A rhodium-catalyzed C‒H activation/cyclization approach toward the total syntheses of cassiarin C and 8-O-methylcassiarin A from a common intermediate DOI
Didier F. Vargas, Santiago Fonzo, Sebastián O. Simonetti

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(38), С. 7880 - 7894

Опубликована: Янв. 1, 2024

Three short and efficient total syntheses of cassiarin C are reported, from a chromanone common key intermediate. A C-H activation strategy, under rhodium catalysis on its pivaloyl oxime, enabled the installation pyridine ring. Dehydrogenation 8-

Язык: Английский

A rhodium-catalyzed C‒H activation/cyclization approach toward the total syntheses of cassiarin C and 8-O-methylcassiarin A from a common intermediate DOI
Didier F. Vargas, Santiago Fonzo, Sebastián O. Simonetti

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(38), С. 7880 - 7894

Опубликована: Янв. 1, 2024

Three short and efficient total syntheses of cassiarin C are reported, from a chromanone common key intermediate. A C-H activation strategy, under rhodium catalysis on its pivaloyl oxime, enabled the installation pyridine ring. Dehydrogenation 8-

Язык: Английский

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