In-Situ Polymerization for Catalytic Graphitization of Boronated PAN Using Aluminum and Zirconium Containing Co-Catalysts
Inorganics,
Год журнала:
2025,
Номер
13(1), С. 16 - 16
Опубликована: Янв. 8, 2025
In-situ
polymerization
is
an
effective
method
for
integrating
co-catalysts
homogeneously
into
the
polymer
matrix.
Polyacrylonitrile
(PAN)-derived
highly
graphitized
carbon
a
state-of-the-art
material
with
diverse
applications,
including
materials
energy
storage
devices,
electrocatalysis,
sensing,
adsorption,
and
making
structural
composites
of
various
technologies.
Such
can
be
effectively
obtained
through
in-situ
polymerization.
The
addition
external
catalysts
during
not
only
enhances
rate
but
also
facilitates
degree
graphitization
quality
graphitic
upon
at
moderate
temperatures.
In
this
study,
we
apply
technique
to
integrate
aluminum
triflate
(Al(OTf)3)
zirconocene
dichloride
(C5H5)2ZrCl2
co-catalyst
boronated
polyacrylonitrile
(B-PAN)
ensures
uniform
distribution
without
aggregation,
facilitating
formation
well-ordered
structure
moderated
temperature.
Boronated
solutions,
(Al(OTf)3,
or
both)
were
prepared
process,
dried
in
oven,
then
subjected
1250
°C
heating
1
min−1
h
under
N2
atmosphere.
resulting
was
characterized
determine
impact
on
graphitization.
This
study
provides
valuable
insights
synthesizing
high-quality
materials,
offering
promising
pathways
their
scalable
production
strategic
use
co-catalysis.
These
have
potential
applications
fields,
environmental
technologies,
storage,
conversion,
pathway
design
facile
economical
materials.
Язык: Английский
Production of Bioderived Graphitizable Materials by Alternative Catalytic Processing: Technoeconomic Assessment and Upscaling Insights
ACS Sustainable Chemistry & Engineering,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 8, 2025
Язык: Английский
Co-pyrolysis of bamboo with low-dose guanidine phosphate to synthesise heteroatom-enriched porous carbon materials for supercapacitors
Journal of Analytical and Applied Pyrolysis,
Год журнала:
2025,
Номер
unknown, С. 107095 - 107095
Опубликована: Март 1, 2025
Язык: Английский
Utilizing Indonesian Empty Palm Fruit Bunches: Biochar Synthesis via Temperatures Dependent Pyrolysis
Nanomaterials,
Год журнала:
2024,
Номер
15(1), С. 50 - 50
Опубликована: Дек. 31, 2024
Biomass,
though
a
major
energy
source,
remains
underutilized.
Biochar
from
biomass
pyrolysis,
with
its
high
porosity
and
surface
area,
is
especially
useful
as
catalyst
support,
enhancing
catalytic
activity
reducing
electron
recombination
in
photocatalysis.
Indonesia,
the
world’s
top
palm
oil
producer,
generated
around
12
million
tons
of
empty
fruit
bunches
(EFBs)
2023,
making
EFBs
promising
biochar
source.
This
study
synthesizes
leftover
EFB
fibers
at
500,
800,
1000
°C,
analyzing
structural
changes
via
infrared
Raman
spectroscopy,
along
particle
size
area
analysis,
laying
groundwork
for
future
research.
The
smallest
highest
gained
was
71.1
nm
10.6
×
102
m2/g.
Spectroscopic
analysis
indicates
that
produced
°C
has
nano-crystalline
graphite
crystallite
approximately
5.47
nm.
provides
higher
defect
density,
although
lower
conductivity.
Other
studies
indicate
our
can
be
used
support
various
green
energy-related
applications,
i.e.,
counter
electrodes,
electrocatalysts,
photocatalysts.
Язык: Английский