Polymers,
Год журнала:
2023,
Номер
15(11), С. 2525 - 2525
Опубликована: Май 30, 2023
This
research
examines
the
impact
of
self-polymerized
polydopamine
(PDA)
coating
on
mechanical
properties
and
microstructural
behavior
polylactic
acid
(PLA)/kenaf
fiber
(KF)
composites
in
fused
deposition
modeling
(FDM).
A
biodegradable
FDM
model
natural
fiber-reinforced
composite
(NFRC)
filaments,
coated
with
dopamine
reinforced
5
to
20
wt.%
bast
kenaf
fibers,
was
developed
for
3D
printing
applications.
Tensile,
compression,
flexural
test
specimens
were
printed,
influence
content
their
assessed.
comprehensive
characterization
blended
pellets
printed
materials
performed,
encompassing
chemical,
physical,
microscopic
analyses.
The
results
demonstrate
that
acted
as
a
coupling
agent,
enhancing
interfacial
adhesion
between
fibers
PLA
matrix
leading
improved
properties.
An
increase
density
porosity
observed
PLA-PDA-KF
composites,
proportional
content.
enhanced
bonding
particles
contributed
an
up
13.4%
tensile
15.3%
Young's
modulus
30%
compressive
stress.
incorporation
agent
filament
led
improvement
tensile,
compressive,
stresses
strain
at
break,
surpassing
pure
PLA,
while
reinforcement
provided
by
more
delayed
crack
growth,
resulting
higher
break.
coatings
exhibit
remarkable
properties,
suggesting
potential
sustainable
material
diverse
applications
FDM.
Advanced Engineering Materials,
Год журнала:
2023,
Номер
25(21)
Опубликована: Авг. 29, 2023
Stimuli‐responsive
polymers
(SRPs)
are
special
types
of
soft
materials,
which
have
been
extensively
used
for
developing
flexible
actuators,
robots,
wearable
devices,
sensors,
self‐expanding
structures,
and
biomedical
thanks
to
their
ability
change
shapes
functional
properties
in
response
external
stimuli
including
light,
humidity,
heat,
pH,
electric
field,
solvent,
magnetic
field
or
combinations
two
more
these
stimuli.
In
recent
years,
additive
manufacturing
(AM)
aka
3D
printing
technology
SRPs,
also
known
as
4D
printing,
has
gained
phenomenal
attention
different
engineering
fields,
its
unique
develop
complex,
personalized,
innovative
undergo
twisting,
elongating,
swelling,
rolling,
shrinking,
bending,
spiraling,
other
complex
morphological
transformations.
Herein,
an
effort
made
provide
insightful
information
about
the
AM
techniques,
type
applications
including,
but
not
limited
tissue
engineering,
bionics,
construction,
smart
textiles.
This
article
incorporates
current
challenges
prospects,
hoping
basis
utilization
this
fields.
It
is
expected
that
amalgamation
with
SRPs
would
unparalleled
advantages
arenas.
International Journal of Biological Macromolecules,
Год журнала:
2023,
Номер
251, С. 126287 - 126287
Опубликована: Авг. 11, 2023
Cellulose
nanocrystals
(CNCs)
have
gained
significant
attraction
from
both
industrial
and
academic
sectors,
thanks
to
their
biodegradability,
non-toxicity,
renewability
with
remarkable
mechanical
characteristics.
Desirable
characteristics
of
CNCs
include
high
stiffness,
strength,
excellent
flexibility,
large
surface-to-volume
ratio.
Additionally,
the
properties
can
be
tailored
through
chemical
modifications
for
high-end
applications
including
tissue
engineering,
actuating,
biomedical.
Modern
manufacturing
methods
3D/4D
printing
are
highly
advantageous
developing
sophisticated
intricate
geometries.
This
review
highlights
major
developments
additive
manufactured
CNCs,
which
promote
sustainable
solutions
across
a
wide
range
applications.
this
contribution
also
presents
current
challenges
future
research
directions
CNC-based
composites
developed
techniques
myriad
engineering
sectors
wound
healing,
wearable
electronics,
robotics,
anti-counterfeiting
Overall,
will
greatly
help
scientists
chemistry,
materials,
biomedicine,
other
disciplines
comprehend
underlying
principles,
properties,
additively
structures.
Giant,
Год журнала:
2023,
Номер
17, С. 100209 - 100209
Опубликована: Ноя. 15, 2023
Additive
manufacturing
(AM)
aka
three-dimensional
(3D)
printing
has
been
a
well-established
and
unparalleled
technology,
which
is
expanding
the
boundaries
of
materials
science
exhibiting
an
enormous
potential
to
fabricate
intricate
geometries
for
healthcare,
electronics,
construction
sectors.
In
contemporary
era,
combination
AM
technology
stimuli-responsive
hydrogels
(SRHs)
helps
create
dynamic
functional
structures
with
extreme
accuracy,
are
capable
changing
their
shape,
functional,
or
mechanical
properties
in
response
environmental
cues
such
as
humidity,
heat,
light,
pH,
magnetic
field,
electric
etc.
3D
SRHs
permits
creation
on-demand
dynamically
controllable
shapes
excellent
control
over
various
self-repair,
self-assembly,
multi-functionality,
These
accelerate
researchers
think
unthinkable
applications.
Additively
manufactured
objects
have
shown
applications
like
tissue
engineering,
drug
delivery,
soft
robots,
sensors,
other
biomedical
devices.
The
current
review
provides
recent
progress
SRHs,
more
focus
on
techniques,
stimuli
mechanisms,
shape
morphing
behaviors,
Finally,
trends
future
roadmap
additively
smart
different
also
presented,
will
be
helpful
research.
This
holds
great
promise
providing
fundamental
knowledge
about
diverse
Giant,
Год журнала:
2024,
Номер
19, С. 100299 - 100299
Опубликована: Июнь 5, 2024
In
the
era
of
smart
and
sustainable
technology
driven
by
naturally
occurring
materials,
various
nanocellulose-based
materials
play
a
crucial
role.
Shape
memory
behaviour
self-healing
capabilities
nanocelluloses
are
emerging
as
focal
points
in
numerous
research
domains.
Nanocellulose
its
derivatives
such
cellulose
nanocrystals
(CNC)
nanofibers
(CNF),
currently
limelight
due
to
their
excellent
shape-memory
properties,
making
them
suitable
for
multifunctional
devices.
this
regard,
CNF,
cutting-edge
material,
has
spurred
researchers
explore
potential
developing
contemporary
personalized
health
Therefore,
timely
comprehensive
review
is
essential
gain
deep
insights
into
effectiveness
CNF
Herein,
we
first
provide
succinct
introduction
all
nanocellulose
materials.
This
also
depicts
recent
advancements
breakthroughs
large
effective
synthesis
CNF-based
hybrid
Next,
focusing
on
performance,
sheds
new
light
advanced
applications
Finally,
perspectives
current
challenges
opportunities
field
summarized
future
an
in-depth
understanding
"CNF-based
materials."
Solids,
Год журнала:
2022,
Номер
3(3), С. 508 - 548
Опубликована: Сен. 16, 2022
This
publication
summarises
the
current
state
of
knowledge
and
technology
on
possibilities
limitations
using
mineral
synthetic
fillers
in
field
3D
printing
thermoplastics.
FDM
can
be
perceived
as
a
miniaturised
variation
conventional
extrusion
processing
(a
microextrusion
process).
However,
scaling
process
down
has
an
undoubtful
drawback
significantly
reducing
extrudate
diameter
(often
by
factor
≈20–30).
Therefore,
results
produced
under
cannot
simply
translated
to
processes
run
with
application
technology.
With
that
mind,
discussing
latest
findings
composite
materials
preparation
was
necessary.
Journal of Materials Science Materials in Medicine,
Год журнала:
2023,
Номер
34(12)
Опубликована: Ноя. 20, 2023
Abstract
3D
printing
technology
is
an
emerging
method
that
gained
extensive
attention
from
researchers
worldwide,
especially
in
the
health
and
medical
fields.
Biopolymers
are
class
of
materials
offering
excellent
properties
flexibility
for
additive
manufacturing.
widely
used
biomedical
applications
biosensing,
immunotherapy,
drug
delivery,
tissue
engineering
regeneration,
implants,
devices.
Various
biodegradable
non-biodegradable
polymeric
considered
as
bio-ink
3d
printing.
Here,
we
offer
literature
review
on
current
synthetic
biopolymers
field
A
trend
publication
last
10
years
focused
by
analyzing
more
than
100
publications.
Their
application
classification
based
biodegradability
discussed.
The
various
studies,
along
with
their
practical
applications,
elaborated
subsequent
sections
polyethylene,
polypropylene,
polycaprolactone,
polylactide,
etc.
applications.
disadvantages
discussed,
future
perspectives
like
combating
biocompatibility
problems
using
printed
biomaterials
to
build
compatible
prosthetics
also
discussed
potential
resin
combination
customized
personalized
delivery
systems
organ
a
chip
technologies
expected
open
new
set
chances
development
healthcare
regenerative
medicine
future.
Graphical
Composites Part C Open Access,
Год журнала:
2023,
Номер
12, С. 100392 - 100392
Опубликована: Авг. 23, 2023
Tri-material
and
tri-layered
composites
find
numerous
applications
in
the
biomedical,
aerospace,
automotive
industries.
However,
such
face
challenges
when
fabricated
through
conventional
methods
(Electrospinning,
hand
lay-up,
Film
Casting,
In-situ
polymerization),
as
interface
bond
strength,
strength-to-mass
ratio,
etc.
Additive
manufacturing
can
be
used
to
fabricate
overcome
these
challenges.
In
this
study,
a
tri-material
based
3D-printed
(TM3DP)
polymer
composite
of
polylactic
acid
(PLA),
polyethylene
terephthalate
glycol
(PETG),
acrylonitrile
butadiene
styrene
(ABS)
was
successfully
processed
using
fused
filament
fabrication
(FFF)
for
first
time.
The
is
that
33.3%
PLA
printed
first,
followed
by
PETG,
and,
end,
ABS
so
PETG
sandwiched
between
ABS.
effect
FFF
processing
parameters
on
tensile
properties
investigated.
After
preliminary
experiments
literature
review,
infill
density
(ID),
printing
speed
(PS),
layer
thickness
(LT)
were
selected
main
parameters.
strength
(TS)
strain
(ℇ)
outputs
(responses)
study.
Tensile
testing
performed
after
samples
Instron
Universal
Testing
Machine
(5
KN).
An
analysis
variance
(ANOVA)
also
check
significance
process
results
concluded
significant
interaction
state
both
properties.
Scanning
electron
microscopy
(SEM)
optical
performed,
which
indicated
various
defects,
including
micropores,
voids,
micro
/
major
delamination
occurred
conditions
high
LT,
PS,
low
ID.
This
resulted
TS
27.1
MPa
ℇ
0.5
mm/mm.
No
defects
observed
under
ID,
highest
39.5
0.95.
Finally,
optimum
suggested
fabricating
thick
TM3DP
samples,
believed
enhance
ratio
16.4
%
compared
single
solid
base
materials.
Processes,
Год журнала:
2023,
Номер
11(3), С. 868 - 868
Опубликована: Март 14, 2023
Graphene
is
an
important
nanocarbon
nanofiller
for
polymeric
matrices.
The
polymer–graphene
nanocomposites,
obtained
through
facile
fabrication
methods,
possess
significant
electrical–thermal–mechanical
and
physical
properties
technical
purposes.
To
overcome
challenges
of
nanocomposite
processing
high
performance,
advanced
strategies
have
been
applied
to
design
the
next-generation
materials–devices.
This
revolutionary
review
basically
offers
a
fundamental
sketch
graphene,
three-dimensional
(3D)
four-dimensional
(4D)
printing
techniques.
main
focus
article
portray
impact
3D
4D
techniques
in
field
nanocomposites.
Polymeric
matrices,
such
as
polyamide,
polycaprolactone,
polyethylene,
poly(lactic
acid),
etc.
with
processed
using
or
technologies.
employ
various
cutting-edge
processes
offer
engineering
opportunities
meet
manufacturing
demands
nanomaterials.
methods
used
graphene
nanocomposites
include
direct
ink
writing,
selective
laser
sintering,
stereolithography,
fused
deposition
modeling
other
approaches.
Thermally
stable
acid)–graphene
oxide
technique.
3D-printed
poly(methyl
methacrylate)–graphene
printed
stereolithography
additive
revealed
enhanced
morphological,
mechanical
biological
properties.
polyethylene–graphene
by
diffusion
superior
thermal
conductivity,
strength,
modulus
radiation-
shielding
features.
number
approaches,
including
modeling,
etc.,
resulting
unique
honeycomb
morphology,
surface
temperature,
resistivity,
glass
transition
temperature
linear
coefficient.
has
on
acrylonitrile-butadiene-styrene,
acid)
thermosetting
matrices
nanofiller.
Stereolithography-based
4D-printed
nanomaterials
complex
shape-changing
nanostructures
having
resolution.
These
materials
stability
performance
applications.
Consequently,
3D-
applications
relevance,
photovoltaics,
sensing,
energy
storage
fields.
In
short,
this
paper
reviewed
background
printing,
graphene-based
3D–4D
development
technologies
printing.
European Polymer Journal,
Год журнала:
2024,
Номер
210, С. 112988 - 112988
Опубликована: Март 27, 2024
This
study
demonstrates
the
use
of
fused
filament
fabrication
(FFF)
4D
printing
(4DP)
to
print
programmable
continuous
fibre-reinforced
composite
(CFRC)
structures
with
exceptional
strength
and
eco-friendly
features.
research
focuses
on
bio-shape
memory
polymer
composites
(SMPCs)
employs
experiments
fabricate
lightweight
CFRC
parts
using
FFF
technology.
Different
types
fibres,
including
carbon
fibre
(CF),
aramid
(AF),
fibreglass
(FG),
are
incorporated
into
a
biopolymer
matrix
made
biodegradable
polylactic
acid
(PLA).
The
evaluates
microstructure,
mechanical
properties,
shape
properties
SMPCs,
employing
techniques
like
cold
hot
programming.
Continuous
fibres
significantly
enhance
increasing
by
over
1027.5
%
in
tensile
tests
nearly
497.3
three-point
bending
tests.
also
addresses
recovery
fixity
ratios
4D-printed
finding
decrease
when
PLA.
Notably,
FGPLA
specimens
achieve
highest
ratio
approximately
95
±
1
after
pure
These
findings
highlight
potential
CFRCs
various
applications,
from
human-material
interaction
biomedical
fields.
They
contribute
sustainability
reducing
material
consumption
waste,
demonstrated
through
creation
reusable
items
hooks,
lockers,
finger
splints,
meta-composites.