Journal of Materials Research and Technology,
Год журнала:
2023,
Номер
27, С. 542 - 563
Опубликована: Сен. 30, 2023
Deep
eutectic
solvents
(DESs)
are
an
emerging
class
of
materials
that
show
promise
for
applications
as
inexpensive
"designer"
with
tunable
properties.
A
detailed
review
the
current
literature
reveals
a
lack
predictive
understanding
microscopic
mechanisms
govern
structure−property
relationships
in
this
solvents.
They
can
dissolve
both
organic
and
inorganic
compounds,
including
salts
metal
oxides.
Zinc
oxide
is
used
substrate
synthesis
various
task-specific
materials,
has
excellent
antibacterial
In
work,
DES
DES+ZnO
combination
were
first
time
admixtures
cement
composites,
shown
to
improve
final
properties
matrix.
The
obtained
exhibit
good
properties,
even
small
amounts
zinc
oxide,
improved
mechanical
durability
when
subjected
freezing–thawing
cycles.
Pharmaceuticals,
Год журнала:
2024,
Номер
17(1), С. 124 - 124
Опубликована: Янв. 18, 2024
The
extraction
of
bioactive
compounds
pharmaceutical
interest
from
natural
sources
has
been
significantly
explored
in
recent
decades.
However,
the
techniques
used
were
not
very
efficient
terms
time
and
energy
consumption;
additionally,
solvents
for
harmful
environment.
To
improve
environmental
impact
extractions
at
same
increase
yields,
several
new
developed.
Among
most
ones
are
ultrasound-assisted
microwave-assisted
extraction.
These
increased
yield
selectivity
a
smaller
amount
with
decrease
consumption.
Nevertheless,
high
volume
organic
was
still
extraction,
causing
subsequent
problem.
Neoteric
appeared
as
green
alternatives
to
solvents.
neoteric
solvents,
deep
eutectic
evidenced
be
one
best
due
their
intrinsic
characteristics.
considered
because
they
made
up
such
sugars,
amino
acids,
carboxylic
acids
having
low
toxicity
degradability.
In
addition,
simple
prepare,
an
atomic
economy
100%,
attractive
physicochemical
properties.
Furthermore,
huge
number
that
can
synthesize
these
make
them
useful
since
tailored
selective
towards
specific
component
or
class
components.
main
aim
this
paper
is
give
comprehensive
review
which
describes
properties,
characteristics,
production
methods
well
its
application
extract
interest.
Additionally,
overview
more
sustainable
also
given.
Green Chemical Engineering,
Год журнала:
2023,
Номер
5(4), С. 409 - 417
Опубликована: Ноя. 28, 2023
Green
solvents
such
as
water
and
ionic
liquids
(ILs)
are
pillars
of
the
great
mansion
green
chemistry
processing.
Initially
proposed
a
new
family
ILs,
deep
eutectic
(DESs)
have
received
fast
development
in
past
two
decades.
In
this
contribution,
DESs
reviewed
critically
concept
is
extended
to
low-melting
mixture
(LoMMSs),
which
cover
all
kinds
materials
including
compounds,
molecular
metals.
Six
classes
LoMMSs
classification
system
examples
given.
Finally,
several
thermodynamic
issues
concerning
discussed.
Two
concepts,
robustness
high-entropy
LoMMSs,
proposed.
The
Lithium-ion
battery
(LIB)
is
one
of
the
main
energy
storage
equipment.
Its
cathode
material
contains
Li,
Co,
and
other
valuable
metals.
Therefore,
recycling
spent
LIBs
can
reduce
environmental
pollution
resource
waste,
which
significant
for
sustainable
development.
However,
traditional
metallurgical
methods
are
not
environmentally
friendly,
with
high
cost
toxicity.
Recently,
concept
green
chemistry
gives
rise
to
efficient
technology,
promotes
transition
solvents
from
organic
represented
by
deep
eutectic
(DESs).
DESs
considered
as
ideal
alternative
in
extraction
processes,
attracting
great
attention
due
their
low
cost,
toxicity,
good
biodegradability,
capacity.
It
very
important
develop
system
development
economic
technology.
In
this
work,
applications
research
progress
recovery
reviewed,
physicochemical
properties
such
viscosity,
toxicity
regulatory
summarized
discussed.
particular,
data
collected
analyzed.
Finally,
guidance
prospects
future
put
forward,
aiming
explore
more
suitable
metals
batteries.
Food Frontiers,
Год журнала:
2024,
Номер
5(3), С. 1265 - 1301
Опубликована: Март 21, 2024
Abstract
The
conventional
techniques
for
protein
extraction
from
biomass
are
not
fully
aligned
with
sustainability
goals,
so
it
is
important
to
look
some
alternate
solutions.
By
simultaneously
extracting
both
soluble
and
insoluble
proteins,
deep
eutectic
solvents
(DESs)
offer
a
viable
method
valorizing
protein‐rich
variety
of
sources.
Notably,
the
molecular
crowding
effects
DESs
may
have
helped
unfolded
proteins
acquire
compact
stable
conformations,
facilitating
solubilization
effective
extraction.
However,
there
still
lack
information
regarding
how
interact
affect
structure
properties
recovered
proteins.
To
enable
their
widespread
usage
as
sustainable
dietary
safety
DES‐extracted
must
also
be
addressed.
In
this
paper,
we
review
state
science
in
DES‐mediated
extraction,
focusing
on
mechanism
interactions
between
Additionally,
aspects
that
could
structure,
technofunctional,
nutritional
characteristics,
extracted
explored.
DES‐based
helpful
valorize
different
biomasses
production
food
due
specific
features.