Catalytic Conversion of Carbon Dioxide to Propylene Carbonate: Catalyst Design and Industrialization Progress
Jun Wu,
Yaxuan Du,
Xiejun Wang
и другие.
ACS Catalysis,
Год журнала:
2025,
Номер
unknown, С. 1305 - 1340
Опубликована: Янв. 7, 2025
Converting
CO2
into
valuable
chemicals
is
an
effective
way
to
alleviate
the
high
level
of
global
CO2.
The
cycloaddition
reaction
and
propylene
oxide
(PO)
has
atomic
economy
advantage
environmental
friendliness
compared
with
traditional
phosgene
method
carbonate
(PC).
Due
chemical
inertness
CO2,
catalysts
are
needed
make
proceed
smoothly.
Through
rational
design,
a
multifunctional
catalyst
that
combines
activation
sites
attack
PO
adsorption
can
be
formed.
At
same
time,
use
harmful
substances
reduced
by
making
catalytic
process
more
environmentally
friendly.
In
this
work,
we
discuss
research
progress
synthesis
PC
from
PO.
Starting
mechanism,
system
summarized
perspective
design.
homogeneous
catalysts,
focus
on
effect
composition
performance.
heterogeneous
heterogenization
(preparation
methods),
including
supported,
confined,
polymerized
catalysts.
addition,
promising
photocatalysis
biomass
catalysis
especially
introduced.
Finally,
in
order
experimental
results
move
toward
industrial
production,
several
problems
existing
industrialization
discussed,
production
equipment,
influence
source,
product/catalyst
separation.
Язык: Английский
Guanidine-functionalized basic binuclear poly(ionic liquid)s for low partial pressure CO2 fixation into cyclic carbonate
Separation and Purification Technology,
Год журнала:
2024,
Номер
339, С. 126682 - 126682
Опубликована: Фев. 5, 2024
Язык: Английский
Enhanced photoelectric performance of ZnFe2O4 catalysts for oxidative carboxylation of styrene by tuning crystal planes and thermal and electrical conductivity
Journal of Cleaner Production,
Год журнала:
2024,
Номер
440, С. 141002 - 141002
Опубликована: Янв. 29, 2024
Язык: Английский
Bottom-up fabrication of DABCO-based bicationic ionic liquid-grafted MIL-101(Cr): Facilitating simultaneous activation of CO2 and epoxides for cyclic carbonate synthesis
Separation and Purification Technology,
Год журнала:
2024,
Номер
354, С. 128851 - 128851
Опубликована: Июль 20, 2024
Язык: Английский
The embedding of 1,8-diazabicyclo[5.4.0]undec-7-ene into hyper-crosslinked ionic polymers for efficient CO2 conversion at atmospheric pressure
Separation and Purification Technology,
Год журнала:
2024,
Номер
unknown, С. 130148 - 130148
Опубликована: Окт. 1, 2024
Язык: Английский
C4C recent developments: carbonaceous-supported catalysts for CO2 conversion into cyclic carbonates
Carbon Research,
Год журнала:
2025,
Номер
4(1)
Опубликована: Фев. 17, 2025
Abstract
The
conversion
of
CO
2
into
value-added
chemicals
and
fuels
is
one
the
potential
approaches
to
deal
with
environmental
issues
caused
by
increasing
carbon
dioxide
concentration
in
atmosphere.
can
be
transformed
a
variety
valuable
products,
including
but
not
limited
monoxide,
cyclic
carbonates,
formic
acid,
methanol,
methane,
ethanol,
acetic
propanol,
light
olefins,
aromatics,
gasoline
through
thermal
catalysis,
electrocatalysis,
photo(electro)catalysis.
In
ongoing
search
for
new
catalytic
conversions,
utilization
carbon-based
materials
as
catalyst
supports
demonstrates
improvement
performance.
This
because
unique
features
carbonaceous
supports,
such
tunable
porous
structure,
high
specific
surface
area,
good
chemical
stability,
excellent
conductivity.
Though
there
are
other
strategies
chemicals,
cycloaddition,
methanation,
hydrogenation,
photocatalysis,
five-membered
carbonates
has
garnered
significant
attention
its
address
concerns
reduce
reliance
on
fossil
fuels;
however,
it
faces
considerable
challenges
due
thermodynamic
stability
.
To
these
issues,
this
review
particularly
presents
recent
advancements
fixation
carbonate
using
carbonaceous-supported
systems
viz.
graphitic
nitride,
graphene,
nanotubes,
nanofiber,
activated
carbon,
sphere,
that
provide
advantages
structures,
areas,
stability.
Furthermore,
easily
modified
introducing
defects
or
heteroatoms
enhance
their
provides
information
current
research,
development
trends,
necessary
path
expedite
technological
technologies
terms
materials,
various
experimental
conditions
employed
reactions.
important
role
molecular
process
modeling
implementing
at
commercial
scale
also
highlighted.
aims
demonstrate
catalysts
improve
efficiency
production,
thereby
contributing
more
sustainable
processes.
Graphical
Язык: Английский
Non-stoichiometric protic ionic liquids for efficient carbon dioxide capture and subsequent conversion under mild conditions
Separation and Purification Technology,
Год журнала:
2024,
Номер
354, С. 129302 - 129302
Опубликована: Авг. 23, 2024
Incorporation of Mg/Al metal oxide into ionic liquids for CO2 capture and conversion into cyclic carbonate under solvent-free conditions: effect of coordination ability, recyclability, and catalytic study
Green Chemical Engineering,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 1, 2024
Язык: Английский
Non-Stoichiometric Protic Ionic Liquids for Efficient Carbon Dioxide Capture and Subsequent Conversion Under Mild Conditions
Опубликована: Янв. 1, 2024
Язык: Английский
Construction of a Binary Organocatalytic System Based on Urea-Based Hydrogen Bond Donors and Polyether Ionic Liquids and its Application to CO<sub>2</sub> Cycloaddition Reactions
Materials science forum,
Год журнала:
2024,
Номер
1138, С. 49 - 54
Опубликована: Дек. 17, 2024
To
alleviate
the
environmental
problems
caused
by
excessive
emission
of
CO
2
,
this
study
designed
and
synthesized
a
binary
organocatalytic
system
based
on
urea-based
hydrogen
bond
donors
polyether
ionic
liquids
cycloaddition
reaction
that
converts
small-molecule
epoxides
into
cyclic
carbonates
with
high
industrial
application
value.
The
is
liquid,
introducing
an
organic
base
(to
trap
activate
),
donor
epoxide),
nucleophilic
reagent
unit
help
open
ring
epoxides),
variety
active
sites.
In
paper,
effects
as
well
structure
activity
were
investigated,
optimal
HBD/Lewis
catalytic
was
established,
cycle
life
tested.
Язык: Английский