Zeitschrift für Physikalische Chemie,
Год журнала:
2023,
Номер
237(9), С. 1421 - 1442
Опубликована: Авг. 15, 2023
Abstract
Herein,
we
have
scrutinized
the
influence
of
vitamin
B3
(nicotinic
acid)
and
its
isomer
isonicotinic
acid
at
varying
concentrations
on
micellization
properties
1-tetradecyl-3-methylimidazolium
bromide
[C
14
mim]
[Br]
a
given
temperature
range
298.15–308.15
K
to
further
explore
their
advancement
in
medicinal
chemistry.
The
behavior
ionic
liquid
surface
was
determined
using
tensiometry,
while
conductivity,
steady-state
fluorescence,
UV–visible
spectroscopy
were
used
determine
bulk.
Various
thermodynamic,
surface,
parameters
been
determined.
evaluated
CMC
values
for
pure
found
increase
with
increasing
concentration
external
additives
acid).
Further,
negative
∆Gm
mathvariant="normal">i
mathvariant="normal">c
0
${{\increment}G}_{\mathrm{m}\mathrm{i}\mathrm{c}}^{0}$
H
${{\increment}H}_{\mathrm{m}\mathrm{i}\mathrm{c}}^{0}$
state
feasible
exothermic
nature
process.
results
attained
employing
different
methods
correlated
each
other
are
be
good
agreement.
obtained
from
various
studies
indicate
presence
hydrophobic
electrostatic
interactions
occurring
between
aggregates.
Materials Advances,
Год журнала:
2024,
Номер
5(11), С. 4563 - 4600
Опубликована: Янв. 1, 2024
Graphical
abstract
illustrates
how
ionic
liquids
protect
metal
surface
from
corrosion,
highlights
the
factors
affecting
efficacy
and
associated
chemical
reactions
with
without
liquids,
highlighting
their
role
in
preventing
rust
formation.
Chemical Reviews,
Год журнала:
2024,
Номер
124(8), С. 4679 - 4733
Опубликована: Апрель 15, 2024
The
review
presents
a
detailed
discussion
of
the
evolving
field
studying
interactions
between
ionic
liquids
(ILs)
and
biological
systems.
Originating
from
molten
salt
electrolytes
to
present
multiapplication
substances,
ILs
have
found
usage
across
various
fields
due
their
exceptional
physicochemical
properties,
including
excellent
tunability.
However,
with
systems
potential
influence
on
living
organisms
remain
largely
unexplored.
This
examines
cytotoxic
effects
cell
cultures,
biomolecules,
vertebrate
invertebrate
organisms.
Our
understanding
IL
toxicity,
while
growing
in
recent
years,
is
yet
nascent.
established
findings
include
correlations
harmful
ability
disturb
cellular
membranes,
trigger
oxidative
stress
cells,
cause
death
via
apoptosis.
Future
research
directions
proposed
distribution
within
compartments
organelles,
investigating
metabolic
transformations
cells
organisms,
analysis
proteins
involved
apoptosis,
correlation
studies
doses,
exposure
times
resulting
adverse
effects,
examination
subtoxic
concentrations
objects.
aims
serve
as
critical
current
body
knowledge
IL-related
toxicity
mechanisms.
Furthermore,
it
can
guide
researchers
toward
design
less
toxic
informed
use
drug
development
medicine.
Molecules,
Год журнала:
2025,
Номер
30(5), С. 1180 - 1180
Опубликована: Март 6, 2025
Six
biobased
ionic
liquids
were
prepared
from
saturated
fatty
acids
(octanoic,
decanoic
and
dodecanoic
acids)
choline
with
yields
up
to
90%
following
procedures
respecting
green
chemistry
principles.
These
fully
characterized
(NMR,
IR,
elemental
analysis,
viscosimetry
TGA)
used
as
extraction
solvents
for
bioactive
compounds
(curcuminoids
carvacrol)
using
classical
conditions,
the
able
be
recovered
after
five
runs
without
loss
of
activity.
The
liquid
containing
a
C12
carbon
chain
was
best
extracting
solvent,
95%
total
curcuminoids
contained
in
turmeric
69%
carvacrol
oregano,
which
are
higher
compared
described
literature.
As
more
cytotoxic
than
C8
ones,
biological
activity
extracted
evaluated
on
MIAPaCa-2,
pancreatic
adenocarcinoma
cell
line
antitumor
had
previously
been
reported.
Compared
cytotoxicity
commercially
available
extract,
extracts
slightly
weaker.
Energy & Fuels,
Год журнала:
2023,
Номер
37(20), С. 15394 - 15428
Опубликована: Окт. 5, 2023
Carbon
capture
and
storage
(CCS)
technologies
are
the
"knight
in
shining
armor"
that
can
save
humanity
from
burnout
longer
term,
minimizing
damage
CO2
emissions
by
keeping
them
out
of
atmosphere.
Metal–organic
frameworks
(MOFs)
have
received
a
promising
career
for
due
to
their
high
porosity,
surface
area,
excellent
metal-to-ligand
interaction,
good
affinity
molecules.
On
other
hand,
Ionic
liquids
(ILs)
as
emerging
solvents
reported
significant
influence
on
solubility
wide
range
tunability
selection
variety
cations
anions
along
with
advantage
nonvolatility,
thermal
stability,
nonflammability.
The
current
Review
highlights
recent
progress
ongoing
careers
employing
MOFs
ILs
carbon
before
commercialization
large
scale.
A
brief
overview
capturing
using
is
given
under
possible
functionalization
enhance
separation.
Information
integration
MOFs-ILs
composite
system
or
membrane-based
gas
separation
also
presented
detail.
has
potential
while
unit
operation
costs
stable,
efficient,
smooth
industrial
operation.
Present
work
attempts
link
chemistry
MOF
IL
successful
hybridization
(MOF-IL
composite)
process
economics
capture.
Journal of Computational Biophysics and Chemistry,
Год журнала:
2024,
Номер
23(10), С. 1303 - 1323
Опубликована: Авг. 23, 2024
The
study
examined
the
interactions
between
a
deep
eutectic
solvent
(DES)
containing
choline
chloride
(ChCl)
along
with
ethylene
glycol
(EG)
in
molar
ratio
of
1:3,
and
three
carboxylic
acids:
acetic
acid,
propanoic
acid
butanoic
acid.
structural
stability,
electrical
characteristics
dynamic
behavior
these
DES-carboxylic
systems
were
investigated
utilizing
techniques
like
density
functional
theory
(DFT),
natural
bond
orbital
(NBO)
analysis
molecular
dynamics
(MD)
simulations.
results
showed
that
addition
acids
DES
framework
had
substantial
impact
on
distribution
electrons
molecules
system.
More
specifically,
presence
longer
alkyl
chains
caused
more
significant
disturbance
hydrogen-
network
DES.
This
was
observed
through
alterations
electron
localization
function
(ELF)
noncovalent
interaction
(NCI)
investigations.
yielded
useful
insights
into
design
implementation
DESs,
including
improving
their
stability
reactivity
targeted
interactions.
