Toward sustainable energy: Metal oxide semiconductor/MXene-based nanocomposite for the production of solar fuels
International Journal of Hydrogen Energy,
Год журнала:
2025,
Номер
109, С. 174 - 198
Опубликована: Фев. 11, 2025
Язык: Английский
2D/2D Hybrids: Re-visiting Interfacial Synthesis and Charge-Carrier Dynamics for Photocatalysis
Results in Engineering,
Год журнала:
2025,
Номер
unknown, С. 105045 - 105045
Опубликована: Май 1, 2025
Язык: Английский
Photocatalysis Fundamental with Essential Parameters for a Water Splitting Process
Kindnew Demssie Dejen,
Bui Hai Khue,
Arief Nugroho
и другие.
Green energy and technology,
Год журнала:
2025,
Номер
unknown, С. 1 - 62
Опубликована: Янв. 1, 2025
Язык: Английский
Unified Catalytic Performance of Assimilated Bimetallic Sulfide onto Niobium Carbide MXene for Overall Water Splitting
Advanced Sustainable Systems,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 3, 2025
Abstract
The
move
from
carbon
fuels
to
renewable
energy
is
accelerating
the
demand
for
efficient,
affordable
electrocatalysts.
MXenes
are
rapidly
budding
as
promising
candidates
advanced
carrier
and
storage
systems.
Ti‐based
have
been
widely
studied;
however,
their
conductivity
relatively
low
compared
niobium‐based
MXenes.
In
this
work,
etching
process
optimized
successfully
remove
Al
Nb
MAX
phase,
thereby
developing
a
well‐exfoliated
Nb‐MXene
(NbX).
Furthermore,
enhance
overall
electrochemical
performance,
novel
catalyst
introduced
by
depositing
nickel‐cobalt
sulfide
(NCS)
onto
NbX
(NCS@NbX)
improve
its
activity
both
oxygen
evolution
reaction
(OER)
hydrogen
(HER).
resulting
achieves
impressive
overpotentials
of
115
130
mV
in
0.5
m
H
2
SO
4
1
KOH
HER
OER,
respectively,
nearly
three
times
lower
than
values
observed
pristine
NbX.
Electrochemical
testing
further
reveals
Tafel
slopes
93
98
dec⁻¹
respectively.
also
exhibits
remarkable
stability
analyzed
with
help
chronoamperometry
testing,
maintaining
performance
over
40
h
acidic
20
basic
conditions,
highlighting
robustness.
Язык: Английский
Progress of MXene-Based Materials in the Field of Rechargeable Batteries
Materials,
Год журнала:
2025,
Номер
18(10), С. 2386 - 2386
Опубликована: Май 20, 2025
With
the
rapid
development
of
electrical
energy
storage
technologies,
traditional
battery
systems
are
limited
in
practical
applications
by
insufficient
density
and
short
cycle
life.
This
review
provides
a
comprehensive
critical
summary
MXene
or
MXene-based
composites
as
electrode
materials
for
high-performance
devices.
By
integrating
synthesis
techniques
MXenes
that
have
been
studied,
this
paper
systematically
illustrates
physicochemical
properties,
strategies,
mechanisms
MXenes,
analyzes
bottlenecks
their
large-scale
preparation.
Meanwhile,
it
collates
latest
research
achievements
field
metal–ion
batteries
recent
years,
focusing
on
progress
lithium–ion,
sodium–ion,
lithium–sulfur,
multivalent
ion
(Zn2+,
Mg2+,
Al3+)
batteries,
reveals
action
different
material
cases.
Combining
DFT
analysis
effects
surface
functional
groups
adsorption
with
experimental
studies
clarifies
structure–activity
relationships
composites.
However,
using
hybrid
compounds
remains
its
infancy.
Future
directions
should
focus
understanding
regulating
chemistry,
investigating
specific
electrodes,
exploring
developing
related
to
bimetallic
MXenes.
Язык: Английский
Exploring the structural and electronic properties of N-doped Ti2C MXenes for novel applications in advanced materials and devices: A DFT study
Materials Science in Semiconductor Processing,
Год журнала:
2024,
Номер
186, С. 109091 - 109091
Опубликована: Ноя. 7, 2024
Язык: Английский
Theoretical Study of Catalytic Performance of Pristine M2C and Oxygen-Functionalized M2CO2 MXenes as Cathodes for Li–N2 Batteries
ACS Applied Materials & Interfaces,
Год журнала:
2024,
Номер
16(26), С. 33710 - 33722
Опубликована: Июнь 21, 2024
Li–N2
batteries
are
a
promising
platform
for
electrochemical
energy
storage,
but
their
performance
is
limited
by
the
low
activity
of
cathode
catalysts.
In
this
work,
density
functional
theory
was
used
to
study
catalytic
pristine
M2C
and
oxygen-functionalized
M2CO2
MXenes
(M
=
Sc,
Ti,
V)
as
cathodes
batteries.
The
calculated
results
suggest
that
show
high
electrical
conductivity
due
Fermi
level
crossing
metal
3d
states.
stable
adsorption
N2
occurs
on
via
side-on
model
strengthens
gradually
with
decreasing
atomic
number.
Furthermore,
kinetics
dissociation
can
be
significantly
accelerated
coadsorption
Li
MXenes.
However,
surfaces
too
difficult
occur
strong
electrostatic
repulsion.
Li-mediated
nitrogen
reduction
reaction
during
discharge
proceeds
favorably
(N
+
N)*
→
(LiN
LiN)*
(Li2N
Li2N)*
(Li3N
Li3N)*
form
two
isolated
Li3N*
charge–discharge
overpotentials
decrease
in
order
Sc2C
<
Ti2C
V2C.
Notably,
MXene
has
great
potential
catalyst
because
its
conductivity,
adsorption,
favorable
dissociation,
ultralow
discharging,
charging,
total
(0.07,
0.06,
0.13
V).
This
offers
theoretical
foundation
future
research
Язык: Английский