Molecules,
Год журнала:
2024,
Номер
29(21), С. 5172 - 5172
Опубликована: Окт. 31, 2024
Biomass-derived
carbon
materials
(BDCs)
are
highly
regarded
for
their
renewability,
environmental
friendliness,
and
broad
potential
application.
A
significant
advantage
of
these
lies
in
the
high
degree
customization
physical
chemical
properties,
especially
terms
pore
structure.
Pore
engineering
is
a
key
strategy
to
enhance
performance
BDCs
critical
areas,
such
as
energy
storage,
catalysis,
remediation.
This
review
focuses
on
engineering,
exploring
definition,
classification,
adjustment
techniques
structures,
well
how
factors
affect
application
energy,
Our
aim
provide
solid
theoretical
foundation
practical
guidance
facilitate
rapid
transition
from
laboratory
industrial
applications.
Energy Science & Engineering,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 14, 2025
ABSTRACT
The
increasing
demand
for
sustainable
fuels
has
driven
extensive
research
into
biodiesel
production,
which
typically
relies
on
the
use
of
active
catalysts
to
facilitate
transesterification
oils.
While
homogeneous
are
commonly
employed,
they
pose
challenges
in
terms
recyclability
and
environmental
impact,
leading
growing
interest
heterogeneous
catalysts.
Among
these,
metal‐organic
frameworks
(MOFs)
have
gained
attention
due
their
high
surface
area
tuneable
properties.
This
study
investigates
performance
a
copper
benzene‐
1
,
3
5
‐tricarboxylate
(CuBTC)
MOF
as
an
effective
catalyst
production.
CuBTC
was
synthesised
via
solvothermal
method
thoroughly
characterised
using
scanning
electron
microscopy
examine
morphology,
powder
X‐ray
diffraction
determine
crystalline
structure,
Fourier
transform
infrared
spectroscopy
identify
functional
groups.
octahedral
morphology
successfully
catalysed
production
with
unsaturated
fatty
acids
within
C
16
18
range,
achieving
yield
78.6%
wt.%
10:1
methanol‐to‐oil
molar
ratio.
iodine
value
produced
59.3
g
I/g,
higher
heating
39.2
MJ/kg.
Recycled
maintained
its
efficacy,
yielding
76.6%
63.4%
acid
methyl
esters
first
second
recycling
runs,
respectively,
16.6%
15.3%
acids.
met
quality
standards
outlined
EN
14214,
highlighting
CuBTC's
potential
Energies,
Год журнала:
2023,
Номер
16(2), С. 844 - 844
Опубликована: Янв. 11, 2023
The
environmental
impact
of
traditional
fuels
and
related
greenhouse
gas
emissions
(GHGE)
has
promoted
policies
driven
towards
renewable
fuels.
This
review
deals
with
green
diesel,
a
biofuel
obtained
by
catalytic
deoxygenation
edible
non-edible
biomasses.
Green
biodiesel,
petrodiesel
are
compared,
diesel
being
the
best
option
in
terms
physical–chemical
properties
reduction
GHGE.
process
types
catalysts,
feedstocks,
operating
conditions
presented.
Reactor
configurations
also
discussed,
summarizing
experimental
studies.
Several
simulations
economic
analyses—up
to
larger
scales—are
gathered
from
literature
that
analyze
potential
as
substitute
for
petrodiesel.
In
addition,
current
industrial
processes
production
introduced.
Future
research
development
efforts
should
concern
catalysts
use
waste
biomasses
feedstock,
well
arrangement
national
international
policies.
