Synergistic vacancy defects and bandgap engineering in an Ag/S co-doped Bi₂O₃-based sulfur oxide catalyst for efficient hydrogen evolution

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(17), С. 10494 - 10506

Опубликована: Янв. 1, 2024

Herein, an Ag/S co-doped Bi 2 O 3 -based sulfur oxide catalyst was prepared via a facile green method.

Язык: Английский

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Synergism of heterovalent valence state and oxygen vacancy defect engineering in Co/S co-doped TiO₂ for nitrogen photoreduction to ammonia

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(16), С. 9871 - 9885

Опубликована: Янв. 1, 2024

Herein, we demonstrate a Co/S co-doped TiO 2 bimetal sulfur oxide catalyst with heterovalent Co states and abundant oxygen vacancy defects for the photocatalytic nitrogen reduction reaction in an ambient environment.

Язык: Английский

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Synthesis and characterization of bi-functional Cu and Ni co-doped ZnO photocatalysts for organic pollutant degradation and antimicrobial activity

Ceramics International, Год журнала: 2024, Номер 50(13), С. 24716 - 24724

Опубликована: Апрель 19, 2024

Язык: Английский

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W/Br co-doped Zn(O,S) with Zn/O bi-vacancy defects and heterovalent states for enhanced photocatalytic hydrogen evolution

Materials Today Energy, Год журнала: 2025, Номер unknown, С. 101828 - 101828

Опубликована: Фев. 1, 2025

Язык: Английский

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A novel V/S co-doped BiOBr catalyst for high-efficiency catalytic reduction of toxic organic and hexavalent chromium pollutants under dark

Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(2), С. 112111 - 112111

Опубликована: Фев. 2, 2024

Язык: Английский

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Synthesis and characterization of Ce-BiOBr/Bi2S3 catalyst with enhanced catalytic activity for organic dye reduction under dark

Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(5), С. 113383 - 113383

Опубликована: Июнь 20, 2024

Язык: Английский

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Construction of bionic sea urchin-like ZnFe2O4/Bi2S3 heterojunction for microwave-induced catalytic reduction of Cr(VI): Performance and mechanism insights

Chemical Engineering Journal, Год журнала: 2024, Номер 488, С. 150766 - 150766

Опубликована: Март 27, 2024

Язык: Английский

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Cellulose‐Supported SnW(S,O)₄ Bimetal Sulfo‐Oxide Catalysts for the Catalytic Reduction of Pollutants in the Dark

ChemistrySelect, Год журнала: 2025, Номер 10(1)

Опубликована: Янв. 1, 2025

Abstract In this paper, cellulose‐supported SnW(S,O) 4 bimetal sulfo‐oxide catalysts (labeled as SnWSO‐C or SW@C) with exceptional catalytic performance in the reduction of MB, RhB, and Cr(VI) presence NaBH under dark conditions were synthesized via an in‐situ hydrolysis method. The catalyst system diverse tree species Pinus massoniana (Pm), Populus tomentosa Carrière (Ptc), Rice hull (Rh), Phyllostachys edulis (Pe) was investigated. 100 mL solutions MB (20 ppm), RhB (50 ppm) completely reduced by SW@Cotton, SW@Pe, SW@Rh, SW@Ptc, SW@Pm within 10, 7, 13, 4, min for MB; 8, RhB; 5, 8 Cr(VI), respectively. Among them, SW@Pe exhibits highest efficiency excellent stability, maintaining a removal rate 96% after six cycles. superior attributed unique properties cellulose, characterized low crystallinity (53.25%), minimal ash content (0.15%), lowest degree polymerization (1267). These features facilitated improved dispersion SnWSO sulfo‐oxide, leading to smaller crystal size, lower electrochemical impedance (2.24 Ω), larger electrochemically active surface area (21.86 mF/cm 2 ). This study demonstrates potential wastewater treatment, which is significant advancing future research on environmental pollution management using biomass‐based materials.

Язык: Английский

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Mn/S co-doped BiOCl regulated with a hydrophobic-to-superhydrophilic transition and oxygen-vacancy defects for assisting photocatalytic hydrogen evolution

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161621 - 161621

Опубликована: Март 1, 2025

Язык: Английский

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Synergistic Tuning of Heterovalent States and Oxygen-Vacancy Defect Engineering in Hydrophilic W-Doped Sb₂OS₂ for Enhanced Nitrogen Photoreduction to Ammonia

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер 16(43), С. 58764 - 58779

Опубликована: Окт. 16, 2024

Nitrogen fixation reaction via photocatalysis offers a green and promising strategy for renewable NH3 synthesis, catalysts with high-efficiency photocatalytic properties are essential to the process. Herein, we demonstrate W-doped Sb2OS2 bimetal oxysulfide catalyst (labeled as SbWOS) abundant oxygen vacancies, heterovalent metal states, hydrophilic surfaces nitrogen photoreduction ammonia. The SbWOS-3 suitable W-doping exhibited excellent activity of 408.08 μmol·g-1·h-1 an apparent quantum efficiency (AQE) 1.88% at 420 nm solar-to-ammonia (STA) conversion 0.082% in pure water under AM1.5G light irradiation. not only transforms hydrophobic into catalyst, making it easier H2O molecules adsorbed on SbWOS surface catalyzed protons, but also endows rich acting active sites trapping activating N2 molecule, produce protons reduction reaction. hydrazine drives which acts photogenerate electrons quickly hopping between W5+ W6+ transfer This study provides feasible scheme applying vacancy defects, hydrophobic-to-hydrophilic wetting engineering

Язык: Английский

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