Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Авг. 5, 2024
Abstract
It
is
crucial
to
minimize
cobalt
content
in
Ni‐rich
layered
single‐crystal
cathodes
due
their
high
price
and
limited
availability,
yet
it
will
inevitably
lead
cation
disordering,
capacity
degradation,
thermal
issues.
Herein,
overcome
the
intrinsic
trade‐off
between
performance
composition
of
Co‐less
cathodes,
a
precursor
engineering
strategy
with
an
epitaxially
grown
enrichment
on
surface
innovatively
proposed.
In
contrast
traditional
coating
modifications
random
orientation
rigid
surface‐bulk
boundary,
enriched
layer
undergoes
rapid
interdiffusion
internal
Ni
3+
during
optimized
sintering
process.
This
eliminates
promoting
uniform
distribution
synergistically
addressing
Li/Ni
intermixing.
Moreover,
enhanced
Li
+
diffusion
obtained,
thereby
suppressing
concentration
gradient
intragranular
cracks
generation.
Consequently,
modified
LiNi
0.7
Co
0.07
Mn
0.23
O
2
exhibits
impressive
cycling
stability
increased
retention
both
coin‐type
half‐cells
pouch‐type
full‐cells
(91%
after
1000
cycles),
even
under
harsh
condition
high‐temperature,
surpassing
majority
previously
reported
cathodes.
work
opens
new
avenues
toward
low
cost,
energy
density,
stability,
long
cyclic
life
for
sheds
light
large‐scale
commercial
production.
Abstract
Planar
gliding
along
with
anisotropic
lattice
strain
of
single‐crystalline
nickel‐rich
cathodes
(SCNRC)
at
highly
delithiated
states
will
induce
severe
delamination
cracking
that
seriously
deteriorates
LIBs’
cyclability.
To
address
these
issues,
a
novel
lattice‐matched
MgTiO
3
(MTO)
layer,
which
exhibits
same
structure
as
Ni‐rich
cathodes,
is
rationally
constructed
on
LiNi
0.9
Co
0.05
Mn
O
2
(SC90)
for
ultrastable
mechanical
integrity.
Intensive
in/ex
situ
characterizations
combined
theoretical
calculations
and
finite
element
analysis
suggest
the
uniform
MTO
coating
layer
prevents
direct
contact
between
SC90
organic
electrolytes
enables
rapid
Li‐ion
diffusion
depressed
Li‐deficiency,
thereby
stabilizing
interfacial
accommodating
stress
SC90.
More
importantly,
superstructure
simultaneously
formed
in
SC90,
can
effectively
alleviate
changes
decrease
cation
mobility
during
successive
high‐voltage
de/intercalation
processes.
Therefore,
as‐acquired
MTO‐modified
cathode
displays
desirable
capacity
retention
stability.
When
paired
commercial
graphite
anodes,
pouch‐type
cells
deliver
high
175.2
mAh
g
−1
89.8%
after
500
cycles.
This
lattice‐matching
strategy
demonstrate
effective
pathway
to
maintain
structural
stability
electrode
materials,
be
pioneering
breakthrough
commercialization
cathodes.
ACS Nano,
Год журнала:
2024,
Номер
18(15), С. 10566 - 10581
Опубликована: Апрель 1, 2024
Ni-rich
layered
oxides
have
received
significant
attention
as
promising
cathode
materials
for
Li-ion
batteries
due
to
their
high
reversible
capacity.
However,
intergranular
and
intragranular
cracks
form
at
state-of-charge
(SOC)
levels
exceeding
4.2
V
(vs.
Li/Li+),
representing
a
prominent
failure
mechanism
of
oxides.
The
nanoscale
crack
formation
SOC
is
attributed
volume
change
resulting
from
phase
transition
between
the
H2
H3
phases.
Herein,
in
contrast
electrochemical
levels,
another
chemical
pit
on
directly
evidenced
fully
lithiated
(low
levels).
This
associated
with
stress
corrosion
cracking,
driven
by
elevated
temperatures.
nanoscopic
behavior
during
aging
temperatures
investigated
using
high-resolution
transmission
electron
microscopy,
revealing
that
microcracks
can
develop
through
two
distinct
mechanisms:
cycling
corrosion.
Notably,
occur
even
discharged
state
levels),
whereas
are
observed
only
levels.
finding
provides
comprehensive
understanding
complex
mechanisms
an
opportunity
improve
performance.
Advanced Materials,
Год журнала:
2024,
Номер
36(32)
Опубликована: Июнь 11, 2024
Abstract
The
cycling
stability
of
LiNi
0.8
Co
0.1
Mn
O
2
under
high
voltages
is
hindered
by
the
occurrence
hybrid
anion‐
and
cation‐redox
processes,
leading
to
oxygen
escape
uncontrolled
phase
collapse.
In
this
study,
an
interfacial
engineering
strategy
involving
a
straightforward
mechanical
ball
milling
low‐temperature
calcination,
employing
Se‐doped
FeSe
&Fe
3
‐modified
approach
proposed
design
stable
Ni‐rich
cathode.
Se
2−
are
selectively
adsorbed
within
vacancies
form
─
TM
bond,
effectively
stabilizing
lattice
oxygen,
preventing
structural
distortion.
Simultaneously,
Se‐NCM811//FeSe
//Fe
self‐assembled
electric
field
activated,
improving
charge
transfer
coupling.
Furthermore,
accelerates
Li
+
diffusion
reacts
with
Fe
SeO
.
coating
mitigates
hydrofluoric
acid
erosion
acts
as
electrostatic
shield
layer,
limiting
outward
migration
anions.
Impressively,
modified
materials
exhibit
significantly
improved
electrochemical
performance,
capacity
retention
79.7%
after
500
cycles
at
1C
4.5
V.
it
provides
extraordinary
94.6%
in
3–4.25
V
550
pouch‐type
full
battery.
This
dual‐modification
demonstrates
its
feasibility
opens
new
perspective
for
development
lithium‐ion
batteries
operating
voltages.
Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Авг. 5, 2024
Abstract
It
is
crucial
to
minimize
cobalt
content
in
Ni‐rich
layered
single‐crystal
cathodes
due
their
high
price
and
limited
availability,
yet
it
will
inevitably
lead
cation
disordering,
capacity
degradation,
thermal
issues.
Herein,
overcome
the
intrinsic
trade‐off
between
performance
composition
of
Co‐less
cathodes,
a
precursor
engineering
strategy
with
an
epitaxially
grown
enrichment
on
surface
innovatively
proposed.
In
contrast
traditional
coating
modifications
random
orientation
rigid
surface‐bulk
boundary,
enriched
layer
undergoes
rapid
interdiffusion
internal
Ni
3+
during
optimized
sintering
process.
This
eliminates
promoting
uniform
distribution
synergistically
addressing
Li/Ni
intermixing.
Moreover,
enhanced
Li
+
diffusion
obtained,
thereby
suppressing
concentration
gradient
intragranular
cracks
generation.
Consequently,
modified
LiNi
0.7
Co
0.07
Mn
0.23
O
2
exhibits
impressive
cycling
stability
increased
retention
both
coin‐type
half‐cells
pouch‐type
full‐cells
(91%
after
1000
cycles),
even
under
harsh
condition
high‐temperature,
surpassing
majority
previously
reported
cathodes.
work
opens
new
avenues
toward
low
cost,
energy
density,
stability,
long
cyclic
life
for
sheds
light
large‐scale
commercial
production.