Doping Si/O to enhance interfacial occupancy of demulsifiers for low‐carbon breaking of water‐in‐heavy oil emulsions DOI
Ying Tian,

Changqing He,

Xincheng Zhang

и другие.

AIChE Journal, Год журнала: 2024, Номер 71(3)

Опубликована: Ноя. 26, 2024

Abstract Separating water‐in‐heavy oil (W/HO) emulsions at low (room) temperature is challenging when exploiting heavy oil. We propose an adaptable strategy for constructing Si/O‐doped demulsifiers. A nonionic demulsifier (APBMP) has been synthesized based on polysiloxane modified by allyl polyether and butyl acrylate. APBMP achieves 95.97% dehydration within 5 min W/HO 288.15 K complete in 15 323.15 K. Mechanistic studies found that doping Si/O into the molecules increases number of hydrogen bond sites, which enables demulsifiers to quickly disperse natural stabilizers (e.g., asphaltenes) replace them oil–water interfacial film. The prefer occupy sites rather than dissolve bulk or water phases. Driven hydrogen‐bond‐dominated noncovalent interactions, film softened, reconstructed, broken. These findings provide insights developing novel materials separations a low‐carbon way.

Язык: Английский

Comprehensive review of stabilising factors, demulsification methods, and chemical demulsifiers of oil-water emulsions DOI
Xue Yang, Sijia Chen, Huiying Chen

и другие.

Separation and Purification Technology, Год журнала: 2024, Номер unknown, С. 130206 - 130206

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

13

Constructing oxygen-based multiple hydrogen bonding sites and delocalized π bonds for efficient oil-water-solid interfacial separation DOI
Xincheng Zhang,

Changqing He,

Mohamed M. Mostafa

и другие.

Journal of Hazardous Materials, Год журнала: 2025, Номер 490, С. 137766 - 137766

Опубликована: Фев. 27, 2025

Язык: Английский

Процитировано

1

Enhancing interfacial regulation by S/O co-doping for effective oil–solid and oil–water separation at room temperature DOI
Ying Tian,

Changqing He,

He Lin

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 131709 - 131709

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Reconfiguration of intermolecular hydrogen bond for viscosity reduction of heavy oil DOI
Huimin Zhou, Xueqian Liu,

Changqing He

и другие.

Chemical Engineering Science, Год журнала: 2025, Номер unknown, С. 121696 - 121696

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Efficient dewatering of water-in-shale oil emulsions by a newly branched demulsifier co-modified by phenoxy and carboxyl DOI
Xincheng Zhang, Mohamed M. Mostafa, Zhenyu Wang

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 133553 - 133553

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0

Esterified polyether demulsifier efficiently breaking water-in-heavy oil emulsions at low temperature DOI
Lulu Yan,

Xiao Xia,

Jun Ma

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 133678 - 133678

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0

A facile synthesis of low-temperature polyamine-based demulsifiers for the treatment of crude oil emulsions DOI
Yajun Zhao, Xiaotian Xu, Yulong Ding

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 133789 - 133789

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0

Understanding the demulsification of highly waxy shale oil emulsions by oxygen-rich demulsifiers DOI
Waseem Akram, Xincheng Zhang, Zhenyu Wang

и другие.

Fuel, Год журнала: 2025, Номер 401, С. 135766 - 135766

Опубликована: Июнь 2, 2025

Язык: Английский

Процитировано

0

Synthesis of a demulsifier with concentrated hydrogen bonding sites and its demulsification mechanism DOI

Zhan‐Ting Li,

Zhongyang Luo, Wentao Ma

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 133888 - 133888

Опубликована: Июнь 1, 2025

Язык: Английский

Процитировано

0

Doping Si/O to enhance interfacial occupancy of demulsifiers for low‐carbon breaking of water‐in‐heavy oil emulsions DOI
Ying Tian,

Changqing He,

Xincheng Zhang

и другие.

AIChE Journal, Год журнала: 2024, Номер 71(3)

Опубликована: Ноя. 26, 2024

Abstract Separating water‐in‐heavy oil (W/HO) emulsions at low (room) temperature is challenging when exploiting heavy oil. We propose an adaptable strategy for constructing Si/O‐doped demulsifiers. A nonionic demulsifier (APBMP) has been synthesized based on polysiloxane modified by allyl polyether and butyl acrylate. APBMP achieves 95.97% dehydration within 5 min W/HO 288.15 K complete in 15 323.15 K. Mechanistic studies found that doping Si/O into the molecules increases number of hydrogen bond sites, which enables demulsifiers to quickly disperse natural stabilizers (e.g., asphaltenes) replace them oil–water interfacial film. The prefer occupy sites rather than dissolve bulk or water phases. Driven hydrogen‐bond‐dominated noncovalent interactions, film softened, reconstructed, broken. These findings provide insights developing novel materials separations a low‐carbon way.

Язык: Английский

Процитировано

1