Tetracycline degradation by dual-frequency ultrasound combined with peroxymonosulfate

Ultrasonics Sonochemistry, Год журнала: 2024, Номер 106, С. 106886 - 106886

Опубликована: Апрель 27, 2024

Tetracycline has received a great deal of interest for the harmful effects substance abuse on ecosystems and humanity. The different processes degradation tetracycline were compared, with dual-frequency ultrasound (DFUS) in combination peroxymonosulfate (PMS) being most effective degradation. Free radical scavenging experiments showed that O2∙-, SO4∙- •OH main reactive radicals tetracycline. According to major intermediates identified, three possible pathways proposed, which are significance translational studies Notably, these found be significantly less toxicity. number active bubbles vessel was calculated using semi-empirical formula, higher value 1.44 × 108 L-1s−1 obtained when at 20 kHz (210 W/L) 80 (85.4 W/L). Therefore, compared kHz, although yield strong oxidizing substances from individual decreased slightly, significant increment still resulted synergistic effect, DFUS PMS should promoting generation free mass transfer within vessel, provides method efficient removal wastewater.

Язык: Английский

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Facile synthesis of BiOI/BaNbO3 composite for rapid sonocatalytic degradation of tetracycline hydrochloride

Journal of Solid State Chemistry, Год журнала: 2024, Номер 333, С. 124644 - 124644

Опубликована: Фев. 27, 2024

Sonocatalysis, a vibration-induced chemical reaction, has shown great potential for catalytic applications. This study used water bath method to prepare BiOI/BaNbO3 composites with various mass ratios. Under the influence of sonocatalysis, BI/B-0.5 catalyst could degrade tetracycline hydrochloride up 96.5 % after 20 min, and stability was good. In comparison pure BiOI BaNbO3, reaction rate constants were found be 7.2 13.7 times higher, respectively. Furthermore, we systematically investigated sonocatalytic degradation effect on HTC under conditions. Finally, propose possible mechanism by composite catalyst. Our results underscore superior efficiency achieved catalyst, demonstrating its efficient removal organic pollutants.

Язык: Английский

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Exploring the dual role of BiVO4 nanoparticles: unveiling enhanced antimicrobial efficacy and photocatalytic performance

Journal of Sol-Gel Science and Technology, Год журнала: 2025, Номер unknown

Опубликована: Фев. 4, 2025

Язык: Английский

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Sonocatalytic performance of Bi2WO6 nanoparticles for degradation of tetracycline antibiotics

Applied Catalysis O Open, Год журнала: 2024, Номер 191, С. 206957 - 206957

Опубликована: Май 25, 2024

In this study, Bi2WO6 nanoparticles have been synthesized successfully via a facile hydrothermal method. The structure and morphology of materials were characterized by XRD, SEM, HRTEM, XPS, UV–vis DRS. sonocatalytic activities catalysts placed in sono-reactor (40 kHz 200 W) to investigate the degradation tetracycline antibiotics. effects parameters including ultrasonic power, catalyst dosage, initial concentration, pH values presence anions ions environment on (TC) studied optimize performance. Among all samples, sample E3 showed best activity (around 97%) TC within 120 min optimum conditions. A potentially mechanism was put forward based free radical entrapping experiment

Язык: Английский

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Machine learning predict the degradation efficiency of aqueous refractory organic pollutants by ultrasound-based advanced oxidation processes

Journal of Water Process Engineering, Год журнала: 2024, Номер 66, С. 106022 - 106022

Опубликована: Авг. 24, 2024

Язык: Английский

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Optimizing the UV-Fenton Degradation of m-Cresol Wastewater: An Experimental and Artificial Intelligence Modeling Approach

Industrial & Engineering Chemistry Research, Год журнала: 2024, Номер 63(2), С. 921 - 929

Опубликована: Янв. 6, 2024

Wastewater treatment, especially the efficient degradation of contaminants such as m-cresol, remains a pivotal challenge. This study investigates application artificial neural networks (ANN) in predicting total organic carbon (TOC) removal rates from m-cresol-contaminated wastewater by using ultraviolet (UV)-Fenton oxidation process. Six key variables, namely, Fe2+ dosage, H2O2 catalyst quantity, reaction time, pH, and substrate concentration, were employed inputs to ANN model. Leveraging this multivariable input comprehensive data set, model projected maximum TOC rate 87.12%, validated an efficiency 86.26% achieved through experiments under derived optimal conditions: dosage at 16.09 mg/L, 1.40 quantity 0.11 g/L, time 29.80 min, initial pH 3.66, concentration 50 mg/L. Comparative analysis with other machine learning algorithms further revealed that notably outperformed linear regression, support vector random forest terms precision. work paves way for resource-optimized experimental designs, fostering real-time monitoring refining advanced process proficiency industrial applications.

Язык: Английский

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Improved photocatalytic activation of PMS using Co-doped g-C3N4 composites for effective degradation of tetracycline: Catalyst performance, photogenerated carrier transfer and degradation mechanism

Materials Research Bulletin, Год журнала: 2024, Номер 182, С. 113132 - 113132

Опубликована: Окт. 6, 2024

Язык: Английский

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Palladium nanoparticles supported on biochar/graphitic carbon nitride as a heterogeneous catalyst for pharmaceutical degradation

Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(4), С. 113150 - 113150

Опубликована: Май 23, 2024

Язык: Английский

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A simple fabrication of pH-modified BiVO4 to enhance the degradation of tetracycline by peroxymonosulfate activation under simulated sunlight

Journal of environmental chemical engineering, Год журнала: 2025, Номер 13(1), С. 115320 - 115320

Опубликована: Янв. 5, 2025

Язык: Английский

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Electron Push-Pull Effect of Benzotrithiophene-Based Covalent Organic Frameworks on the Photocatalytic Degradation of Pharmaceuticals and Personal Care Products

Molecules, Год журнала: 2025, Номер 30(2), С. 336 - 336

Опубликована: Янв. 16, 2025

A covalent organic framework (COF) has emerged as a promising photocatalyst for the removal of pharmaceutical and personal care product (PPCP) contaminants; however, high-performance COF photocatalysts are still scarce. In this study, three were successfully synthesized by condensation benzo[1,2-b:3,4-b':5,6-b'']trithiophene-2,5,8-tricarbaldehyde (BTT) with 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TAPT), 1,3,5-Tris(4-aminophenyl)benzene (TAPB), 4,4',4''-nitrilotris(benzenamine) (TAPA), namely, BTT-TAPA, BTT-TAPB, BTT-TAPT, respectively. The surface areas BTT-TAPT found to be 800.46, 1203.60, 1413.58 cm2∙g-1, respectively, providing abundant active sites photocatalytic reactions. Under visible-light irradiation, exhibited highest rate tetracycline (TC), reaching 82.7% after 240 min. superior performance was attributed its large specific area strong electron-acceptor properties triazine group. Electron paramagnetic resonance capture experiments liquid chromatograph mass spectrometer analysis confirmed that superoxide radicals played pivotal role in degradation TC ciprofloxacin. Moreover, high stability reproducibility during process. This study confirms BTT-based COFs class PPCPs water, their can further optimized tuning structure composition frameworks.

Язык: Английский

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