C4C recent developments: carbonaceous-supported catalysts for CO2 conversion into cyclic carbonates

Carbon Research, Год журнала: 2025, Номер 4(1)

Опубликована: Фев. 17, 2025

Abstract The conversion of CO 2 into value-added chemicals and fuels is one the potential approaches to deal with environmental issues caused by increasing carbon dioxide concentration in atmosphere. can be transformed a variety valuable products, including but not limited monoxide, cyclic carbonates, formic acid, methanol, methane, ethanol, acetic propanol, light olefins, aromatics, gasoline through thermal catalysis, electrocatalysis, photo(electro)catalysis. In ongoing search for new catalytic conversions, utilization carbon-based materials as catalyst supports demonstrates improvement performance. This because unique features carbonaceous supports, such tunable porous structure, high specific surface area, good chemical stability, excellent conductivity. Though there are other strategies chemicals, cycloaddition, methanation, hydrogenation, photocatalysis, five-membered carbonates has garnered significant attention its address concerns reduce reliance on fossil fuels; however, it faces considerable challenges due thermodynamic stability . To these issues, this review particularly presents recent advancements fixation carbonate using carbonaceous-supported systems viz. graphitic nitride, graphene, nanotubes, nanofiber, activated carbon, sphere, that provide advantages structures, areas, stability. Furthermore, easily modified introducing defects or heteroatoms enhance their provides information current research, development trends, necessary path expedite technological technologies terms materials, various experimental conditions employed reactions. important role molecular process modeling implementing at commercial scale also highlighted. aims demonstrate catalysts improve efficiency production, thereby contributing more sustainable processes. Graphical

Язык: Английский

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Efficient conversion of CO2 into quinazoline-2,4(1H,3H)-diones by glutarimide-based ionic liquids: Relationship among catalytic activity, CO2 absorption capacity, and the interaction force of cations and anions

Sustainable Chemistry and Pharmacy, Год журнала: 2025, Номер 44, С. 101956 - 101956

Опубликована: Фев. 20, 2025

Язык: Английский

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MOF-derived zinc and nickel bimetals grown on carbon fibers as efficient catalysts for synergistic photo-thermal catalytic CO2 cycloaddition

Molecular Catalysis, Год журнала: 2025, Номер 576, С. 114949 - 114949

Опубликована: Фев. 27, 2025

Язык: Английский

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Nitrogen-rich metal–organic framework of nickel(ii) as a highly efficient and reusable catalyst for the synthesis of cyclic carbonates at ambient pressure of CO₂

RSC Advances, Год журнала: 2025, Номер 15(10), С. 7236 - 7247

Опубликована: Янв. 1, 2025

Nitrogen-rich metal organic frameworks (MOFs) structures have a great potential for the chemical fixation of CO2. In this direction, we utilized highly efficient nitrogen-rich dual linker MOF nickel(ii) as heterogeneous catalyst in solvent-free CO2 into cyclic carbonates at ambient pressure. present work, nickel-MOF, Ni-ImzAdn, was synthesized from imidazole and adenine linkers under hydrothermal conditions (Imz = Imidazole Adn Adenine). The Ni-ImzAdn characterized thoroughly via various physicochemical analyses such FT-IR, SEM, EDX, EDX-mapping, XRD, ICP-OES, BET, BJH, TG-DTA, CO2-TPD, NH3-TPD. with adequate free nitrogen sites exhibit high catalytic activity cycloaddition styrene oxide (93% yield) attributed to synergistic effect strong Lewis acid base on catalyst, which were acquired by NH3-TPD respectively. addition, presented recyclable without significant loss after six reaction cycles low ion leaching (analyzed (ICP-OES)). Thermogravimetry-differential thermal analysis (TG-DTA) showed had stability up 318 °C.

Язык: Английский

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Recent Developments in Metal-free Materials for Photocatalytic and Electrocatalytic Carbon Dioxide Conversion into Value Added Products

Energy & Fuels, Год журнала: 2025, Номер unknown

Опубликована: Март 24, 2025

Язык: Английский

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