Advancements in particle-reinforced high-entropy alloy coatings: microstructure, mechanical properties and mechanisms
Journal of Alloys and Compounds,
Год журнала:
2025,
Номер
unknown, С. 180787 - 180787
Опубликована: Май 1, 2025
Язык: Английский
Oxygen Evolution Enhancement of Bulk FeCoNiAlMo High-Entropy Alloy through Electrochemical Dealloying in ChCl-EG Deep Eutectic Solvent
Weijia Chen,
Changbin Hu,
J. Li
и другие.
Langmuir,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 31, 2025
High-entropy
alloys
(HEAs),
which
represent
a
new
type
of
multielement
alloys,
have
received
growing
research
as
potential
electrocatalytic
oxygen
evolution
reaction
(OER)
materials
because
their
excellent
catalytic
performances.
In
this
study,
the
FeCoNiAlMo
HEA
with
an
equal
atomic
ratio
was
used
precursor
to
form
three-dimensional
porous
structure
through
electrochemical
dealloying
in
choline
chloride
ethylene
glycol
(ChCl-EG).
At
current
density
10
mA
cm-2,
overpotential
alloy
reached
low
274
mV,
is
lower
than
that
commercial
RuO2-IrO2.
Furthermore,
after
long-term
electrolysis,
exhibited
performance
and
good
stability.
Moreover,
it
deduced
dual-phase
Fe20Co20Ni20Al20Mo20
mainly
composed
face-centered
cubic
(FCC)
body-centered
(BCC)
phases,
its
phase
distribution
morphology
similar
Turing
structure.
During
process,
owing
different
corrosion
resistances
elements
elemental
distributions
within
two
FCC
underwent
preferential
corrosion.
This
unique
synergistically
reduces
energy
barrier
during
water
dissociation,
imparting
material
significant
advantage
OER.
Язык: Английский
Influence of Laser Power on CoCrFeNiMo High-Entropy Alloy Coating Microstructure and Properties
Materials,
Год журнала:
2025,
Номер
18(11), С. 2650 - 2650
Опубликована: Июнь 5, 2025
This
work
studies
the
fabrication
of
CoCrFeNiMo
high-entropy
alloy
(HEA)
coatings
via
coaxial
powder-fed
laser
cladding,
addressing
porosity
and
impurity
issues
in
conventional
methods.
The
HEA
exhibited
eutectic/hypereutectic
microstructures
under
all
power
conditions.
A
systematic
investigation
effects
(1750–2500
W)
reveals
that
2250
W
optimizes
microstructure
performance,
yielding
a
dual-phase
structure
with
FCC
matrix
dispersed
σ
phases
(Fe-Cr/Mo-rich).
coating
achieves
exceptional
hardness
(738.3
HV0.2,
3.8×
substrate),
ultralow
wear
rate
(4.55
×
10−5
mm3/N·m),
minimized
corrosion
current
(2.31
10−4
A/cm2)
3.5
wt.%
NaCl.
friction
mechanism
is
high-speed
wear,
oxide
film
formed
on
surface
coating,
then
rupture
leads
to
adhesive
abrasive
wear.
galvanic
caused
by
potential
difference
between
phase
phase.
Язык: Английский