Polymers,
Год журнала:
2023,
Номер
15(11), С. 2525 - 2525
Опубликована: Май 30, 2023
This
research
examines
the
impact
of
self-polymerized
polydopamine
(PDA)
coating
on
mechanical
properties
and
microstructural
behavior
polylactic
acid
(PLA)/kenaf
fiber
(KF)
composites
in
fused
deposition
modeling
(FDM).
A
biodegradable
FDM
model
natural
fiber-reinforced
composite
(NFRC)
filaments,
coated
with
dopamine
reinforced
5
to
20
wt.%
bast
kenaf
fibers,
was
developed
for
3D
printing
applications.
Tensile,
compression,
flexural
test
specimens
were
printed,
influence
content
their
assessed.
comprehensive
characterization
blended
pellets
printed
materials
performed,
encompassing
chemical,
physical,
microscopic
analyses.
The
results
demonstrate
that
acted
as
a
coupling
agent,
enhancing
interfacial
adhesion
between
fibers
PLA
matrix
leading
improved
properties.
An
increase
density
porosity
observed
PLA-PDA-KF
composites,
proportional
content.
enhanced
bonding
particles
contributed
an
up
13.4%
tensile
15.3%
Young's
modulus
30%
compressive
stress.
incorporation
agent
filament
led
improvement
tensile,
compressive,
stresses
strain
at
break,
surpassing
pure
PLA,
while
reinforcement
provided
by
more
delayed
crack
growth,
resulting
higher
break.
coatings
exhibit
remarkable
properties,
suggesting
potential
sustainable
material
diverse
applications
FDM.
SPE Polymers,
Год журнала:
2024,
Номер
5(2), С. 228 - 240
Опубликована: Фев. 20, 2024
Abstract
Additive
manufacturing
(AM)
has
revolutionized
the
industry
by
enabling
fabrication
of
complex
geometries
and
designs
with
ease.
3D
printing—fused
deposition
modeling
(FDM)
emerged
as
a
prevalent
technique,
owing
to
its
versatility
cost‐effectiveness.
However,
FDM
process
is
depends
on
multiple
parameters,
which
makes
it
challenging
obtain
high‐quality
consistent
printed
components.
The
purpose
this
study
simplify
printing
for
users
potentially
improve
overall
quality
consistency
objects.
This
research
delved
into
optimising
specifically
raster
orientation
in‐fill
speed,
PLA
material
through
three
experimental
studies.
mean
effect
these
parameters
effects
their
interaction
analysis
variance
(ANOVA)
tensile
properties
were
also
discussed.
Initial
experiments
identified
most
suitable
optimal
values
PLA,
then
applied
five
different
materials:
PETG,
tough,
Recycle
Plain
ABS.
Tensile
tests
assessed
parts,
scanning
electron
microscopy
(SEM)
was
employed
analyze
fracture
interfaces
failure
causes.
45°/−45°
30
mm/s
infill
speed
diverse
materials.
Notably,
ABS,
tough
exhibited
better
strengths,
surpassing
manufacturer
benchmarks.
Recycled
despite
lower
proved
valuable
specific
applications.
Interestingly,
all
tested
materials
showed
greater
flexibility
than
recommendations,
suggesting
suitability
in
scenarios
needing
both
strength
flexibility.
study's
results
offer
promising
avenues
refining
practices,
advantage
users.
findings
from
significant
insights
future
investigate
other
leading
further
advancements
AM.
Highlights
Optimised
parameters.
Applicability
optimised
settings
extended
across
various
exceeded
benchmarks
strength.
Experimental
ANOVA
are
good
agreement,
revealing
ACS Applied Polymer Materials,
Год журнала:
2023,
Номер
5(6), С. 4034 - 4044
Опубликована: Май 5, 2023
Fused
filament
fabrication
(FFF)
has
been
extensively
studied
for
conventional
polymers,
but
there
are
few
studies
that
address
the
processing
challenges
biobased,
biodegradable
polymers
such
as
poly(lactic
acid)
(PLA)
and
poly(hydroxy
alkenoates)
(PHA)
in
FFF
processes.
This
study
investigated
elongational
shear
rheological
properties
thermophysical
characteristics
of
PLA/PHA
hybrid
materials
to
determine
effects
conditions,
including
nozzle
temperatures,
bed
speeds,
on
quality
printed
products,
e.g.,
adhesion
strength
tensile
properties.
Our
findings
showed
adding
PHA
composition
material
leads
a
reduction
extensional
viscosities,
causing
rise
elongation
at
break
while
showing
comparable
with
PLA
samples.
In
addition
presence
combination
materials,
temperature,
print
speed,
were
found
be
effective
products.
results
suggested
among
parameters,
temperature
most
significant
effect
characteristics.
Samples
215
°C
an
order
magnitude
higher
up
34%
enhancement
compared
samples
185
°C.
sheds
light
significance
parameters
obtaining
products
from
polymers.
Polymers,
Год журнала:
2023,
Номер
15(21), С. 4219 - 4219
Опубликована: Окт. 25, 2023
Additive
manufacturing
(AM,
aka
3D
printing)
is
generally
acknowledged
as
a
“green”
technology.
However,
its
wider
uptake
in
industry
largely
relies
on
the
development
of
composite
feedstock
for
imparting
superior
mechanical
properties
and
bespoke
functionality.
Composite
materials
are
especially
needed
polymer
AM,
given
otherwise
poor
performance
most
parts
load-bearing
applications.
As
drawback,
shift
from
mono-material
to
may
worsen
environmental
footprint
AM.
This
perspective
aims
discuss
this
chasm
between
advantage
embedding
advanced
functionality,
disadvantage
causing
harm
environment.
Fused
filament
fabrication
(FFF,
fused
deposition
modelling,
FDM)
analysed
here
case
study
account
unparalleled
popularity.
FFF,
which
belongs
material
extrusion
(MEX)
family,
presently
widespread
AM
technique
industrial,
educational,
recreational
On
one
hand,
FFF
has
already
transitioned
“from
lab
fab”
finally
community,
with
far-reaching
implications
sustainability.
other
thermoplastic-based,
hence
highly
amenable
recycling.
The
literature
shows
that
recycled
thermoplastic
such
poly(lactic
acid)
(PLA),
acrylonitrile-butadiene-styrene
(ABS),
polyethylene
terephthalate
(PET,
or
glycol-modified
form
PETG)
can
be
used
printing
by
printed
objects
when
they
at
end
life.
Reinforcements/fillers
also
obtained
materials,
help
valorise
waste
by-products
wide
range
industries
(for
example,
paper,
food,
furniture)
agriculture.
Increasing
attention
being
paid
recovery
carbon
fibres
aviation),
reuse
glass
fibre-reinforced
polymers
end-of-life
wind
turbines).
Although
technical
challenges
economical
constraints
remain,
adoption
recycling
strategies
appears
essential
limiting
impact
reducing
depletion
natural
resources,
cutting
down
volume
mitigating
dependency
petrochemicals.
Polymer Composites,
Год журнала:
2024,
Номер
45(8), С. 6741 - 6770
Опубликована: Фев. 29, 2024
Abstract
Solid
composites
used
in
material
extrusion
additive
manufacturing
have
experienced
considerable
expansion
over
the
past
5
years,
incorporating
functional
properties
into
3D‐printed
objects.
This
paper
presents
a
systematic
review
that
aims
to:
(I)
analyze
current
state
of
development
field;
(II)
quantify
and
categorize
adopted
polymeric
matrices,
reinforcing
materials,
feedstock
shapes,
characterization
strategies,
mechanisms;
(III)
identify
applications,
limitations,
trends
for
future
research.
The
PRISMA
statement
was
followed
databases
Scopus,
Web
Science,
PubMed
were
consulted.
Among
116
included
studies,
use
customized
filaments
surpassed
commercially
available
ones,
with
particulate
matter
being
most
common
form
filler
when
melt‐mixed
polymer.
Polyamide
is
widely
matrix
(30.3%),
by
PLA
(22.0%)
ABS
(17.4%).
In
terms
reinforcements,
carbon
fiber
(32.4%),
glass
(12.5%),
ceramics
(12.5%)
compose
podium
as
frequently
used,
nanofillers
receiving
increasing
attention.
conducted
analysis,
no
standardized
protocols
identified
clearly
encompassed
entire
process
from
formulation
to
technical
prototype
fabrication.
At
last,
recycling,
exploration
biodegradable
4D
printing
main
opportunities
Highlights
Reinforced
polymers
enable
enhancement
parts.
Composite
usually
formulated
mixed
before
printing.
3D
printers
filament‐
or
screw‐based
mechanisms
been
used.
Mechanical
morphological
analyses
are
characterization.
No
applications
employed
real‐world
scenarios.
Biosensors,
Год журнала:
2022,
Номер
12(8), С. 568 - 568
Опубликована: Июль 26, 2022
Breast
cancer
is
the
second
most
common
worldwide,
characterized
by
a
high
incidence
and
mortality
rate.
Despite
advances
achieved
in
management,
improvements
quality
of
life
breast
survivors
are
urgent.
Moreover,
considering
heterogeneity
that
characterizes
tumors
patients,
focusing
on
individuality
fundamental.
In
this
context,
3D
printing
(3DP)
4D
(4DP)
techniques
allow
for
patient-centered
approach.
At
present,
3DP
applications
against
focused
three
main
aspects:
treatment,
tissue
regeneration,
recovery
physical
appearance.
Scaffolds,
drug-loaded
implants,
prosthetics
have
been
successfully
manufactured;
however,
some
challenges
must
be
overcome
to
shift
clinical
practice.
The
introduction
fourth
dimension
has
led
an
increase
degree
complexity
customization
possibilities.
However,
4DP
still
early
stages;
thus,
research
needed
prove
its
feasibility
healthcare
applications.
This
review
article
provides
overview
current
approaches
including
standard
treatments
reconstruction
strategies.
benefits
limitations
technologies
discussed,
as
well
their
application
fight
cancer.
Future
perspectives
outlined
encourage
promote
AM
real-world
Advanced Functional Materials,
Год журнала:
2022,
Номер
33(6)
Опубликована: Дек. 9, 2022
Abstract
In
recent
years,
4D
printing
has
allowed
the
rapid
development
of
new
concepts
multifunctional/adaptive
structures.
The
technology
makes
it
possible
to
generate
shapes
and/or
property‐changing
capabilities
by
combining
smart
materials,
multiphysics
stimuli,
and
additive
manufacturing.
Hygromorphs
constitute
a
specific
class
materials
where
their
properties
morphing
are
dependent
on
surrounding
humidity,
which
drives
actuation.
Although
multiple
efforts
have
been
made
fabricate
hygromorph
demonstrators,
comprehensive
design
process
produce
hygromorphs
techniques
is
not
yet
available.
broad
aim
this
review
concept
paper
i)
highlight
existing
scientific
gaps
in
field
4D‐printed
hygromorphs,
ii)
identify
tools
other
research
fields
for
filling
those
gaps,
iii)
discuss
series
guidelines
tackling
future
challenges
opportunities
develop
composite
related
manufacturing
processes.
Accordingly,
describes
used
fabrication.
Moreover,
relevant
parameters
that
control
actuation,
models
selection
performance,
methods
actuation
measurements
customized
discussed.