Challenges and Opportunities: Metal–Organic Frameworks for Direct Air Capture

Advanced Functional Materials, Год журнала: 2023, Номер 34(43)

Опубликована: Окт. 12, 2023

Abstract Global reliance on fossil fuel combustion for energy production has contributed to the rising concentration of atmospheric CO 2 , creating significant global climate challenges. In this regard, direct air capture (DAC) from atmosphere emerged as one most promising strategies counteract harmful effects environment, and further development commercialization technology will play a pivotal role in achieving goal net‐zero emissions by 2050. Among various DAC adsorbents, metal–organic frameworks (MOFs) show great potential due their high porosity ability reversibly adsorb at low concentrations. However, adsorption efficiency cost‐effectiveness these materials must be improved widely deployed sorbents. To that end, perspective provides critical discussion several types benchmark MOFs have demonstrated capacities, including an assessment stability, mechanism, capture‐release cycling behavior, scale‐up synthesis. It then concludes highlighting limitations addressed go research laboratory implementation devices scale so they can effectively mitigate change.

Язык: Английский

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Advances in porous materials for efficient separation and purification of flue gas

Separation and Purification Technology, Год журнала: 2024, Номер 352, С. 128238 - 128238

Опубликована: Май 31, 2024

Язык: Английский

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Biomass-MOF composites in wastewater treatment, air purification, and electromagnetic radiation adsorption – A review

Chemical Engineering Journal, Год журнала: 2024, Номер 494, С. 152932 - 152932

Опубликована: Июнь 7, 2024

Язык: Английский

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Precision-Engineered Construction of Proton-Conducting Metal–Organic Frameworks

Nano-Micro Letters, Год журнала: 2024, Номер 17(1)

Опубликована: Дек. 11, 2024

Proton-conducting materials have attracted considerable interest because of their extensive application in energy storage and conversion devices. Among them, metal-organic frameworks (MOFs) present tremendous development potential possibilities for constructing novel advanced proton conductors due to special advantages crystallinity, designability, porosity. In particular, several design strategies the structure MOFs opened new doors advancement MOF conductors, such as charged network construction, ligand functionalization, metal-center manipulation, defective engineering, guest molecule incorporation, pore-space manipulation. With implementation these strategies, proton-conducting developed significantly profoundly within last decade. Therefore, this review, we critically discuss analyze fundamental principles, methods targeted at improving conductivity through representative examples. Besides, structural features, conduction mechanism behavior are discussed thoroughly meticulously. Future endeavors also proposed address challenges practical research. We sincerely expect that review will bring guidance inspiration further motivate research enthusiasm materials.

Язык: Английский

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Hydrophobic and hydrophilic functional groups and their impact on physical adsorption of CO2 in presence of H2O: A critical review

Journal of CO2 Utilization, Год журнала: 2024, Номер 86, С. 102908 - 102908

Опубликована: Авг. 1, 2024

Язык: Английский

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Recent advances and challenges in solid sorbents for CO2 capture

Carbon Capture Science & Technology, Год журнала: 2025, Номер unknown, С. 100386 - 100386

Опубликована: Фев. 1, 2025

Язык: Английский

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Carbon dioxide capturing activities of porous metal-organic frameworks (MOFs)

Microporous and Mesoporous Materials, Год журнала: 2023, Номер 366, С. 112932 - 112932

Опубликована: Дек. 5, 2023

Язык: Английский

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Nanoscale MOF-74-based QCM gas sensor for CO2 detection at room temperature

Sensors and Actuators B Chemical, Год журнала: 2024, Номер 413, С. 135874 - 135874

Опубликована: Апрель 24, 2024

Язык: Английский

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Synergistic applications of cyclodextrin-based systems and metal–organic frameworks in transdermal drug delivery for skin cancer therapy

Journal of Materials Chemistry B, Год журнала: 2024, Номер 12(16), С. 3807 - 3839

Опубликована: Янв. 1, 2024

This review article explores the innovative field of eco-friendly cyclodextrin-based coordination polymers and metal-organic frameworks (MOFs) for transdermal drug delivery in case skin cancer therapy. We critically examine significant advancements developing these nanocarriers, with a focus on their unique properties such as biocompatibility, targeted release, enhanced permeability. These attributes are instrumental addressing limitations inherent traditional treatments represent paradigm shift towards more effective patient-friendly therapeutic approaches. Furthermore, we discuss challenges faced optimizing synthesis process large-scale production while ensuring environmental sustainability. The also emphasizes immense potential clinical applications nanocarriers therapy, highlighting role facilitating targeted, controlled release which minimizes systemic side effects. Future could see being customized to individual patient profiles, potentially revolutionizing personalized medicine oncology. With further research trials, hold promise transforming landscape treatment. this study, aim provide comprehensive overview current state outline future directions advancing development application nanocarriers.

Язык: Английский

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Confinement Synthesis of Atomic Copper‐Anchored Polymeric Carbon Nitride in Crystalline UiO‐66‐NH2 for High‐Performance CO2‐to‐CH3OH Photocatalysis

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(45)

Опубликована: Июль 29, 2024

Photocatalytic CO

Язык: Английский

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