Unveiling the Mystery of Precision Catalysis: Dual‐Atom Catalysts Stealing the Spotlight DOI Open Access
Mengyang Zhang,

Xuchuan Cao,

Jie Dong

и другие.

Small, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

In the era of atomic manufacturing, precise manipulation structures to engineer highly active catalytic sites has become a central focus in catalysis research. Dual-atom catalysts (DACs) have garnered significant attention for their superior activity, selectivity, and stability compared single-atom (SACs). However, comprehensive review that integrates geometric electronic factors influencing DAC performance remains limited. This systematically explores structure DAC, addressing key macroscopic parameters, such as spatial arrangements interatomic distances, well microscopic factors, including local coordination environments structures. Additionally, metal-support interactions (MSI) long-range (LSI) are comprehensively analyzed, which play pivotal yet underexplored role governing behavior. integration tailored functional groups is further discussed fine-tune properties, thereby optimizing intermediate adsorption, enhancing reaction kinetics, expanding multifunctionality various electrochemical environments. offers novel insights into rational design by elucidating intricate mechanisms underlying DACs' exceptional performance. Ultimately, DACs positioned critical players precision catalysis, highlighting potential drive breakthroughs across broad spectrum applications.

Язык: Английский

Enhancing Water Electrolysis Performance by Bubble Behavior Management DOI Open Access

Jiaxuan Qiu,

Jiayi Yao, Yufeng Zhang

и другие.

Small Methods, Год журнала: 2025, Номер unknown

Опубликована: Фев. 16, 2025

Abstract Electrocatalytic water splitting for hydrogen generation plays a crucial role in promoting the energy transition and achieving goals of carbon neutrality. Nevertheless, context electrolysis, generated bubbles have an adverse impact on consumption mass transfer efficiency. To address this challenge, variety strategies are investigated to accelerate bubble detachment transport. It is utmost significance summarize those facilitating advancement electrolysis performance. In review, comprehensive account presented enhancing performance through behavior management. First, electrolyte discussed. Then, optimized interactions between electrode surface introduced, which focus reducing adhesion forces implementing other forces. Next, dynamic bubbling deformable catalysts discussed, such as fern‐ caterpillar‐like catalysts. Following that, bubble‐bubble coalescence proved be beneficial earlier departure compared buoyancy effect alone. Finally, outlooks future development efficient removal enhanced The review aims deepen comprehension stimulate management strategies, thereby further electrolysis.

Язык: Английский

Процитировано

1

Theoretical insight into the cooperative effect of transition metal dimer M1M2 (M1/M2 = Cu, Cr, Mn) and N for CO oxidation on modified graphene catalysts DOI

Teng-ge Mi,

Y.K. Zeng, Xiaodong Fang

и другие.

Surfaces and Interfaces, Год журнала: 2025, Номер unknown, С. 106266 - 106266

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Revealing the effect of sulfur doping in NiCo-layered double hydroxides for enhanced electrocatalytic water splitting and glucose sensing performance DOI
Chenhuinan Wei,

Yurun Hu,

Zitong Yang

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162216 - 162216

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Catalytic mechanism and biomedical applications of diatomic nanozymes DOI Open Access
Xiaonan Wang,

Lingjie Hou,

Mengyu Dang

и другие.

Microstructures, Год журнала: 2025, Номер 5(3)

Опубликована: Апрель 21, 2025

The diatomic nanozymes (DANs) represent a class of nanomaterials containing dual metals as active centers with enzyme-like activity inspired by natural enzymes. They hold unique catalytic properties caused their dual-atom structure, which have attracted significant attention. mechanism DANs may involve synergistic interactions between neighboring metal atoms and the regulation electron arrangement near center, enhancing specificity. excellent exceptional stability make promising candidates for developing sensitive biosensors capable precisely detecting disease markers. Furthermore, show great promise antitumor therapeutic agents, offering enhanced efficacy while minimizing side effects. This review outlines biomedical applications DANs. discussion section highlights challenges prospects in development DANs, insights future research endeavors this field.

Язык: Английский

Процитировано

0

Unveiling the Mystery of Precision Catalysis: Dual‐Atom Catalysts Stealing the Spotlight DOI Open Access
Mengyang Zhang,

Xuchuan Cao,

Jie Dong

и другие.

Small, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

In the era of atomic manufacturing, precise manipulation structures to engineer highly active catalytic sites has become a central focus in catalysis research. Dual-atom catalysts (DACs) have garnered significant attention for their superior activity, selectivity, and stability compared single-atom (SACs). However, comprehensive review that integrates geometric electronic factors influencing DAC performance remains limited. This systematically explores structure DAC, addressing key macroscopic parameters, such as spatial arrangements interatomic distances, well microscopic factors, including local coordination environments structures. Additionally, metal-support interactions (MSI) long-range (LSI) are comprehensively analyzed, which play pivotal yet underexplored role governing behavior. integration tailored functional groups is further discussed fine-tune properties, thereby optimizing intermediate adsorption, enhancing reaction kinetics, expanding multifunctionality various electrochemical environments. offers novel insights into rational design by elucidating intricate mechanisms underlying DACs' exceptional performance. Ultimately, DACs positioned critical players precision catalysis, highlighting potential drive breakthroughs across broad spectrum applications.

Язык: Английский

Процитировано

0