Progress on the Design of Electrocatalysts for Large‐Current Hydrogen Production by Tuning Thermodynamic and Kinetic Factors

Advanced Functional Materials, Год журнала: 2024, Номер 34(28)

Опубликована: Март 11, 2024

Abstract Electrochemical water splitting to produce green hydrogen offers a promising technology for renewable energy conversion and storage, as well realizing carbon neutrality. The efficiency, stability, cost of electrocatalysts toward evolution reaction (HER) electrocatalytic overall (EOWS) at large current densities are essential practical application. In this review, the key factors that determine catalytic performance summarized from angel thermodynamic kinetic correlation. corresponding design strategies presented. electronic structure density active sites affect adsorption/desorption intermediates considered aspects, while charge transfer mass transport capabilities closely associated with electrode resistance intermediate diffusion assigned effects. Recent development bifunctional integrated EOWS is also discussed in detail. Finally, perspective direction on under proposed. This comprehensive overview will offer profound insights guidance continued advancement field.

Язык: Английский

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Advances of layered double hydroxide electrocatalysts for high-current-density alkaline water/seawater splitting

Coordination Chemistry Reviews, Год журнала: 2024, Номер 510, С. 215832 - 215832

Опубликована: Март 28, 2024

Язык: Английский

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Growth in defects and surface area for the photocatalytic performance of GO-based Fe-doped bismuth oxide mesoporous nanocomposite

Ceramics International, Год журнала: 2024, Номер 50(7), С. 11179 - 11189

Опубликована: Янв. 3, 2024

Язык: Английский

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NiSe-modified CoMoO4 nanosheets as bifunctional electrocatalysts for hydrogen and oxygen evolution reactions

Journal of Alloys and Compounds, Год журнала: 2024, Номер 978, С. 173495 - 173495

Опубликована: Янв. 11, 2024

Язык: Английский

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Material Engineering Strategies for Efficient Hydrogen Evolution Reaction Catalysts

Small Methods, Год журнала: 2024, Номер unknown

Опубликована: Май 15, 2024

Abstract Water electrolysis, a key enabler of hydrogen energy production, presents significant potential as strategy for achieving net‐zero emissions. However, the widespread deployment water electrolysis is currently limited by high‐cost and scarce noble metal electrocatalysts in evolution reaction (HER). Given this challenge, design synthesis cost‐effective high‐performance alternative catalysts have become research focus, which necessitates insightful understandings HER fundamentals material engineering strategies. Distinct from typical reviews that concentrate only on summary recent catalyst materials, review article shifts focus to strategies developing efficient catalysts. In‐depth analysis approaches catalysts, such doping, vacancy defect creation, phase engineering, metal‐support are illustrated along with cases. A special emphasis placed designing metal‐free brief discussion advancements electrocatalytic water‐splitting technology. The also delves into important descriptors, reliable evaluation parameters characterization techniques, aiming link fundamental mechanisms its catalytic performance. In conclusion, it explores future trends integrating theoretical, experimental industrial perspectives, while acknowledging challenges remain.

Язык: Английский

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Advances in MXene-based single-atom catalysts for electrocatalytic applications

Coordination Chemistry Reviews, Год журнала: 2025, Номер 529, С. 216462 - 216462

Опубликована: Янв. 21, 2025

Язык: Английский

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Synthesis and characterization of bi-functional Cu and Ni co-doped ZnO photocatalysts for organic pollutant degradation and antimicrobial activity

Ceramics International, Год журнала: 2024, Номер 50(13), С. 24716 - 24724

Опубликована: Апрель 19, 2024

Язык: Английский

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Exploring progress in binary and ternary nanocomposites for photoelectrochemical water splitting: A comprehensive review

Coordination Chemistry Reviews, Год журнала: 2024, Номер 522, С. 216180 - 216180

Опубликована: Сен. 6, 2024

Язык: Английский

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Built-in electric field drives n-n heterojunction toward enhanced electrochemical freshwater and seawater oxidation

Applied Surface Science, Год журнала: 2024, Номер 657, С. 159777 - 159777

Опубликована: Фев. 24, 2024

Язык: Английский

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Construction of unique NiCoP/FeNiCoP hollow heterostructured ellipsoids with modulated electronic structure for enhanced overall water splitting

Journal of Colloid and Interface Science, Год журнала: 2024, Номер 666, С. 403 - 415

Опубликована: Март 30, 2024

Transition metal phosphides have been demonstrated to be promising non-noble catalysts for water splitting, yet their electrocatalytic performance is impeded by unfavorable free energies of adsorbed intermediates. The achievement nanoscale modulation in morphology and electronic states imperative enhancing intrinsic activity. Herein, we propose a strategy expedite the splitting process over NiCoP/FeNiCoP hollow ellipsoids modulating structure d-band center. These unique phosphorus (P) vacancies-rich are synthesized through an ion-exchange reaction between uniform NiCo-nanoprisms K

Язык: Английский

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