Advances and perspectives on separators of aqueous zinc ion batteries DOI Creative Commons
Jizhang Chen, Minfeng Chen, Hong Ma

и другие.

Energy Reviews, Год журнала: 2022, Номер 1(1), С. 100005 - 100005

Опубликована: Авг. 19, 2022

With the advantages of intrinsic safety, good affordability, environmental friendliness, moderate energy density, and large power aqueous zinc ion batteries (AZIBs) have gained considerable research interest. However, dendrites, hydrogen evolution, inert byproducts, metal corrosion severely hinder practical applications AZIBs. In order to address these issues, many works been carried out modify interface between anode electrolyte. fact, engineering takes effect at surface near separator. a specialized review on separators AZIBs is still lacking. Herein, basic requirements recent advances modification strategies including employment functional groups, establishment coatings, construction hybrid architectures, regulations porosity, utilization bipolar membrane are reviewed. Besides, perspectives for further investigations outlined. This could offer useful guidance future explorations

Язык: Английский

Comprehensive understanding of the roles of water molecules in aqueous Zn-ion batteries: from electrolytes to electrode materials DOI
Ming Li, Zilan Li, Xuanpeng Wang

и другие.

Energy & Environmental Science, Год журнала: 2021, Номер 14(7), С. 3796 - 3839

Опубликована: Янв. 1, 2021

This review summarizes the influences of water molecules during energy storage process from perspectives electrolyte, Zn anode, and cathode materials, including basic theory, modification methods, practical applications.

Язык: Английский

Процитировано

401

Cotton-derived cellulose film as a dendrite-inhibiting separator to stabilize the zinc metal anode of aqueous zinc ion batteries DOI
Weijun Zhou, Minfeng Chen, Qinghua Tian

и другие.

Energy storage materials, Год журнала: 2021, Номер 44, С. 57 - 65

Опубликована: Окт. 4, 2021

Язык: Английский

Процитировано

356

Navigating fast and uniform zinc deposition via a versatile metal–organic complex interphase DOI
Huanyan Liu, Jian‐Gan Wang, Wei Hua

и другие.

Energy & Environmental Science, Год журнала: 2022, Номер 15(5), С. 1872 - 1881

Опубликована: Янв. 1, 2022

A universal and versatile metal–organic complex interphase strategy is proposed as a splendid dendrite corrosion inhibitor for achieving ultrastable Zn anodes with substantially improved Coulombic efficiency extended cycling lifetime.

Язык: Английский

Процитировано

202

Building Ohmic Contact Interfaces toward Ultrastable Zn Metal Anodes DOI
Huanyan Liu, Jian‐Gan Wang, Wei Hua

и другие.

Advanced Science, Год журнала: 2021, Номер 8(23)

Опубликована: Окт. 20, 2021

Zn metal holds grand promise as the anodes of aqueous batteries for grid-scale energy storage. However, rampant zinc dendrite growth and severe surface side reactions significantly impede commercial implementation. Herein, a universal Zn-metal oxide Ohmic contact interface model is demonstrated effectively improving plating/stripping reversibility. The high work function difference between oxides enables building an interfacial anti-blocking layer dendrite-free deposition. Moreover, can physical barrier to suppress pernicious reactions. Consequently, proof-of-concept CeO2 -modified anode delivers ultrastable durability over 1300 h at 0.5-5 mA cm-2 improved Coulombic efficiency, feasibility which also evidenced in MoS2 //Zn full cells. This study enriches fundamental comprehension interfaces on deposition, may shed light development other battery anodes.

Язык: Английский

Процитировано

150

Boosting zinc-ion intercalation in hydrated MoS2 nanosheets toward substantially improved performance DOI
Huanyan Liu, Jian‐Gan Wang, Wei Hua

и другие.

Energy storage materials, Год журнала: 2020, Номер 35, С. 731 - 738

Опубликована: Дек. 11, 2020

Язык: Английский

Процитировано

149

A Safe Flexible Self-Powered Wristband System by Integrating Defective MnO2–x Nanosheet-Based Zinc-Ion Batteries with Perovskite Solar Cells DOI
Jiangqi Zhao, Zhengjie Xu, Zhan Zhou

и другие.

ACS Nano, Год журнала: 2021, Номер 15(6), С. 10597 - 10608

Опубликована: Май 26, 2021

The booming market of portable and wearable electronics has aroused the requests for advanced flexible self-powered energy systems featuring both excellent performance high safety. Herein, we report a safe, flexible, wristband system by integrating high-performance zinc-ion batteries (ZIBs) with perovskite solar cells (PSCs). ZIBs were first fabricated on basis defective MnO2–x nanosheet-grown carbon cloth (MnO2–x@CC), which was obtained via simple lithium treatment MnO2 nanosheets to slightly expand interlayer spacing generate rich oxygen vacancies. When used as ZIB cathode, MnO2–x@CC ultrahigh mass loading (up 25.5 mg cm–2) exhibits much enhanced specific capacity (3.63 mAh cm–2 at current density 3.93 mA cm–2), rate performance, long cycle stability (no obvious degradation after 5000 cycles) than those MnO2@CC. Importantly, MnO2–x@CC-based quasi-solid-state not only achieves flexibility an 5.11 mWh (59.42 cm–3) but also presents safety under wide temperature range various severe conditions. More importantly, can be integrated PSCs construct wristband, is able harvest light power commercial smart bracelet. This work sheds development cathodes thus offers good strategy electronics.

Язык: Английский

Процитировано

146

Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries DOI Creative Commons
Yunxiang Zhao,

Shan Guo,

Manjing Chen

и другие.

Nature Communications, Год журнала: 2023, Номер 14(1)

Опубликована: Ноя. 4, 2023

The detrimental parasitic reactions and uncontrolled deposition behavior derived from inherently unstable interface have largely impeded the practical application of aqueous zinc batteries. So far, tremendous efforts been devoted to tailoring interfaces, while stabilization grain boundaries has received less attention. Here, we demonstrate that preferential distribution intermetallic compounds at via an alloying strategy can substantially suppress intergranular corrosion. In-depth morphology analysis reveals their thermodynamic stability, ensuring sustainable potency. Furthermore, hybrid nucleation growth mode resulting reduced Gibbs free energy contributes spatially uniform Zn nuclei, promoting dense deposition. These integrated merits enable a high reversibility 99.85% for over 4000 cycles, steady charge-discharge 10 mA cm-2, impressive cyclability roughly 3500 cycles in Zn-Ti//NH4V4O10 full cell. Notably, multi-layer pouch cell 34 mAh maintains stable cycling 500 cycles. This work highlights fundamental understanding microstructure motivates precise tuning boundary characteristics achieve highly reversible anodes.

Язык: Английский

Процитировано

143

Challenges and design strategies for high performance aqueous zinc ion batteries DOI
Xingyu Zhao,

Xinqi Liang,

Li Yu

и другие.

Energy storage materials, Год журнала: 2021, Номер 42, С. 533 - 569

Опубликована: Авг. 1, 2021

Язык: Английский

Процитировано

134

Recent Advances on Challenges and Strategies of Manganese Dioxide Cathodes for Aqueous Zinc‐Ion Batteries DOI Creative Commons

Yuhui Xu,

Gaini Zhang,

Jingqian Liu

и другие.

Energy & environment materials, Год журнала: 2022, Номер 6(6)

Опубликована: Дек. 24, 2022

Aqueous zinc‐ion batteries (AZIBs) are regarded as promising electrochemical energy storage devices owing to its low cost, intrinsic safety, abundant zinc reserves, and ideal specific capacity. Compared with other cathode materials, manganese dioxide high voltage, environmental protection, theoretical capacity receives considerable attention. However, the problems of structural instability, dissolution, poor electrical conductivity make exploration high‐performance still a great challenge impede practical applications. Besides, mechanisms involved complex somewhat controversial. To address these issues, tremendous efforts, such surface engineering, heteroatoms doping, defect electrolyte modification, some advanced characterization technologies, have been devoted improving performance illustrating mechanism. In this review, we particularly focus on classification based crystal structures, ions mechanisms, existing challenges, corresponding optimization strategies well structure–performance relationship. final section, application perspectives oxide materials in AZIBs prospected.

Язык: Английский

Процитировано

134

Advanced Multifunctional Aqueous Rechargeable Batteries Design: From Materials and Devices to Systems DOI
Lei Li, Qichong Zhang, Bing He

и другие.

Advanced Materials, Год журнала: 2021, Номер 34(5)

Опубликована: Окт. 24, 2021

Multifunctional aqueous rechargeable batteries (MARBs) are regarded as safe, cost-effective, and scalable electrochemical energy storage devices, which offer additional functionalities that conventional cannot achieve, ideally leads to unprecedented applications. Although MARBs among the most exciting rapidly growing topics in scientific research industrial development nowadays, a systematic summary of evolution advances field is still not available. Therefore, review presented comprehensively systematically summarizes design principles recent by categories smart ARBs integrated systems, together with an analysis their device configuration, performance, diverse functions. The two promising strategies construct novel may be A) introduction functional materials into ARB components, B) integration other devices. ongoing challenges future perspectives this outlined foster MARBs. Finally, important upcoming directions developing highlighted lead commercialization further broadening range

Язык: Английский

Процитировано

129