Food Chemistry X,
Год журнала:
2024,
Номер
23, С. 101760 - 101760
Опубликована: Авг. 24, 2024
The
recycling
of
fruit
peel
resources
is
a
current
research
hotspot.
This
study
screened
and
configured
composite
extractant
consisting
chemical
through
extraction
experiments
explored
the
heavy
metals(HMs)
release
effect.
results
showed
that
Scientific Reports,
Год журнала:
2024,
Номер
14(1)
Опубликована: Июль 30, 2024
The
development
of
nanomaterials
incorporating
organic
components
holds
significant
importance
in
addressing
the
efficient
removal
metal
ions
through
adsorption.
Hence,
this
study,
a
novel
MnFe2O4/chitosan/Schiff
base
nanocomposite
was
successfully
synthesized
by
crosslinking
MnFe2O4
nanoparticles
with
functionalized
chitosan
using
Schiff
base.
created
condensation
reaction
between
2-aminophenol
and
terephthalaldehyde.
Comprehensive
characterization
performed
FT-IR,
XRD,
SEM,
VSM
analyses,
revealing
less
crystalline
arrangement
compared
to
pure
chitosan,
rough
non-uniform
surface
morphology,
reduced
magnetization
value
30
emu/g.
Furthermore,
working
as
an
adsorbent
for
effective
disposal
Zn(II)
from
aqueous
solutions.
exhibited
maximum
sorption
capacity
289.86
mg/g
ions.
Additionally,
results
indicated
that
spontaneous,
chemical,
endothermic
process,
aligning
well
Langmuir
isotherm
pseudo-second-order
model.
at
pH
7.5,
contact
duration
100
min
temperature
328
K,
fabricated
reached
its
study
demonstrate
effectiveness
newly
removing
media.
synthesis
approach
high
adsorption
underscore
potential
composite
practical
applications
industrial
wastewater
treatment.
dual
mechanism
involving
electrostatic
attraction
complexation
processes
further
enhances
utility,
making
it
valuable
contribution
field
environmental
remediation.
Separation Science and Technology,
Год журнала:
2024,
Номер
unknown, С. 1 - 20
Опубликована: Окт. 9, 2024
Three
grades
of
allyl-mannitol
cross-linker-based
hydrogel
(AMCLHs
hydrogel)
have
been
synthesized
with
the
help
acrylic
acid
and
acrylamide
monomers
using
a
free
radical
co-polymerization
technique.
The
three
prepared
AMCLHs
referred
to
as
AMCLHs-1,
AMCLHs-2,
AMCLHs-3,
respectively.
hydrogels
characterized
by
several
analytical
techniques
viz.
Fourier
transform
infrared
(FTIR)
spectroscopy,
thermogravimetric
(TG)
analysis,
point
zero
charge
(ΔpHPZC),
scanning
electron
microscope
(SEM)
utilized
for
elimination
Cu2+
Co2+
ions
from
wastewater.
properties
hydrogels,
i.e.
swelling
water
retention
ratio
studied
in
distilled
under
optimized
conditions.
maximum
best
grade
(AMCLHs-1)
has
found
be
400.5
g/g
75.09%
during
24
h.
These
findings
indicate
AMCLHs-1
remarkable
capacity.
metal
ion
removal
efficiency
aqueous
solutions
96.6%
94.2%
optimum
experimental
data
fitted
well
Langmuir
Freundlich
adsorption
models,
revealing
capacities
431.03
mg/g
414.93
ions,
In
addition,
rate
onto
follows
both
Pseudo
first
second-order
kinetic
models.
negative
ΔG
values
that
process
occurs
spontaneously,
while
positive
ΔH
suggest
is
exothermic
nature.
reusable
exhibits
high
desorption
87.63%
85.21%
even
after
fourth
cycle.
Overall,
cost-effective
adsorbent
possesses
significant
potential
heavy
solutions.
For
sustainable
development,
wastewater
treatment
and
recycling
are
inevitable;
using
adsorbents
to
treat
is
widely
accepted.
This
article
aimed
synthesize
(novel
biochars)
from
agricultural
wastes
investigate
the
adsorption
behaviours
of
Pb(II)
Cd(II)
on
novel
biochars.
Nitrogen
purged
biochar
(NPBC)
was
synthesized
by
pyrolysis
with
nitrogen
purgation
wheat
straw;
whereas,
steam
activated
(SABC)
pyrolysis-cum-hydrothermal
(steam)
activation.
Synthesized
NPBC
SABC
were
characterized
physical,
chemical,
XRD,
FTIR,
SEM–EDX
methods.
more
porous
amorphous
in
nature
higher
specific
surface
area
(SSA),
but
consisted
relatively
less
polar
functional
groups
than
that
NPBC.
The
external
layer
both
negatively
charged
(pH
>
pHPZC).
Results
revealed
exhibited
97%
80%
recovery
efficiency
Cd(II),
respectively,
while
demonstrated
removal
efficiencies
87.6%
69.4%,
at
initial
concentrations
50
5
mg
L−1.
Adsorption
upon
occurred
spontaneously,
also
exothermically,
decreased
increased
reaction
temperature.
maximum
capacities
(qmax)
for
452.13
1117
g−1,
whereas
those
314.9
470.43
according
Langmuir
isotherm
approach
(R2
0.989).
So,
performed
better
removing
metals
wastewater.
Both
exhibit
substantial
prospects
regeneration
consequent
adsorbent
recovery.
Hence,
designed
can
be
very
effective
towards
cationic
toxic
heavy
metal