Analyzing the physical chemistry of the structural dynamics and stabilizing interactions of citrazinic acid‐ammonium formamide complex DOI Open Access

Sneha Anna Sunny,

Nathan Hrangkhawl,

Devadath Jayakumar

и другие.

Vietnam Journal of Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 13, 2024

Abstract This paper studies the nature of non‐covalent interactions in complex formed by citrazinic acid and ammonium formamide (CA‐AF), employing principles density functional theory (DFT). The individual molecules CA AF, as well their combined dimer CA‐AF, underwent optimization a gas‐phase environment, utilizing M062X/aug‐cc‐pVDZ approach. study calculated binding energy for optimized to evaluate its thermodynamic stability. To qualitatively dissect within CA‐AF complex, techniques such reduced gradient (RDG) method quantum atoms (QTAIM) were applied. Charge distribution across complex's was scrutinized through Mulliken population analysis natural analysis. also explored electronic characteristics with focus on charge delocalization, which analyzed using bond orbital techniques. investigation unveiled notable hydrogen interaction between CA's AF's oxygen atoms, finding corroborated QTAIM exploration enhances understanding bonding molecular structures, offering valuable insights into dynamics.

Язык: Английский

Unveiling the host-guest interactions: CC2 nanocage as an advanced sensor for detection of nitrogenous bases in DNA DOI
Atazaz Ahsin,

Aamna Qamar,

Sadegh Kaviani

и другие.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2025, Номер 709, С. 136112 - 136112

Опубликована: Янв. 5, 2025

Язык: Английский

Процитировано

0

Spectroscopic, Quantum computational investigation, Light Harvesting Effect, Insilco biological evaluations and Molecular Docking of novel Pyrazole derivative - A potential Anti-Cancer agent DOI
P. Manikandan, Mohit Kumar,

S. Kaleeswaran

и другие.

Journal of the Indian Chemical Society, Год журнала: 2025, Номер 102(5), С. 101657 - 101657

Опубликована: Март 5, 2025

Язык: Английский

Процитировано

0

Halogens’ effect on human cancer cells of synthesized Vilsmeier reaction-based indole-containing azines derivatives DOI
Sameena Bano, Mohd Asif,

Zainab Feroz

и другие.

Medicinal Chemistry Research, Год журнала: 2025, Номер unknown

Опубликована: Апрель 7, 2025

Язык: Английский

Процитировано

0

Unveiling the Multifunctionality of Chalcone-based Organic Crystal: A Study on Nonlinear Optics, Photoluminescence, and Molecular Simulations DOI

Keerthikumara Venkatesha,

Mahesh Sankanahalli Srinivas,

Ananda Swamynayaka

и другие.

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 142469 - 142469

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Medicinal significance of sp2/sp3 hybridized at C-3-substituted indole-containing lead molecules and FDA-approved drugs DOI

Mohd Faiyyaz,

Akanksha Tiwari,

Nuzhat Bashir

и другие.

Medicinal Chemistry Research, Год журнала: 2024, Номер unknown

Опубликована: Сен. 13, 2024

Язык: Английский

Процитировано

2

Synthesis of highly functionalized imine-containing halogen-substituted-1-oxo-acenaphthenes and their quantum computational investigation as propitious drugs for anti-skin cancer DOI
Aslı Eşme, Abul Hasnat,

Nuzhat Bashir

и другие.

Journal of Molecular Liquids, Год журнала: 2024, Номер 415, С. 126402 - 126402

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

1

Quantum computational and experimental spectroscopic investigation (FT-IR, Raman, UV–Vis), PES, LHE and topological investigations of 7-[(2R)-2-hydroxypropyl]-1,3-dimethylpurine-2,6-dione DOI

S. Gayathri,

M. Saravanakumar,

P. Manikandan

и другие.

Journal of Photochemistry and Photobiology A Chemistry, Год журнала: 2024, Номер 459, С. 116067 - 116067

Опубликована: Окт. 9, 2024

Язык: Английский

Процитировано

0

Novel Spirooxindole–Benzofuran Scaffold: Potential Inhibition Against Hepatocellular Carcinoma by Targeting MDM2‐p53 Interaction DOI
Muhanna K. Al‐Muhanna, Assem Barakat, Mohammad Shahidul Islam

и другие.

ChemistrySelect, Год журнала: 2024, Номер 9(46)

Опубликована: Дек. 1, 2024

Abstract We synthesized a novel compound library featuring spirooxindole core structure combined with various heterocycles, including benzofuran, benzothiophene, and thiophene scaffolds. Evaluation using MTT assays against HepG2, 4T1, MDA‐MB‐231 cells revealed the most potent candidate, hybrid 5c , an IC50 of 5 ± 0.6 µM inducing G2/M phase cell cycle arrest, inhibition wound healing, induction ROS. Selected conjugates exhibited significant inhibitory potential MDM2, KD values ranging from 0.0531 to 16.8 µM. Notably, salt analogue 5q demonstrated highest activity at K D = 53.1 nM. Molecular docking studies excellent accommodation designed compounds within MDM2 receptor. All displayed favorable ADME profiles, suggesting their as lead for further optimization.

Язык: Английский

Процитировано

0

Analyzing the physical chemistry of the structural dynamics and stabilizing interactions of citrazinic acid‐ammonium formamide complex DOI Open Access

Sneha Anna Sunny,

Nathan Hrangkhawl,

Devadath Jayakumar

и другие.

Vietnam Journal of Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 13, 2024

Abstract This paper studies the nature of non‐covalent interactions in complex formed by citrazinic acid and ammonium formamide (CA‐AF), employing principles density functional theory (DFT). The individual molecules CA AF, as well their combined dimer CA‐AF, underwent optimization a gas‐phase environment, utilizing M062X/aug‐cc‐pVDZ approach. study calculated binding energy for optimized to evaluate its thermodynamic stability. To qualitatively dissect within CA‐AF complex, techniques such reduced gradient (RDG) method quantum atoms (QTAIM) were applied. Charge distribution across complex's was scrutinized through Mulliken population analysis natural analysis. also explored electronic characteristics with focus on charge delocalization, which analyzed using bond orbital techniques. investigation unveiled notable hydrogen interaction between CA's AF's oxygen atoms, finding corroborated QTAIM exploration enhances understanding bonding molecular structures, offering valuable insights into dynamics.

Язык: Английский

Процитировано

0