New Journal of Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
The
widespread
accumulation
of
antibiotic
pollutants
in
water
sources
calls
for
advanced
and
efficient
remediation
strategies
to
curb
environmental
contamination.
Advanced Energy Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Авг. 13, 2024
Abstract
The
rational
design
of
a
photocatalyst
and
its
microenvironmental
modulation
is
crucial
in
the
heterogeneous
photocatalysis
process,
yet
relevant
research
on
photocatalytic
biodiesel
synthesis
not
explored.
Herein,
based
prediction
density
functional
theory
(DFT)
calculations,
highly
efficient
ternary
biocompatible
montmorillonite
(Mt)
nanocomposites
S‐scheme
heterojunction
photocatalysts
(g‐C
3
N
4
‐TiO
2
@Mt,
CTM)
are
successfully
rationally
designed.
By
modulating
microenvironment
production,
CTM‐2
demonstrates
exceptional
catalytic
performance
stability,
achieving
record‐breaking
yield
98.5%.
Through
ex/in
situ
X‐ray
photoelectron
spectroscopy
(XPS),
absorption
near‐edge
(XANES),
theoretical
formation
revealed,
which
can
generate
an
interface
electric
field
(IEF)
that
provides
intrinsic
driving
force
for
carrier
migration
enhances
surface
positivity.
This
boosts
enrichment
effect
electronegative
oleic
acid
(OA)
carboxyl
molecules,
thus
greatly
enriching
substrate
concentration
improving
reaction
microenvironment.
Moreover,
fourier
transform
infrared
spectrometer
(FT‐IR)/Raman
together
with
electron
paramagnetic
resonance
(EPR)
further
confirm
key
intermediates
CH
O•
ester
carbonyl
(C═O),
DFT
calculations
provide
reference
pathway,
determined
to
be
capable
significantly
reducing
energy
barrier
rate‐determining
step.
Inorganic Chemistry Frontiers,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
This
summary
describes
and
elucidates
an
enhanced
strategy
for
photocatalytic
nitrogen
fixation
over
Bi
2
MO
6
(M
=
Mo,
W)-based
catalysts
points
out
the
development
prospects
of
fixation.