107993
Опубликована: Май 1, 2025
Язык: Английский
Solid State Sciences, Год журнала: 2025, Номер unknown, С. 107993 - 107993
Опубликована: Май 1, 2025
Язык: Английский
Journal of Colloid and Interface Science, Год журнала: 2025, Номер 691, С. 137458 - 137458
Опубликована: Март 30, 2025
Язык: Английский
Процитировано
1ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown
Опубликована: Май 15, 2025
Utilizing metal-organic frameworks (MOFs) to facilitate the formation of AgI and construct novel heterojunction material is a promising strategy for water remediation. However, achieving strong connections at active sites MOFs improving charge transfer processes remain challenge. Herein, we proposed Zn-driven approach anchor on Zn-doped NH2-MIL-125(Ti) (ZTNML), which exhibited 6.7 times 5.3 higher imidacloprid degradation efficiencies than that NH2-MIL-125(Ti), respectively. Density functional theory calculations revealed Zn in ZTNML played critical role anchoring AgI, facilitated by I- adsorption Ag+ binding. This unique Zn-I interaction significantly enhanced from promoting separation photogenerated electron-hole pairs through Z-scheme mechanism, induced both difference work functions interfacial interactions. As derived Fukui function analysis liquid chromatography-mass spectrometry (LC-MS) data, potential pathway driven superoxide radicals singlet oxygen species was proposed. Furthermore, QSAR modeling employed predict toxicity intermediates, providing an assessment environmental safety. Our converts heavy metal ions while constructing heterojunctions efficiently eliminating organic pollutants, sustainable protection.
Язык: Английский
Процитировано
0Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2025, Номер unknown, С. 136770 - 136770
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0Solid State Sciences, Год журнала: 2025, Номер unknown, С. 107993 - 107993
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0