Tuning ionic liquid-based functional deep eutectic solvents and other functional mixtures for CO2 capture

Chemical Engineering Journal, Год журнала: 2023, Номер 463, С. 142298 - 142298

Опубликована: Март 10, 2023

Язык: Английский

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A review on the role of deep eutectic solvents in mango (Mangifera indica) extraction

RSC Advances, Год журнала: 2025, Номер 15(6), С. 4296 - 4321

Опубликована: Янв. 1, 2025

The present review attempts to evaluate the applicability of deep eutectic solvents (DES) as a green technique for extraction phytochemicals from Mangifera indica L. and their therapeutic potential.

Язык: Английский

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Facile Construction of Carboxyl-Functionalized Ionic Polymer towards Synergistic Catalytic Cycloaddition of Carbon Dioxide into Cyclic Carbonates

International Journal of Molecular Sciences, Год журнала: 2022, Номер 23(18), С. 10879 - 10879

Опубликована: Сен. 17, 2022

The development of bifunctional ionic polymers as heterogeneous catalysts for effective, cocatalyst- and metal-free cycloaddition carbon dioxide into cyclic carbonates has attracted increasing attention. However, facile fabrication such having high numbers active sites, suitable types hydrogen bond donors (HBDs), controlled spatial positions dual sites remains a challenging task. Herein, imidazolium-based with hydroxyl/carboxyl groups density were facilely prepared by one-pot quaternization reaction. Catalytic evaluation demonstrated that the presence HBDs (hydroxyl or carboxyl) could enhance catalytic activities significantly toward CO2 Among catalysts, carboxyl-functionalized polymer (PIMBr-COOH) displayed highest activity (94% yield) in benchmark reaction epichlorohydrin, which was higher than hydroxyl-functionalized (PIMBr-OH, 76% yield), far exceeded without (PIMBr, 54% yield). Furthermore, PIMBr-COOH good recyclability wide substrate tolerance. Under ambient pressure, number epoxides smoothly cycloadded carbonates. Additionally, functional theory (DFT) calculation verified formation strong bonds between epoxide polymers. possible mechanism proposed based on synergistic effect carboxyl Br- functionalities. Thus, facile, synthetic strategy construction developed fixation.

Язык: Английский

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Ionic liquid-based (nano)catalysts for hydrogen generation and storage

Journal of Molecular Liquids, Год журнала: 2022, Номер 365, С. 120142 - 120142

Опубликована: Авг. 24, 2022

Язык: Английский

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Novel hydroquinazoline derivatives from Schiff base and study their biological activity

Materials Today Proceedings, Год журнала: 2023, Номер unknown

Опубликована: Май 1, 2023

Язык: Английский

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Triple role of thiocyanate-containing protic ionic liquids in chemodivergent ring-opening of 1,3-indanedione-derived donor–acceptor cyclopropanes

Journal of Molecular Liquids, Год журнала: 2023, Номер 385, С. 122401 - 122401

Опубликована: Июнь 20, 2023

Язык: Английский

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In‐silico Computational Investigations of AntiViral Lignan Derivatives as Potent Inhibitors of SARS CoV‐2

ChemistrySelect, Год журнала: 2022, Номер 7(28)

Опубликована: Июль 26, 2022

Due to alarming outbreak of pandemic COVID-19 in recent times, there is a strong need discover and identify new antiviral agents acting against SARS CoV-2. Among natural products, lignan derivatives have been found effective several viral strains including Total twenty-seven reported plant origin selected for computational studies the potent inhibitors Molecular docking study has carried out order predict describe molecular interaction between active site enzyme derivatives. Out identified hits, clemastatin B

Язык: Английский

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Biannual Account of Anti‐malarial Agents reported in 2021 and 2022: A Comprehensive Coverage

ChemistrySelect, Год журнала: 2024, Номер 9(10)

Опубликована: Март 7, 2024

Abstract Malaria remains a severe infectious disease caused by Plasmodium parasites among the primarily afflicting impoverished populations. According to World Health Organization (WHO) report, there were an estimated 247 million malarial cases globally, resulting in approximately 6,19,000 fatalities. Particularly prevalent tropical and subtropical regions, development of drug resistance has exacerbated this public health challenge. Consequently, been concrete effort explore novel compounds with anti‐malarial properties. In continuation our previous works, review focuses on heterocyclic documented 2021 2022, including artemisinin, benzimidazole, benzofuran, β‐lactam, coumarin, furan, indole, morpholine, piperazine, pyrimidine, quinoline, triazole, etc. highlighting their efficacy, structural characteristics, vitro vivo activities, other relevant aspects for broad interest medicinal chemists working design agents.

Язык: Английский

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The literature of heterocyclic chemistry, part XXII, 2022

Advances in heterocyclic chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Язык: Английский

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Merrifield Resin Supported Ionic Liquids: Catalytic Applications in Organic Synthesis

Current Organic Chemistry, Год журнала: 2023, Номер 27(2), С. 130 - 152

Опубликована: Янв. 1, 2023

Abstract: Ever since their discovery, Ionic Liquids have raised great interest in organic transformations ranging from solvents to catalytic entities. These belong a class of nonmolecular compounds composed ions having curiously low melting points. In the last few years, Supported drawn attention researchers and chemists due advantages over homogeneous catalysis. The most commonly used support for immobilized ionic liquids is polymeric. Due its efficient recovery, reusability chemical inertness, Merrifield resin can be considered an excellent solid liquids. present review summarizes synthesis application Resin (MRSILs). MRSILs synthesized by immobilization amines like ammonium, choline, imidazolium, DABCO, DMAP, pyridine, many other functionalized precursors. Additionally, these play incredible role field catalysis, where both metal-free metal-containing are embodied as catalyst.

Язык: Английский

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