Molecules, Год журнала: 2025, Номер 30(6), С. 1314 - 1314
Опубликована: Март 14, 2025
The 2,6-bis(pyrazol-1-yl)pyridine (bpp) ligand family is widely recognized for its versatile coordination abilities and broad functionalization potential. This review examines bpp modifications at the pyridine ring’s 4-position, focusing on their influence magnetic, optical, electronic properties. Key applications discussed include spin crossover (SCO), single-ion single-molecule magnetism (SIM SMM), luminescence, redox flow batteries (RFBs), photonic devices. We provide a comprehensive overview of involving carboxylates, extended aromatic systems, radicals, redox-active units such as tetrathiafulvalene (TTF), alongside supramolecular architectures. highlights fundamental design principles, particularly role substituents in tuning SCO behavior, photophysical properties, self-assembly into functional nanostructures. Notable advancements SCO-driven conductivity modulation, reversible luminescent switching, amphiphilic bpp-based vesicles multicolor emission. By analyzing interplay between structure functions, we insights potential derivatives advanced materials design. presents recent experimental theoretical developments, offering foundation future exploration compounds multifunctional
Язык: Английский