Bis(2,4,4-trimethylpentyl)phosphinic acid/phenol deep eutectic solvent: Physicochemical properties and application prospects for the extraction of trivalent rare earth elements

Journal of Molecular Liquids, Год журнала: 2025, Номер unknown, С. 126984 - 126984

Опубликована: Янв. 1, 2025

Язык: Английский

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Recent Uses of Ionic Liquids in the Recovery and Utilization of Rare Earth Elements

Minerals, Год журнала: 2024, Номер 14(7), С. 734 - 734

Опубликована: Июль 22, 2024

The importance of rare earth elements as a basis for the development new technologies or improvement existing ones makes their recovery from raw and waste materials necessary. In this recovery, hydrometallurgy its derivative solvometallurgy play key roles due to operational characteristics, which are emphasized with use ionic liquids. This manuscript reviews most recent advances (2023 2024) in liquids unit operations (leaching separation technologies) aimed at these valuable strategic metals. Moreover, comprehensive review is presented chemicals advanced containing some elements.

Язык: Английский

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Extraction of Rare Earth Elements from Nitrate Solutions by Hydrophobic Eutectic Solvents Based on Phosphorus-Containing Compounds

Industrial & Engineering Chemistry Research, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 26, 2024

Язык: Английский

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Recent Uses of Ionic Liquids in the Recovery and Utilization of Rare Earth Elements

Опубликована: Июнь 11, 2024

The importance of rare earth elements as the basis in development new technologies or improvement used ones, made a necessity its recovery, besides that from raw materials, waste materials. In this Hydrometallurgy and derivative Solvometallurgy, play key role due to operational characteristics, which are emphasized with use ionic liquids. manuscript reviewed most recent advances (2023 2024 years) about liquids unit operations (leaching separation technologies) aimed recovery these valuable strategic metals. Moreover, comprehensive review chemicals advanced materials containing some is presented.

Язык: Английский

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Neoteric Solvents for Rare Earths Processing: Perspectives on the Potential of Ionic Liquids and Deep Eutectic Solvents From a Bibliometric Analysis

Solvent Extraction and Ion Exchange, Год журнала: 2024, Номер unknown, С. 1 - 35

Опубликована: Дек. 17, 2024

Rare earth elements have become critical in today's technological societies and neoteric solvents, such as ionic liquids (ILs) deep eutectic solvents (DESs), are being called upon to replace traditional organic order improve the environmental sustainability of rare processing. A bibliometric analysis was performed investigate scientific documents published Scopus database until 2023 regarding use ILs DESs for earths The search identified 731 papers since pioneering works last years 20th century amount accumulated throughout time followed a quadratic evolution. China, main producer worldwide, most prolific country, publishing 276 (37.8% contribution), almost four times higher than contribution United States (75 documents), second country ranking. triad important keywords consists liquids, extraction. In addition separation by solvent extraction, leaching from mineral ores secondary resources e-waste using has been extensively investigated. addition, these innovative can be considered promising media electrowinning processes obtain pure earths.

Язык: Английский

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Denitrogenation of Light Hydrocarbon Fractions with Natural Deep Eutectic Solvents Using Commercial Extraction Equipment

Theoretical Foundations of Chemical Engineering, Год журнала: 2023, Номер 57(6), С. 1276 - 1291

Опубликована: Дек. 1, 2023

Язык: Английский

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Membrane transport of rare earth metal ions N,N’-bisdioctylphosphorylmethyl-1,4-diaminobutane by the active transport mechanism

Journal of Molecular Liquids, Год журнала: 2024, Номер 413, С. 125857 - 125857

Опубликована: Авг. 30, 2024

Язык: Английский

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Separation of Rare-Earth Elements by Synergistic Mixtures of Methyl(tri-n-Octyl)ammonium Nitrate and an Ammonium Di(2-Ethylhexyl)phosphoric Acid Salt

Russian Journal of Inorganic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 30, 2024

Язык: Английский

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Deep Eutectic Solvent (TOPO/D2EHPA/Menthol) for Extracting Metals from Synthetic Hydrochloric Acid Leachates of NMC-LTO Batteries

Metals, Год журнала: 2024, Номер 14(12), С. 1441 - 1441

Опубликована: Дек. 16, 2024

The recycling of lithium-ion batteries is increasingly important for both resource recovery and environmental protection. However, the complex composition cathode anode materials in these makes efficient separation metal mixtures challenging. Hydrometallurgical methods, particularly liquid extraction, provide an effective means separating ions, though they require periodic updates to their extraction systems. This study introduces a hydrophobic deep eutectic solvent composed trioctylphosphine oxide, di(2-ethylhexyl)phosphoric acid, menthol, which Ti(IV), Co(II), Mn(II), Ni(II), Li+ ions from hydrochloric acid leachates NMC (LiNixMnyCo1−x−yO2) with LTO (Li4Ti5O12) anodes. By optimising molar oxide/di(2-ethylhexyl)phosphoric acid/menthol mixture 4:1:5 ratio, high efficiency was achieved. demonstrated stability over 10 cycles, conditions its regeneration were successfully established. At room temperature, DES exhibited density 0.89 g/mL viscosity 56 mPa·s, are suitable laboratory-scale processes. Experimental results laboratory setup mixer-settlers confirmed Ti(IV) Co(II) context kinetics.

Язык: Английский

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Polythermal Study of Component Solubility and Phase Equilibria in the Ternary Water–Dipropylamine–Diisopropylamine System for Extraction Applications

Theoretical Foundations of Chemical Engineering, Год журнала: 2024, Номер 58(6), С. 1890 - 1899

Опубликована: Дек. 1, 2024

Язык: Английский

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