Cost‐effective synthesis of unsymmetric tetrazines DOI Creative Commons
Jangsun Hwang, Bokyung Yoon, Sung‐Eun Suh

и другие.

Bulletin of the Korean Chemical Society, Год журнала: 2024, Номер 45(10), С. 867 - 872

Опубликована: Окт. 1, 2024

Abstract 1,2,4,5‐Tetrazines serve as versatile two‐carbon synthons, essential for synthesizing a variety of (hetero)aromatic compounds. Their specific reactivity with certain dienophiles, without interfering biochemical processes, makes them ideal bioorthogonal ligation. Despite their broad utility, current synthetic methods are costly and raise safety concerns, particularly during scale‐up. This study introduces safer more cost‐effective strategies utilizing zinc chloride or boron trifluoride diethyl etherate catalysts. These alternatives significantly reduce costs enhance safety, potentially expanding the applicability tetrazine synthesis across broader research domains.

Язык: Английский

Benzothiazole a privileged scaffold for Cutting-Edges anticancer agents: Exploring drug design, structure-activity relationship, and docking studies DOI

I. Aayishamma,

Gurubasavaraja Swamy Purawarga Matada, Rohit Pal

и другие.

European Journal of Medicinal Chemistry, Год журнала: 2024, Номер 279, С. 116831 - 116831

Опубликована: Сен. 6, 2024

Язык: Английский

Процитировано

10

Discovery of novel 2,6-disubstituted-3-cyano-4-(trifluoromethyl)pyridine derivatives as potential anti‑prostate cancer agents targeting BLM helicase DOI
Xinyu Liu,

S WEI,

Gang Yu

и другие.

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 142837 - 142837

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0

Chalcone derivatives containing 1,2,4-triazole and pyridine moiety: design, synthesis, and antiviral activity DOI
Hui Xin,

Jiao Tian,

Tianyu Deng

и другие.

Molecular Diversity, Год журнала: 2024, Номер unknown

Опубликована: Дек. 2, 2024

Язык: Английский

Процитировано

2

Anticancer Effect of Novel Phthalazines Derivatives: Synthesis, Biological Evaluation, DFT, ADMET and Docking Study DOI
Walid Ettahiri, Driss Fadili, Mohammed M. Alanazi

и другие.

Journal of Molecular Structure, Год журнала: 2024, Номер unknown, С. 141173 - 141173

Опубликована: Дек. 1, 2024

Язык: Английский

Процитировано

2

Cost‐effective synthesis of unsymmetric tetrazines DOI Creative Commons
Jangsun Hwang, Bokyung Yoon, Sung‐Eun Suh

и другие.

Bulletin of the Korean Chemical Society, Год журнала: 2024, Номер 45(10), С. 867 - 872

Опубликована: Окт. 1, 2024

Abstract 1,2,4,5‐Tetrazines serve as versatile two‐carbon synthons, essential for synthesizing a variety of (hetero)aromatic compounds. Their specific reactivity with certain dienophiles, without interfering biochemical processes, makes them ideal bioorthogonal ligation. Despite their broad utility, current synthetic methods are costly and raise safety concerns, particularly during scale‐up. This study introduces safer more cost‐effective strategies utilizing zinc chloride or boron trifluoride diethyl etherate catalysts. These alternatives significantly reduce costs enhance safety, potentially expanding the applicability tetrazine synthesis across broader research domains.

Язык: Английский

Процитировано

0