Industrial & Engineering Chemistry Research,
Год журнала:
2024,
Номер
63(28), С. 12277 - 12287
Опубликована: Июль 5, 2024
Chemical
chain
extenders
(CEs)
can
be
used
to
restore
the
properties
of
recycled
low-molecular-weight
polyethylene
terephthalate
(PET).
The
aim
this
work
is
investigate
influence
type
and
concentration
CEs
Joncryl
pyromellitic
dianhydride
(PMDA)
on
viscosity
other
rheological
with
a
unique
combination
different
methods
based
industrial
samples
originating
from
PET
bottles
trays.
resulting
chain-extended
thermoplastics
were
characterized
by
differential
scanning
calorimetry,
viscometry,
cone
plate
rheometry,
pyrolysis─gas
chromatography─mass
spectroscopy,
optical
photothermal
infrared
13C
solid-state-
1H
NMR
liquid
size
exclusion
chromatography.
For
mixture
containing
bottle
tray
materials,
our
investigations
have
shown
that
significantly
better
effect
for
elongation
achieved
compared
PMDA.
This
presumably
attributed
water
molecules
formed
during
use
PMDA,
which
accelerate
degradation
PET.
storage
modulus
values
are
therefore
higher
results
study
show
extension
proceeds
reaction
Current Opinion in Green and Sustainable Chemistry,
Год журнала:
2023,
Номер
40, С. 100763 - 100763
Опубликована: Фев. 4, 2023
One
of
the
main
environmentally
threatening
factors
is
plastic
waste
which
generates
in
great
quantity
and
causes
severe
damage
to
both
inhabitants
environment.
Commonly,
generated
on
land
ends
up
water
bodies,
resulting
detrimental
solid
impacts
aquatics
via
poisoning
flooding
marine
ecosystem.
Exploring
various
approaches
convert
wastes
into
new
products
known
as
an
efficient
way
manage
them
enhance
sustainability
environment,
discussed
this
article.
Moreover,
limitation
application
for
construction
purposes
also
considered.
It
wind
that
usage
will
significantly
rectify
our
environment
be
regarded
a
trustworthy
source
materials
applying
conventional
such
concrete
asphalt.
Case Studies in Chemical and Environmental Engineering,
Год журнала:
2024,
Номер
9, С. 100673 - 100673
Опубликована: Фев. 23, 2024
It
is
difficult
to
reuse
wastes
from
polymers
due
the
mismatch
between
amount
of
contaminants
and
secondary
quality
feed.
This
type
operation
much
more
expensive
cost-effective
than
production
polymer
raw
materials
latest
materials.
However,
recyclable
beneficial
if
used
extensively
in
various
concrete
products
wood-polymer
boards.
done
only
cleaning
sorting
are
not
particularly
important
for
products.
Polyethylene
terephthalate
(PET)
a
widely
industries
its
excellent
physical
chemical
properties.
Besides,
increasing
use
PET
has
led
global
crisis
waste
management,
as
improper
disposal
caused
significant
environmental
damage.
major
source
accumulated
landfills,
address
this
issue,
recycling
methods
have
evolved.
In
regard,
present
review
examines
techniques
involved
PET.
Conventional
influence
diverse
depolymerization
reaction
variables
were
discussed,
upsides
downsides
each
technique
considered.
The
summarizes
advances
technologies
plastic
waste,
focusing
on
bio-recycling
PET,
aiming
sustainable,
economical
solutions
circular
economy.
Polymers,
Год журнала:
2022,
Номер
14(15), С. 3133 - 3133
Опубликована: Июль 31, 2022
The
excessive
amount
of
global
plastic
produced
over
the
past
century,
together
with
poor
waste
management,
has
raised
concerns
about
environmental
sustainability.
Plastic
recycling
become
a
practical
approach
for
diminishing
and
maintaining
sustainability
among
management
methods.
Chemical
mechanical
are
typical
approaches
to
waste,
simple
process,
low
cost,
environmentally
friendly
potential
profitability.
Several
materials,
such
as
polypropylene,
polystyrene,
polyvinyl
chloride,
high-density
polyethylene,
low-density
polyurethanes,
can
be
recycled
chemical
approaches.
Nevertheless,
due
waste’s
varying
physical
properties,
separation
becomes
challenge.
Hence,
reliable
effective
technology
is
critical
increasing
value
rate.
Integrating
technologies
would
an
efficient
method
reducing
accumulation
contaminants
by
especially
in
industrial
uses.
This
review
addresses
recent
advances
technology,
mainly
recycling.
article
also
discusses
current
various
materials.
Polymer Composites,
Год журнала:
2022,
Номер
43(9), С. 5831 - 5862
Опубликована: Авг. 20, 2022
Abstract
This
review
article
discusses
the
environmental
and
economic
effects
of
recycling,
as
well
sustainable
thermoplastic
polymer
recycling
technologies.
Several
researchers
have
utilized
recycled
thermoplastics
matrices
in
production
a
variety
natural
synthetic‐based
composites,
which
is
also
focus
this
study.
All
industries
(food
packaging,
construction
building,
transportation,
indoor
usage)
where
large
market
share
are
covered
review.
The
desirable
properties
polymers,
such
corrosion
resistance,
low
density,
user‐friendliness,
caused
plastic
to
surpass
aluminum
other
metals
use
over
past
60
years.
Furthermore,
one
most
important
measures
available
mitigate
these
dynamic
segments
plastics
industry
at
present.
Increased
landfilling
incineration
negative
impact
on
ecosystem,
continued
increase
virgin
fossil
has
environment.
Consequently,
continuous
could
lead
depletion
fuel
resources,
an
emissions
during
processing,
eventual
incineration.
Increasing
numbers
nations
adopting
circular
economy
concept
effort
avoid
all
problems.
emphasizes
reuse
products
materials
according
waste
hierarchy,
rather
than
their
cremation
or
disposal
Polymers,
Год журнала:
2023,
Номер
15(19), С. 3881 - 3881
Опубликована: Сен. 25, 2023
The
concept
of
the
circular
economy
has
emerged
as
a
promising
solution
to
address
mounting
concerns
surrounding
plastic
waste
and
urgent
need
for
sustainable
resource
management.
While
conventional
centralized
recycling
remains
common
practice
waste,
facilities
may
prove
inadequate
in
handling
ever-increasing
volumes
generated
globally.
Consequently,
exploring
alternative
methods,
such
distributed
by
additive
manufacturing,
becomes
paramount.
This
innovative
approach
encompasses
actively
involving
communities
practices
promotes
economy.
comprehensive
review
paper
aims
explore
critical
aspects
necessary
realize
potential
manufacturing.
In
this
paper,
our
focus
lies
on
proposing
schemes
that
leverage
existing
literature
harness
manufacturing
an
effective
We
intricacies
process,
optimize
3D
printing
parameters,
challenges,
evaluate
mechanical
properties
recycled
materials.
Our
investigation
draws
heavily
from
last
five
years,
we
conduct
thorough
assessment
DRAM
implementation
its
influence
structures.
Through
analysis,
reveal
materials
delivering
functional
components,
with
insights
into
their
performance,
strengths,
weaknesses.
serves
guide
those
interested
embracing
transformative
recycling.
By
fostering
community
engagement,
optimizing
processes,
incorporating
suitable
additives,
it
is
possible
collectively
contribute
more
future
while
combatting
crisis.
As
progress
made,
essential
further
delve
complexities
material
behavior,
techniques,
long-term
durability
printed
components.
addressing
these
challenges
head-on,
feasible
refine
advance
viable
pathway
minimize
cultivating
cleaner
planet
generations
come.
Molecules,
Год журнала:
2023,
Номер
28(5), С. 2344 - 2344
Опубликована: Март 3, 2023
The
assessment
of
the
extent
degradation
polymer
molecules
during
processing
via
conventional
(e.g.,
extrusion
and
injection
molding)
emerging
additive
manufacturing;
AM)
techniques
is
important
for
both
final
material
performance
with
respect
to
technical
specifications
circularity.
In
this
contribution,
most
relevant
(thermal,
thermo-mechanical,
thermal-oxidative,
hydrolysis)
mechanisms
materials
are
discussed,
addressing
extrusion-based
manufacturing,
including
mechanical
recycling,
AM.
An
overview
given
experimental
characterization
techniques,
it
explained
how
these
can
be
connected
modeling
tools.
Case
studies
incorporated,
dealing
polyesters,
styrene-based
materials,
polyolefins,
as
well
typical
AM
polymers.
Guidelines
formulated
in
view
a
better
molecular
scale
driven
control.