Oxide-modified bifunctional carbonaceous cathode: oxygen-rich alkaline-like microenvironment strengthened hydrogen peroxide as an electron donor to enhance Fe3+ reduction in Fe(III) electro-Fenton

Process Safety and Environmental Protection, Год журнала: 2025, Номер 196, С. 106847 - 106847

Опубликована: Фев. 7, 2025

Язык: Английский

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Genomic, Transcriptomic and Suspect/Non‐Target Screening Analyses Reveal the Role of CYP450s in the Degradation of Imazalil and Delineate Its Transformation Pathway by Cladosporium herbarum

Microbial Biotechnology, Год журнала: 2025, Номер 18(2)

Опубликована: Фев. 1, 2025

ABSTRACT Imazalil (IMZ), a major surface water contaminant characterised by high environmental recalcitrance and toxicity, is used in fruit‐packaging plants to control fungal infestations during storage. This leads the production of wastewaters which should be treated on site before their release. We previously isolated Cladosporium herbarum strain, first microorganism that could degrade IMZ. Here we describe genetic network utilised fungus IMZ its detailed transformation. Genomic transcriptomic analysis C. pointed involvement strongly upregulated CYP450s degradation, as further verified cessation biodegradation CYP450 inhibitors. LC‐QTOF‐HRMS suspect/non‐target screening identified nine transformation products (TPs) biotransformation mainly proceeded through O‐dealkylation, while other less important paths, most probably controlled oxidases, were operative involving successive hydroxylation reactions. These lead formation TPs like IMZ_313 IMZ_331, with former being transformed imidazole ring scission IMZ_288, TP reported for time. provide evidence mechanism potential genes/enzymes involved, paving way use biodepuration agro‐industrial effluents.

Язык: Английский

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Electro-Fenton process for the removal of Direct Red 23 using BDD anode in chloride and sulfate media

Journal of Electroanalytical Chemistry, Год журнала: 2021, Номер 897, С. 115560 - 115560

Опубликована: Июль 26, 2021

Язык: Английский

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Effective degradation of azo dye from textile wastewater by electro-peroxone process

Chemosphere, Год журнала: 2021, Номер 289, С. 133152 - 133152

Опубликована: Дек. 4, 2021

Язык: Английский

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Hydrogen peroxide generation from gas diffusion electrode for electrochemical degradation of organic pollutants in water: A review

Journal of environmental chemical engineering, Год журнала: 2022, Номер 10(3), С. 107882 - 107882

Опубликована: Май 12, 2022

Язык: Английский

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